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Resin-based overlays as lead-free bearing materials for automobile engines are experimentally studied using tribology testing apparatus and an engine bench test rig. A resin overlay newly proposed is composed of Polybenzimidazole (PBI) as the base resin and solid lubricant Molybdenum disulfide (MoS2) as an additive. PBI has high temperature performance and good adhesion and physical strength under higher temperatures. Consequently, a PBI-based overlay has good sliding properties in terms of wear resistance and fatigue resistance. The resin overlay shows applicability to automobile engine bearings which are used under high loads.

Properties of engine bearings were investigated with different bearing materials and different HTHS viscosity oils by means of both an engine test and a rig test. The rig test well simulated the bearing wear which occurred in the engine test. Lead-bronze bearings with lead-tin-indium overlay gave the least amount of wear in operating under high speed and heavy load conditions even with low HTHS viscosity oil. Aluminum bearings without overlay gave good wear resistance in the case of no seizure occurrence. The wear amount of bearings were well correlated with HTHS viscosity, not with kinematic viscosity.

The diffusion phenomena of tin and indium which are contained in the lead-base overlay of 3-layer copper-lead alloy bearings were studied. Easier diffusion of tin compared with indium decreases the corrosion resistance of the overlay, and the tin reacts with the underlayer to form brittle Ni-Sn or Cu-Sn intermetallic compound, resulting in weak bonding strength. Addition of copper into Pb-In overlay markedly restrains the diffusion of indium and therefore stabilizes the characteristics of corrosion resistance, bonding strength and mechanical properties for a long period. Cavitation tests, seizure tests and bearing fatigue tests were conducted on Pb-In-Cu overlay to study the feasibility of its application to actual engine bearings.

The number of vehicles with engines using idling stop systems and hybrid systems to improve fuel consumption has recently been increasing. However, with such systems the frequent starts and stops of the engine, where the oil film between the bearings and shaft is squeezed out and direct contact between the components is more likely, can result in increased wear of the engine bearings, particularly in the main bearing. Bearings with resin overlays have been shown to display superior resistance to wear from such start-stop cycles. Moreover, cast iron shafts without quenching treatment have also been used in engines for cost reduction. Because the cast shaft has low hardness and unstable surface graphite after abrasive finishing, increase in the wear amount cannot be suppressed by conventional resin overlay in comparison with steel shaft. Therefore, the resin overlay with improved wear resistance achieved by adding hard particles was developed.

The recent trend toward the compact and light-weight construction of diesel engines with high power output has been imposing higher requirements of fatigue strength and antiseizure characteristics on bearings. In order to meet these requirements, the authors developed a new bearing alloy of higher fatigue strength for use in heavy load engines, through the analysis of the Al-Zn-Si alloy which has high corrosion resistance. Experimental results of this new alloy to study its physical properties and bearing performances indicate that it can be applied to bearings in diesel engines which operate in harsh conditions.

Recent engine bearings are operating under severe conditions to support such engine requirements as lower fuel consumption, longer life and protection of global environment. On Al-Sn-Si alloy bearings, it has some issue that fatigue may occur on the bearing alloy under severe condition such as in automotive diesel engines. Higher strength of alloy, which allows the fatigue resistance, can be obtained by solid solution treatment at higher temperature in general. But at the same time it makes intermetallic compounds with less bonding strength between intermediate layer and steel backing. A new bearing without lead has been developed by applying the heat treatment of bimetal and adequate intermediate layer for the process, consequently concluded to have the higher fatigue strength, with usual property on Al-Sn-Si alloy bearings.

As the recent engines are designed for higher performance, piston pin bushing used for small end of connecting rod must endure higher dynamic load and oil temperature conditions. Therefore, the bushing is required higher wear resistance and anti-corrosion. And it is also expected to develop the bushing without lead due to environmental concerns. In this report, lead free copper based bushing alloy was studied. At first, in order to keep the anti-seizure property without lead, we studied the effects of hard particles added into copper based alloy. Second, we evaluated the effect of addition of hard particles on wear resistance and anti-corrosion.

Recently, there has been a tendency of high power and high speed in automotive engines. In addition they have been also required high reliability. And engine bearings have been required to be advanced in wear resistance as well as seizure resistance. Therefore, copper-lead alloy bearings with overlay, which have better seizure resistance, have been widely used for high speed engines up to the present. But it becomes very important for them to advance the overlay wear resistance. In this paper, the composite overlay is mainly researched to improve wear resistance regarding kind of hard particles and their amounts in the overlay.

Recently, as for the rod guide bush bearing materials for shock absorbers, lower friction and the improvement of durability are required along with ride quality and longer life of automobile. Usually, lead is contained in bearing materials. However, the addition of the lead in bearing material is being restricted from the earth environmental problem. Bearing materials for shock absorbers are composite material consists of steel backing and covered with polymer surface layer. This basic material structure hasn't been changed till now, though it has been improved by changing its components and compositions based on the customer's requirement. Bearing material with both lower friction and excellent wear resistance has been developed in this study.

The advent of high-performance, compact, and lightweight engines in recent years brings forth a tendency to increase the load for engine bearings and demands on producing even higher levels of durability and reliability in bearing products against fatigue, seizure, wear, and corrosion. Based on the perspective of extending the bearing life, the authors have studied the problems that are encountered with the current three layer copper-lead alloy bearings after their overlay has worn out. Then, we studied the issues of lowered seizure resistance that results from the exposure of the nickel barrier, and of deficient corrosion resistance that results from the exposure of the bearing alloy. In order to improve upon these areas, we focused on diffusion phenomenon of overlay elements without the nickel barrier and also studied the feasibility of creating engine bearings whose alloy composition has been partially modified.

With increased awareness of environmental issues and regulations, developments for recent automotive engines are progressing towards engines with low fuel consumption. Due to these changes, automotive engine bearings are increasingly used in harsher environments, with higher loading and corresponding wear. From this background, resin overlays, where solid lubricant is dispersed in a resin binder, are being developed. Resin overlays show excellent sliding properties under boundary lubrication conditions, and are known to have superior wear and fatigue resistance compared with conventional aluminium based bearings. However, while conventional resin overlay bearings display excellent sliding properties, they tend to have inferior seizure resistance compared to Al-Sn-Si alloy bearings. In this study, by optimizing the strength of the resin overlay layer with addition of calcium carbonate particles, a resin overlay with equal wear resistance but improved seizure resistance was developed.