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Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

More stringent regulations have been enforced over the past few years on diesel exhaust emissions. White smoke emission, a characteristic of diesel engines during cold starting, needs to be controlled in order to meet these regulations. This study investigates the sources and constituents of white smoke. The effects of fuel properties, design and operating parameters on the formation and emissions of white smoke are discussed. A new technique is developed to measure the real time gaseous hydrocarbons (HC) as well as the solid and liquid particulates. Experiments were conducted on a single cylinder direct injection diesel engine in a cold room. The gaseous HC emissions are measured using a high frequency response flame ionization detector. The liquid and solid particulates are collected on a paper filter placed upstream of the sampling line of the FID and their masses are determined.

An experimental study was carried out to characterize the exhaust flow structure inside the closed-coupled catalytic converter, which is installed on a firing four-cylinder 12-valve passenger car gasoline engine. Simultaneous velocity and pressure measurements were taken using cycle-resolved Laser Doppler anemometer (LDA) technique and pressure transducer. A small fraction of titanium (IV) iso-propoxide was dissolved in gasoline to generate titanium dioxide during combustion as seeding particles for the LDA measurements. It was found that the velocity is highly fluctuating due to the pulsating nature of the engine exhaust flow, which strongly depends on the engine operating conditions and the measuring locations. The pressure oscillation is correlated with the transient exhaust flow characteristics. The main exhaust flow event from each cylinder can only be observed at the certain region in front of the monolith brick.

An experimental study was performed, using cycle-resolved laser Doppler velocimetry (LDV) technique, to characterize the exhaust flow structure inside a catalytic converter retro-fitted to a firing four-cylinder gasoline engine over different operating conditions. A small fraction of titanium (IV) isopropoxide was dissolved in gasoline to generate titanium dioxide during combustion as seeding particles for LDV measurements. It was found that in the front plane of the catalytic monolith, the velocity is highly fluctuating due to the pulsating nature of the engine exhaust flow, which strongly depends on the engine operating conditions. Under unloaded condition, four pairs of major peaks are clearly observed in the time history of the velocity, which correspond to the main exhaust events of each individual cylinder.

The instantaneous frictional torque (IFT) of the engine and the piston-ring assembly frictional force (PRAFF) were determined during cranking and starting of a direct injection single cylinder diesel engine. The measurements included the cylinder gas pressure, the instantaneous torque of the electric starter, the angular velocity of the crankshaft and the axial force on the connecting rod. The engine and piston friction were determined every crank angle degree for all the cycles from the time the starter was engaged to the time the engine reached the idling speed. The data was analyzed and a comparison was made between the friction in successive cycles.

Light duty vehicle emission standards are getting more stringent than ever before as stipulated by US EPA Tier 2 Standards and LEV III regulations proposed by CARB. The research in this paper sponsored by US DoE is focused towards developing a Tier 2 Bin 2 Emissions compliant light duty pickup truck with class leading fuel economy targets of 22.4 mpg “City” / 34.3 mpg “Highway”. Many advanced technologies comprising both engine and after-treatment systems are essential towards accomplishing this goal. The objective of this paper would be to discuss key engine technology enablers that will help in achieving the target emission levels and fuel economy. Several enabling technologies comprising air-handling, fuel system and base engine design requirements will be discussed in this paper highlighting both experimental and analytical evaluations.

Current production heavy duty diesel engines have a brake thermal efficiency (BTE) between 43-46% [1]. In partnership with the United States Department of Energy (DOE) as part of the Supertruck 2 program, Cummins has undertaken a research program to develop a new heavy-duty diesel engine designed to deliver greater than 50% BTE without the use of waste heat recovery. A system level optimization focused on: increased compression ratio, higher injection rate, carefully matched highly efficient turbocharging, variable lube oil pump, variable cooling components, and low restriction after treatment designed to deliver 50% BTE at a target development point. This work will also illustrate the system level planning and understanding of interactions required to allow that same 50% BTE heavy duty diesel engine to be integrated with a waste heat recovery (WHR) system to deliver system level efficiency of 55% BTE at a single point.

The influence of big-end bore fretting on connecting rod fatigue fracture is investigated. A finite element model, including rod-bearing contact interaction, is developed to simulate a fatigue test rig where the connecting rod is subjected to an alternating uniaxial load. Comparison of the model results with a rod fracture from the fatigue rig shows good correlation between the fracture location and the peak ‘Ruiz’ criterion, rather than the peak tensile stress location, indicating the potential of fretting to initiate a fatigue fracture and the usefulness of the ‘Ruiz’ criterion as a measure of location and severity. The model is extended to simulate a full engine cycle using pressure loads from a bearing EHL analysis. A fretting map and a ‘Ruiz’ criterion map are developed for the full engine cycle, giving an indication of a safe ‘Ruiz’ level from an existing engine which has been in service for more than 5 years.

Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature.

Cerebral blood vessels are an integral part of the brain and may play a role in the response of the brain to impact. The purpose of this study was to quantify the effects of surrogate vessels on the deformation patterns of a physical model of the brain under various impact conditions. Silicone gel and tubing were used as surrogates for brain tissue and blood vessels, respectively. Two aluminum cylinders representing a coronal section of the brain were constructed. One cylinder was filled with silicone gel only, and the other was filled with silicone gel and silicone tubing arranged in the radial direction in the peripheral region. An array of markers was embedded in the gel in both cylinders to facilitate strain calculation via high-speed video analysis. Both cylinders were simultaneously subjected to a combination of linear and angular acceleration using a two-segment pendulum.

Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

Natural gas has been considered to be one of the most promising alternative fuels due to its lower NOx and soot emissions, less carbon footprint as well as attractive price. Furthermore, higher octane number makes it suitable for high compression ratio application compared with other gaseous fuels. For better economical and lower emissions, a turbocharged, four strokes, direct injection, high pressure common rail diesel engine has been converted into a diesel/natural gas dual-fuel engine. For dual-fuel engine operation, natural gas as the main fuel is sequentially injected into intake manifold, and a very small amount of diesel is directly injected into cylinder as the ignition source. In this paper, a dual-fuel electronic control unit (ECU) based on the PowerPC 32-bit microprocessor was developed. It cooperates with the original diesel ECU to control the fuel injection of the diesel/natural gas dual-fuel engine.

In modern engine design, downsizing and reducing weight while still providing an increased amount of power has been a general trend in recent decades. Traditionally, an engine design with superior NVH performance usually comes with a heavier, thus sturdier structure. Therefore, modern engine design requires that NVH be considered in the very early design stage to avoid modifications of engine structure at the last minute, when very few changes can be made. NVH design optimization of engine components has become more practical due to the development of computer software and hardware. However, there is still a need for smarter algorithms to draw a direct relationship between the design and the radiated sound power. At the moment, techniques based on modal acoustic transfer vectors (MATVs) have gained popularity in design optimization for their good performance in sound pressure prediction.

A hot and cold water mixing process with a steam condenser and a chilled water heat exchanger is set up for an engine EGR fouling test. The test rig has water recycled in the loop of a pump, heat exchangers, a three-way mixing valve, and a test EGR unit. The target unit temperature is controlled by a heating, cooling and mixing process with individual valves regulating the flow-rate of saturated steam, chilled water and mixing ratio. The challenges in control design are the dead-time, interaction, nonlinearity and multivariable characteristics of heat exchangers, plus the flow recycle in the system. A systems method is applied to extract a simple linear model for control design. The method avoids the nonlinearity and interaction among different temperatures at inlet, outlet and flow-rate. The test data proves the effectiveness of systems analysis and modeling methodology. As a result, the first-order linear model facilitates the controller design.

With increasing energy prices and concerns about the environmental impact of greenhouse gas (GHG) emissions, a growing number of national governments are putting emphasis on improving the energy efficiency of the equipment employed throughout their transportation systems. Within the U.S. transportation sector, energy use in commercial vehicles has been increasing at a faster rate than that of automobiles. A 23% increase in fuel consumption for the U.S. heavy duty truck segment is expected from 2009 to 2020. The heavy duty vehicle oil consumption is projected to grow while light duty vehicle (LDV) fuel consumption will eventually experience a decrease. By 2050, the oil consumption rate by LDVs is anticipated to decrease below 2009 levels due to CAFE standards and biofuel use. In contrast, the heavy duty oil consumption rate is anticipated to double. The increasing trend in oil consumption for heavy trucks is linked to the vitality, security, and growth of the U.S. and global economies.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure.

The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.

Even under steady state operating conditions, the pressure variation in individual cylinders, and the corresponding gas-pressure torque are subjected to small random fluctuations from cycle to cycle. The gas-pressure torque of a cylinder may be expressed as a sum of harmonically variable components, each harmonic being affected by these fluctuations. A probabilistic model of the vector interpreting such a harmonic component is developed and used to determine the statistical parameters of the resultant random vector representing the corresponding harmonic order of the engine torque. At the low frequencies of the lowest harmonic orders of the engine torque the crankshaft behaves like a rigid body. This behavior permits to correlate the statistical parameters of the same harmonic components of the resultant torque and of the measured engine speed. This correlation is proved by experiments and used to identify faulty cylinders.