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The LEV II and SULEV/PZEV emission standards legislated by the US EPA and the Californian ARB will require continuous reduction in the vehicles' emission over the next several years. Similar requirements are under discussion in the European Union (EU) in the EU Stage V program. These future emission standards will require a more efficient after treatment device that exhibits high activity and excellent durabilty over an extended lifetime. The present study summarizes the findings of a joint development program targeting such demanding future emission challenges, which can only be met by a close and intensive co-operation of the individual expert teams. The use of active systems, e.g. HC-adsorber or electrically heated light-off catalysts, was not considered in this study. The following parameters were investigated in detail: The development of a high-tech three-way catalyst technology is described being tailored for applications on ultra thin wall ceramic substrates (UTWS).

This paper describes the results of a joint development program focussing on the introduction of the new generation of Pt/Rh-technology for current and future emission standards as a cost effective alternative to the in serial Pd/Rh based exhaust gas concepts. In the initial phase of the program combinations of Pd- and Pt-based three-way catalyst technologies were evaluated on vehicles equipped with a 8 cylinder engine. One goal in this portion of the study was to achieve technical equivalence between a viable Pd-based technology and the new Pt/Rh technology in the underfloor position at lower precious metal loading. A combination of a close-coupled Pd/Rh technology and the new Pt/Rh in the underfloor position was able to meet the emission targets at significant lower costs of the system after a catalyst aging that resembles more than 100.000 km of vehicle German highway driving.

Investigations of the aerodynamic influence of rotating wheels on a simplified vehicle model as well as on a series production car are presented. For this research CFD simulations are used together with wind tunnel measurements like LDV and aerodynamic forces. Several wheel rim geometries are examined in stationary and in rotating condition. A good agreement could be achieved between CFD simulations and wind tunnel measurements. Based on the CFD analysis the major aerodynamic mechanisms at rotating wheels are characterized. The flow topology around the wheels in a wheel arch is revealed. It is shown, that the reduction of drag and lift caused by the wheel rotation on the isolated wheel and the wheel in the wheel arch are based on different effects of the airflow. Though the forces decrease at the front wheel due to the wheel rotation locally, the major change in drag and lift happens directly on the automotive body itself.

The present paper describes the results of a joint development program focussing on a system approach to meet the EURO IV emission standards for an upper class passenger car equipped with a newly developed high displacement gasoline engine. Based on the well known catalyst systems of recent V6- and V8-engines for the EURO III emission standards with a combination of close coupled catalysts and underfloor catalysts, the specific boundary conditions of an engine with an even larger engine displacement had to be considered. These boundary conditions consist of the space requirements in the engine compartment, the power/torque requirements and the cost requirements for the complete aftertreatment system. Theoretical studies and computer modeling showed essential improvements in catalyst performance by introducing thin wall substrates with low thermal inertia as well as high cell densities with increased geometric surface area.

This paper describes work supporting the development of a new Diesel particulate trap system for heavy duty vehicles based on porous sintered metal materials that exhibit interesting characteristics with respect to ash tolerance. Experimental data characterizing the material (permeability, soot and ash deposit properties) are obtained in a dedicated experimental setup in the side-stream of a modern Diesel engine as well as in an accelerated ash loading rig. System level simulations coupling the new media characteristics to 3-D CFD software for the optimization of complete filter systems are then performed and comparative assessment results of example designs are given.

For the measurement of exhaust emissions, Constant Volume Sampling (CVS) technology is recommended by legislation and has proven its practical capability in the past. However, the introduction of new low emission standards has raised questions regarding the accuracy and variability of the CVS system when measuring very low emission levels. This paper will show that CVS has the potential to achieve sufficient precision for certification of SULEV concepts. Thus, there is no need for the introduction of new test methods involving high cost. An analysis of the CVS basic equations indicates the importance of the Dilution Factor (DF) for calculating true mass emissions. A test series will demonstrate that, by adjusting the dilution and using state of the art analyzers, the consistency of exhaust results is comparable with those of LEV concepts, measured with conventional CVS systems and former standard analyzers.

In view of tight emission standards, injection strategies to reduce raw HC-emissions during the cold starting of port fuel injected engines are evaluated in this study. The relevance of spray targeting and atomization is outlined in the first part of this paper. The foundation and performance of different injector concepts with respect to spray characteristics are discussed. Laboratory experiments demonstrate that concepts relying on auxiliary energy, such as air-assistance, fuel heating and injection at elevated system pressures, are capable of producing spray droplet sizes in the SMD-range of 25μm. For future injection strategies aimed at the compliance of SULEV emission levels, this target value is considered to be essential. In the second part of this paper, emission tests of selected injector concepts are carried out using a V6-3.2I ULEV engine operated both in a vehicle and on a test bench.

