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The Trace Gas Analyzer (TGA, Figure 1) is a self-contained, battery-powered mass spectrometer that is designed for use by astronauts during extravehicular activities (EVA) on the International Space Station (ISS). The TGA contains a miniature quadrupole mass spectrometer array (QMSA) that determines the partial pressures of ammonia, hydrazines, nitrogen, and oxygen. The QMSA ionizes the ambient gas mixture and analyzes the component species according to their charge-to-mass ratio. The QMSA and its electronics were designed, developed, and tested by the Jet Propulsion Laboratory (1,2). Oceaneering Space Systems supported JPL in QMSA detector development by performing 3D computer for optimal volumetric integration, and by performing stress and thermal analyses to parameterize environmental performance.

For planetary exploration, new thermal insulation materials are needed to deal with unique environmental conditions presented to extravehicular activity (EVA). The thermal insulation material and system used in the existing space suit were specifically designed for low orbit environment. They are not adequate for low vacuum condition commonly found in planetary environments with a gas atmosphere. This study attempts to identify the types of lofty nonwoven thermal insulation materials and the construction parameters that yield the best performance for such application. Lofty nonwovens with different construction parameters are evaluated for their thermal conductivity performance. Three different types of fiber material: solid round fiber, hollow fiber, and grooved fiber, with various denier, needling intensity, and web density were evaluated.

Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

Progress on the delivery of the Vehicle Cabin Atmosphere Monitor (VCAM) is reported. VCAM is an autonomous trace-species detector to be used aboard the International Space Station (ISS) for atmospheric analysis. The instrument is based on a low-mass, low-power miniature preconcentrator, gas chromatograph, and Paul ion trap mass spectrometer (PCGC/MS) capable of measuring volatile constituents in a space vehicle or planetary outpost at sub-ppm levels. VCAM detects and quantifies 40 target compounds at their 180-day Spacecraft Maximum Allowable Concentration (SMAC) levels. It is designed to operate autonomously, maintenance-free, with a self-contained carrier and calibration gas supplies sufficient for a one-year lifetime. Two flight units will be delivered for operation in the ISS EXPRESS rack.

This paper present a summary of the design studies for the suit port proof of concept. The Suit Port reduces the need for airlocks by docking the suits directly to a rover or habitat bulkhead. The benefits include reductions in cycle time and consumables traditionally used when transferring from a pressurized compartment to EVA and mitigation of planetary surface dust from entering into the cabin. The design focused on the development of an operational proof of concept evaluated against technical feasibility, level of confidence in design, robustness to environment and failure, and the manufacturability. A future paper will discuss the overall proof of concept and provide results from evaluation testing including gas leakage rates upon completion of the testing program.

Work is underway to deliver an instrument for analysis of the atmosphere aboard the International Space Station. The Vehicle Cabin Atmosphere Monitor (VCAM) is based on a low-mass, low-power miniature preconcentrator gas chromatograph/mass spectrometer (PCGC/MS) capable of providing sub-ppm measurements of volatile constituents in a space vehicle or outpost. VCAM is designed to operate autonomously, maintenance-free, once per day, with its own carrier and calibration gas supplies sufficient for a one-year lifetime. VCAM performance is sufficient to detect and identify 90% of the target compounds specified at their 180-day Spacecraft Maximum Allowable Concentration (SMAC) levels. The flight units will be delivered in mid-2008 and be operated in the ISS EXPRESS rack.

Polymers are one of the major constituents in electrical components. A study investigating pre-combustion off-gassing and particle release by polymeric materials over a range of temperatures can provide an understanding of thermal degradation prior to failure which may result in a fire hazard. In this work, we report simultaneous measurements of pre-combustion vapor and particle release by heated polymeric materials. The polymer materials considered for the current study are silicone and Kapton. The polymer samples were heated over the range 20 to 400°C. Response to vapor releases were recorded using the JPL Electronic Nose (ENose) and Industrial Scientific's ITX gas monitor configured to detect hydrogen chloride (HCl), carbon monoxide (CO) and hydrogen cyanide (HCN). Particle release was monitored using a TSI P-TRAK particle counter.

Simultaneous measurements were made for particle releases and off-gassing products produced by heating electrical wires. The wire samples in these experiments were heated to selected temperatures in a heating chamber and responses to vapor releases were recorded by the JPL Electronic Nose (ENose) and an Industrial Scientific ITX gas-monitor; particles released were detected by a TSI P-Trak particle counter. The temperature range considered for the experiment is room temperature (24−26°C) to 500 °C. The results were analyzed by overlapping responses from the ENose, ITX gas sensors and P-Trak, to understand the events (particle release/off-gassing) and sequence of events as a function of temperature and to determine qualitatively whether ENose may be used to detect pre-combustion event markers.

The incidence of DCS in null gravity appears to be considerably less than predicted by 1-g experiments. In NASA studies in 1-g, 83% of the incidents of DCS occur in the legs. We report first on a study with a crossover design that indicated a considerable reduction in the decompression Doppler bubble grade in the lower extremities in subjects in simulated microgravity (bed rest) as compared to themselves when ambulatory in unit gravity. Second we describe the results of a cardiovascular deconditioning study using a tail-suspended rat model. Since there may be a reduction in bubble production in 0-g, this would reduce the possibility of acquiring neurological DCS, especially by arterial gas embolism. Further, cardiovascular deconditioning appears to reduce the pulmonary artery hypertension (secondary to gas embolization) necessary to effect arterialization of bubbles.

