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Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

The increased use of zinc coatings on steels has led to a decrease in their weldability. Weld current and time need to be increased in order to achieve sound welds on these materials compared to uncoated steels, and electrode tip life suffers greatly due to rapid alloying and degradation. In this work, typical uncoated Class II electrodes were tested along with a TiC metal matrix composite (MMC) coated electrode. Tests were conducted to study the weldability and process of nugget formation for both electrodes on HDG (hot dipped galvanized) HSLA (high strength low alloys) steels. Current and time ranges were constructed for both types of electrodes by varying either the weld current or weld time while holding all other parameters constant. Analysis of weld microstructures was conducted on cross-sectioned welds using SEM (scanning electron microscopy). Using the coated electrodes reduced weld current and times needed to form MWS (minimum weld size) on the coated steels.

The present work investigates weld failure modes during formability tests of multi-gauge aluminum Tailor Welded Blanks (TWBs). The limiting dome height test is used to evaluate formability of TWBs. Three gauge combinations utilizing aluminum alloy 5754 sheets are considered (2 to 1 mm, 1.6 to 1 mm and 2 to 1.6 mm). Three weld orientations have been considered: transverse, longitudinal and 45°. Interaction of several factors determines the type of failure that occurs in a TWB specimen. These factors are weld orientation, morphology and distribution of weld defects, and the magnitude of constraint imposed by the thicker sheet to the thin sheet. The last factor depends on the difference in thickness of the sheet pair and is usually expressed in terms of gauge ratio. In general TWBs show two different types of fracture: weld failure and failure of the thin aluminum sheet. Only the former will be discussed in this paper.

The present work is aimed at investigating the tribological factors influencing the LDH test. The material used was AKDQ cold-rolled bare steel, 0.82mm thick. The investigated factors included: test speed (0.833, 4.167, 6.667, and 8.333 mm/s), lubricant viscosity (4.5, 7.0, and 12.5 mm2/s), punch roughness (0.033 and 0.144 μm Ra), and test temperature (25 and 50 °C). Test speed and lubricant viscosity form a variation of the numerator of the Stribeck curve's x-axis (ηV). With ηV increasing from 4 to 120 mm3/s2 friction decreased, resulting in a 0.5 mm higher LDH. Increasing the punch roughness decreased friction producing an increase of 0.25 mm in the LDH. There appears to be an optimum roughness -- at which the roughness features act as lubricant reservoirs but the asperities do not break through the lubricant film -- resulting in minimum friction, therefore, maximum LDH.

Details of the development of metal transfer and friction were studied by drawing cold-rolled bare, galvannealed, electrogalvanized, and hot-dip galvanized strips with a mineral-oil lubricant of 30 cSt viscosity at 40 C, over a total distance of 2500 mm by three methods. An initial high friction peak was associated with metal transfer to the beads and was largest with pure zinc and smallest with Fe-Zn coatings. Insertion of a new strip disturbed the coating and led to the development of secondary peaks. Long-term trends were governed by the stability of the coating. Stearic acid added to mineral oil delayed stabilization of the coating and increased contact area and thus friction with pure zinc surfaces. The usual practice of reporting average friction values can hide valuable information on lubrication mechanisms and metal transfer.

Light duty vehicle emission standards are getting more stringent than ever before as stipulated by US EPA Tier 2 Standards and LEV III regulations proposed by CARB. The research in this paper sponsored by US DoE is focused towards developing a Tier 2 Bin 2 Emissions compliant light duty pickup truck with class leading fuel economy targets of 22.4 mpg “City” / 34.3 mpg “Highway”. Many advanced technologies comprising both engine and after-treatment systems are essential towards accomplishing this goal. The objective of this paper would be to discuss key engine technology enablers that will help in achieving the target emission levels and fuel economy. Several enabling technologies comprising air-handling, fuel system and base engine design requirements will be discussed in this paper highlighting both experimental and analytical evaluations.

A series plug-in hybrid electric powertrain with all-wheel drive is designed using real-world drive cycles as part of the EcoCAR 2 competition. A stock 2013 Chevrolet Malibu Eco is being re-engineered to reduce fuel consumption and emissions while improving consumer acceptability. Waterloo utilizes a 18.9 kWh A123 energy storage system (ESS), which powers two 105 kW TM4 traction motors. A 2.4 L LE9 General Motors coupled to a 105 kW TM4 motor provides range extending performance. Each step of the design process is discussed, including a novel approach to powertrain selection and controls requirement selection that uses real-world drive cycles. The mechanical integration and unique ESS design is also discussed.