To fulfill future emission standards for diesel engines, combined after-treatment systems consisting of different catalyst technologies and diesel particulate filters (DPF) are necessary. For designing and optimizing the resulting systems of considerable complexity, effective simulation models of different catalyst and DPF technologies have been developed and integrated into a common simulation environment called ExACT (Exhaust After-treatment Components Toolbox). This publication focuses on a model for the NOx storage and reduction catalyst as a part of that simulation environment. A heterogeneous, spatially one-dimensional (1D), physically and chemically based mathematical model of the catalytic monolith has been developed. A global reaction kinetic approach has been chosen to describe reaction conversions on the washcoat. Reaction kinetic parameters have been evaluated from a series of laboratory experiments.

External Exhaust Gas Recirculation, EGR, is a central issue in controlling emissions in up-to-date diesel engines. An empirical model has been developed that calculates the EGR ratio as a function of the engine speed, the engine load and special characteristics of the heat release rate. It was found that three combustion characteristics correlate well with the EGR ratio. These characteristics are the ignition delay, the premixed combustion ratio and the mixing-controlled combustion ratio. The calculation of these characteristics is based on parameter subsets, which were determined using an optimization routine. The model presented was developed based on these optimized characteristics.

The NO distribution in a directly-injected Diesel engine with realistic combustion chamber geometry was investigated with laser-induced fluorescence (LIF) imaging with KrF excimer laser excitation. The highest possible level of selectivity has been ensured using spectrally resolved LIF investigations inside the Diesel engine. To minimize interference from both, oxygen and polycyclic aromatic hydrocarbon (PAH) LIF the NO signal was detected around 237 nm, blue-shifted compared to the excitation wavelength resulting in a background contribution below 10% at the earliest detection timing possible in the engine under study (20°ca after top dead center, TDC). The in-cylinder NO LIF intensities were compared for different injection systems and operating conditions and correlated to variations in pressure traces and soot temperature measurements.

In view of limited crude oil resources, alternative fuels for internal combustion engines are currently being intensively researched. Synthetic fuels from natural gas offer a promising interim option before the development of CO2-neutral fuels. Up to a certain degree, these fuels can be tailored to the demands of modern engines, thus allowing a concurrent optimization of both the engine and the fuel. This paper summarizes investigations of a Gas-To-Liquid (GTL) diesel fuel in a modern, post-EURO 4 compliant diesel engine. The focus of the investigations was on power output, emissions performance and fuel economy, as well as acoustic performance, in comparison to a commercial EU diesel fuel. The engine investigations were accompanied by injection laboratory studies in order to assist in the performance analyses.

The improvement of DI diesel engines for passenger cars to fulfil pollutant emission limits and lower fuel consumption and noise is closely linked to continued development of the injection system. Today's injection systems demonstrate varying potential in terms of the flexibility of injection parameters for improving mixture formation and combustion. DaimlerChrysler evaluated the potential of different injection systems, looking particularly at the distributor pump, unit injection system and Common Rail system. Based on the results of these investigations, the Common Rail system was selected. The tests presented in this paper were performed on a single-cylinder engine with Common Rail system. They focused on increased rail pressure in combination with different nozzle geometries. The results show significant benefits in NOx/smoke trade off at part load conditions with high EGR rate.

In order to fulfill future emissions standards, there is a need for new exhaust-gas aftertreatment concepts, with NOx-emissions reduction in passenger car diesel engines being of particular importance. The NOx storage catalyst is one of the technologies currently under discussion with high NOx conversion potential, and which is under development at DaimlerChrysler for EURO IV standards. With this system, the nitrogen oxides contained in the diesel exhaust gas are stored under lean exhaust-gas conditions and are reduced in the catalyst through an enriched air-fuel ratio of the exhaust-gas and favorable thermal conditions. Hydrocarbons, carbon monoxide and hydrogen are used as reducing agents. DaimlerChrysler has analyzed the effect of sulphur contained in the fuel on the operation of various catalysts during laboratory and engine testing. The sulphur dioxide in the exhaust gas generates sulfates, which remain on the catalyst when nitrate compounds are regenerated briefly.