This paper describes the need and solution for minimizing EVA airlock time and depress gas losses using a new method that minimizes EVA out-the-door time for a suited astronaut and reclaims most of the airlock depress gas. This method consists of one or more related concepts that use an evacuated reservoir tank to store and reclaim the airlock depress gas. The evacuated tank can be an inflatable tank, a spent fuel tank from a lunar lander descent stage, or a backup airlock. During EVA airlock operations, the airlock and reservoir would be equalized at some low pressure, and through proper selection of reservoir size, most of the depress gas would be stored in the reservoir for later reclamation. The benefit of this method is directly applicable to long duration lunar and Mars missions that require multiple EVA missions (up to 100, two-person lunar EVAs) and conservation of consumables, including depress pump power and depress gas.

Gas transfer systems in a closed life support test were controlled by intelligent layered monitoring and control software. Interactive simulation-based testing was used for system-level validation of the discrete sequencer layer of the software. An advanced discrete event simulation tool was used to model diverse components and systems for processing gases in a plant growth chamber, crew chamber and incinerator, and transferring gases between chambers. Models included physico-chemical and biological gas processors, pumps, concentrators, chambers and tanks, and devices for configuring and controlling gas transfer. Several types of control were modeled. This paper describes the models, the testing approach, and some results of the testing.

In a crewed spacecraft environment, atmospheric carbon dioxide (CO2) and moisture control are crucial. Hamilton Sundstrand has developed a stable and efficient amine-based CO2 and water vapor sorbent, SA9T, that is well suited for use in a spacecraft environment. The sorbent is efficiently packaged in pressure-swing regenerable beds that are thermally linked to improve removal efficiency and minimize vehicle thermal loads. Flows are controlled with a single spool valve. This technology has been baselined for the new Orion spacecraft, but additional data was needed on the operational characteristics of the package in a simulated spacecraft environment. One unit was tested with simulated metabolic loads in a closed chamber at Johnson Space Center during the latter part of 2006. Those test results were reported in a 2007 ICES paper.

The development of tunable diode laser systems in the 2 - 5 μm spectral region will have numerous applications for trace gas detection. To date, the development of such systems has been hampered by the difficulties of epitaxial growth, and device processing in the case of the Sb-based materials system. One of the compounding factors in this materials system is the use of aluminum containing compounds in the laser diode cladding layers. This makes the regrowth steps used in traditional lasers very difficult. As an alternative approach we are developing laterally coupled antimonide based lasers structures that do not require the regrowth steps. In this paper, the materials growth, device processing and development of the necessary drive electronics for an antimony based tunable diode laser system are discussed.

Copper- and Iron- based metal-zeolite SCR catalysts are widely used in US and European diesel aftertreatment systems to achieve drastic reduction in NOx emission. These catalysts are highly selective to N2 under wide range of operating conditions. Nevertheless, the type of transition metal has a significant impact on the key performance and durability parameters such as NOx conversion, selectivity towards N2O, hydrothermal stability, and sensitivity to fuel sulfur content. In this study, we explained the differences in the performance characteristics of these catalysts based on their relative acidic-basic nature of transition metal present in these catalysts using practically relevant gas species present in diesel exhaust such as NO2, SOx, and NH3. These experiments show that Fe-zeolite has relatively acidic nature as compared to Cu-zeolite that causes NH3 inhibition and hence explains low NOx conversion on Fe-zeolite at low temperature under standard SCR conditions.

Development of new air revitalization system (ARS) technology can initially be performed in a subscale laboratory environment, but in order to advance the maturity level, the technology must be tested in an end-to-end integrated environment. The Air Revitalization Technology Evaluation Facility (ARTEF) at the NASA Johnson Space Center (JSC) serves as a ground test bed for evaluating emerging ARS technologies in an environment representative of spacecraft atmospheres. At the center of the ARTEF is a hypobaric chamber which serves as a sealed atmospheric chamber for closed loop testing. A Human Metabolic Simulator (HMS) was custom-built to simulate the consumption of oxygen, and production of carbon dioxide, moisture and heat by up to eight persons. A variety of gas analyzers and dew point sensors are used to monitor the chamber atmosphere and the process flow upstream and downstream of a test article. A robust vacuum system is needed to simulate the vacuum of space.

Biological water processors are currently being developed for application in microgravity environments. Work has been performed to develop a single-phase, gravity independent anoxic denitrification reactor for organic carbon removal [1]. As a follow on to this work it was necessary to develop a gravity independent nitrification reactor in order to provide sufficient nitrite and nitrate to the organic carbon oxidation reactor for the complete removal of organic carbon. One approach for providing the significant amounts of dissolved oxygen required for nitrification is to require the biological reactor design to process two-phase gas and liquid in micro-gravity. This paper addresses the design and test results overview for development of a tubular, two-phase, gravity independent nitrification biological water processor.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

Scientists and engineers at NASA are currently developing flight instruments which will demonstrate oxygen production on the Moon and Mars. REGA will extract oxygen from the lunar regolith, measure implanted solar wind and indigenous gases, and monitor the lunar atmosphere. MIP will demonstrate oxygen production on Mars, along with key supporting technologies including filtration, atmospheric acquisition and compression, thermal management, solar cell performance, and dust removal.

The incidence of decompression sickness (DCS) in space appears to be less than that predicted to occur on the basis of ground based altitude chamber trials. Our current work uses six hours of chair rest adynamia and likewise produces fewer gas bubbles when compared to standing in a cross over study. Mild exercise during oxygen prebreathe is also very efficacious in reducing DCS and bubble formation (measured by Doppler ultrasound). The effect is postulated to be the result of the alteration in the populations of tissue micronuclei such that the radii are reduced. Surface tension then becomes too great for bubble growth from the existing inert gas partial pressures.