Current production heavy duty diesel engines have a brake thermal efficiency (BTE) between 43-46% [1]. In partnership with the United States Department of Energy (DOE) as part of the Supertruck 2 program, Cummins has undertaken a research program to develop a new heavy-duty diesel engine designed to deliver greater than 50% BTE without the use of waste heat recovery. A system level optimization focused on: increased compression ratio, higher injection rate, carefully matched highly efficient turbocharging, variable lube oil pump, variable cooling components, and low restriction after treatment designed to deliver 50% BTE at a target development point. This work will also illustrate the system level planning and understanding of interactions required to allow that same 50% BTE heavy duty diesel engine to be integrated with a waste heat recovery (WHR) system to deliver system level efficiency of 55% BTE at a single point.

The influence of big-end bore fretting on connecting rod fatigue fracture is investigated. A finite element model, including rod-bearing contact interaction, is developed to simulate a fatigue test rig where the connecting rod is subjected to an alternating uniaxial load. Comparison of the model results with a rod fracture from the fatigue rig shows good correlation between the fracture location and the peak ‘Ruiz’ criterion, rather than the peak tensile stress location, indicating the potential of fretting to initiate a fatigue fracture and the usefulness of the ‘Ruiz’ criterion as a measure of location and severity. The model is extended to simulate a full engine cycle using pressure loads from a bearing EHL analysis. A fretting map and a ‘Ruiz’ criterion map are developed for the full engine cycle, giving an indication of a safe ‘Ruiz’ level from an existing engine which has been in service for more than 5 years.

Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature.

The development and calibration of stress state-dependent failure criteria for advanced high-strength steel (AHSS) and aluminum alloys requires characterization under proportional loading conditions. Traditional tests to construct a forming limit diagram (FLD), such as Marciniak or Nakazima tests, are based upon identifying the onset of strain localization or a tensile instability (neck). However, the onset of localization is strongly dependent on the through-thickness strain gradient that can delay or suppress the formation of a tensile instability so that cracking may occur before localization. As a result, the material fracture limit becomes the effective forming limit in deformation modes with severe through-thickness strain gradients, and this is not considered in the traditional FLD. In this study, a novel bending test apparatus was developed based upon the VDA 238-100 specification to characterize fracture in plane strain bending using digital image correlation (DIC).

Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

A cold worked and induction hardened SAE1045 steel component exhibited excessive distortion after cold working and straightening, as well as cracking during straightening after induction hardening. Since the problems occurred only in certain heats of electric furnace (EF) steel, in which nitrogen content can vary widely and in some cases be quite high, and never occurred for basic oxygen furnace (BOF) steel for which nitrogen contents are uniformly low it was suspected that the source of the problem was low temperature nitrogen strain aging in heats of EF steel with a high nitrogen content. The measured distortion and mechanical properties at various stages in the fabrication process showed that while nitrogen content had no significant effect on the hot rolled steel the component distortion and strength after cold working and after induction hardening increased with increasing nitrogen content.

In modern engine design, downsizing and reducing weight while still providing an increased amount of power has been a general trend in recent decades. Traditionally, an engine design with superior NVH performance usually comes with a heavier, thus sturdier structure. Therefore, modern engine design requires that NVH be considered in the very early design stage to avoid modifications of engine structure at the last minute, when very few changes can be made. NVH design optimization of engine components has become more practical due to the development of computer software and hardware. However, there is still a need for smarter algorithms to draw a direct relationship between the design and the radiated sound power. At the moment, techniques based on modal acoustic transfer vectors (MATVs) have gained popularity in design optimization for their good performance in sound pressure prediction.

With increasing energy prices and concerns about the environmental impact of greenhouse gas (GHG) emissions, a growing number of national governments are putting emphasis on improving the energy efficiency of the equipment employed throughout their transportation systems. Within the U.S. transportation sector, energy use in commercial vehicles has been increasing at a faster rate than that of automobiles. A 23% increase in fuel consumption for the U.S. heavy duty truck segment is expected from 2009 to 2020. The heavy duty vehicle oil consumption is projected to grow while light duty vehicle (LDV) fuel consumption will eventually experience a decrease. By 2050, the oil consumption rate by LDVs is anticipated to decrease below 2009 levels due to CAFE standards and biofuel use. In contrast, the heavy duty oil consumption rate is anticipated to double. The increasing trend in oil consumption for heavy trucks is linked to the vitality, security, and growth of the U.S. and global economies.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure.

The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.

This work presents comparisons of finite element model predictions of static and dynamic denting with experimental results. Panels were stamped from 0.81, 0.93 and 1.00mm AA6111-T4 and then paint-baked to produce representative automotive outer body panels. Each type of panel was statically and dynamically dented at three locations using a 25.4mm steel ball. Static denting was accomplished with incremental loading of 22.24N loads up to a maximum of 244.48N. Dynamic denting was accomplished by dropping the steel ball from heights ranging from 200mm to 1200mm. Multi-stage finite element analysis was performed using LS-DYNA1 and ABAQUS2 to predict the entire process of forming, spring-back, denting and final spring-back of the dented panels. The predicted results show good correlation with the experiments, but also highlight the sensitivity of the predictions to formulation of the finite element problem.