The influence of adsorption and desorption processes on the non-thermal plasma enhanced catalytic reduction of NOx on NaZSM5- and Al2O3-based lean-NOx catalysts (Pt-NH4ZSM5, Cu-NaZSM5, Fe-NaZSM5, Pt-Al2O3, Pd-Al2O3, CuO-Al2O3, Ag-Al2O3) was investigated by temperature programmed reaction experiments in the temperature range from 100 °C to 600 °C. Dodecane was used as a reducing agent. Strong HC adsorption- and desorption effects were observed on the zeolite catalysts, which were not influenced by plasma-pretreatment. Adsorption of NO2 and desorption of NO occurred on Al2O3-based catalysts. By plasma-pretreatment adsorption of NO2 was induced at low temperatures. NOx-reduction rates of the catalysts Cu-NaZSM5, Fe-NaZSM5, and the Ag-Al2O3 were increased substantially by plasma-pretreatment. Both plasma-induced and catalytic oxidation of HCs were limiting factors of the NOx-reduction obtained on these catalysts.

The paper describes results from investigating Common Rail (CR) injection in a dedicated optical engine with optimum access to the whole cross section of the engine cylinder through piston. This engine maintains all production-type details of the combustion chamber geometry being crucial to the flow fields required for optimum engine performance. This optical engine is used along with 2D optical diagnostics for temperature, soot and OH as well as spray shadowgraphy to analyze all phases of injection and combustion under virtually real engine conditions. By using special prototype CR injectors, the effects of engine design and operation strategies on ignition, combustion and pollutant formation are studied and controlling parameters are isolated. Special emphasis is devoted to the effects of injector stability, spray symmetry, nozzle geometry, injection rate, pilot injection and swirl effects.

This paper addresses the use of neat, indigenous biodiesel in advanced Mercedes-Benz passenger cars. Modern, unmodified EU3 Common-Rail diesel engines with second generation common rail technology were used to determine the effects of neat biodiesel on performance and emission characteristics. The biodiesel was made from the seeds of the Jatropha Curcas plant and sourced from the Central Salt and Marine Chemicals Research Institute in Bhavnagar, India. The production of biodiesel and the vehicle tests are part of a PPP project, funded jointly by the DaimlerChrysler AG and the German DEG. The project aims at providing additional jobs and income in rural Indian areas along with reclaiming unused wasteland. The test vehicles were operated for a cumulative 8000 kilometers with an intention to expose the vehicle and fuel to diverse climatic conditions.

A numerical model describing the ammonia based SCR process of NOX on zeolite catalysts is presented. The model is able to simulate coated and extruded monoliths. The development of the reaction kinetics is based on a study which compares the activity of zeolite and vanadium based catalysts. This study was conducted in a microreactor loaded with washcoat powder and with crushed coated monoliths. A model for the SCR reaction kinetics on zeolite catalysts is presented. After the parameterization of the reaction mechanism the reaction kinetics were coupled with models for heat and mass transport. The model is validated with laboratory data and engine test bench measurement data over washcoated monolith catalysts. A numerical simulation study is presented, aiming to reveal the differences between zeolite and vanadium based SCR catalysts.

A 1D+1D numerical model describing the ammonia based SCR process of NO and NO2 on vanadia-titania catalysts is presented. The model is able to simulate coated and extruded monoliths. Basing on a fundamental investigation of the catalytic processes a reaction mechanism for the NO/NO2 - NH3 reacting system is proposed and modeled. After the parameterization of the reaction mechanism the reaction kinetics have been coupled with models for heat and mass transport. Model validation has been performed with engine test bench experiments. Finally the model has been applied to study the influence of NO2 on SCR efficiency within ETC and ESC testcycles, Additional simulations have been conducted to identify the potential for catalyst volume reduction if NO2 is present in the inlet feed.

A two-dimensional numerical model describing the ammonia based SCR-process on vanadia-titania catalysts is presented. The model is able to simulate coated and extruded monoliths. For the determination of the intrinsic kinetics of the various NH3-NOx reactions, unsteady microreactor experiments were used. In order to account for the influence of transport effects the kinetics were coupled with a fully transient two-phase 1D+1D monolith channel model. The model has been validated extensively with laboratory data and engine test bench measurements. After validation the model has been applied to calculate catalyst NOx conversion maps, which were used to define catalyst sizes. Additional simulations were conducted studying the influence of cell density and NH3-dosage ratio.

The current is an investigation of the effects of charge motion, namely tumble, on the burn characteristics of the new Chrysler Hemi SI engine. In order to reduce prototyping, several combustion system designs were evaluated; some of which were eliminated prior to design inception solely based on CFD simulations. The effects of piston top and number of spark plugs were studied throughout the conceptual stage with the AVL-FIRE CFD code. It has been concluded that large-scale, persistent and coherent tumbling flow structures are essential to charge motion augmentation at ignition only if such structures are decimated right before ignition. Piston top had a detrimental effect on tumbling charge motion as the piston approaches the TDC. When compared to single spark plug operation, dual spark plug reflected considerable improvement on burn characteristics and engine performance as a consequence. The CFD simulations demonstrated good correlation with early dynamometer data.