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“Gas-to-liquids” catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude-derived fuels. Methylal (CH3-O-CH2-O-CH3), also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins B5.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions.

The objective of this study was to quantify the effect of pilot fuel injection on engine-out emissions of potentially toxic compounds from a modern diesel engine operated with different fuels including 15% v/v dimethoxy methane in a low-sulfur diesel fuel. Five diesel fuels were examined: a low-sulfur (∼1 ppm), low aromatic, hydrocracked fuel, the same low-sulfur fuel containing 15% v/v dimethoxy methane, a Fischer-Tropsch fuel, a California reformulated fuel, and a EPA number 2 certification fuel. A DaimlerChrysler OM611 CIDI engine was controlled with a SwRI Rapid Prototyping Electronic Control system. The pilot fuel injection was either turned off or turned on with engine control by either Location of Peak Pressure (LPP) of combustion or the original equipment manufacturer (OEM) calibration strategy. These three control strategies were compared over 2 speed-load modes run in triplicate. Thirty-three potentially toxic compounds were measured.

A menu-driven, PC-based model, ALAMO_ENGINE, has been developed to predict the nitrogen oxides (NOx) reductions in direct-injected, diesel engines due to exhaust gas recirculation (EGR), emulsified fuels, manifold or in-cylinder water injection, fuel injection timing changes, humidity effects, and intake air temperature changes. The approach was to use a diesel engine cycle simulation with detailed gas composition calculations for the intake and exhaust gases (including EGR, water concentration, fuel-type effects, etc.), coupled with a code to calculate stoichiometric, adiabatic flame temperatures and expressions that correlate measured NOx emissions with the flame temperature. Execution times are less than 10 seconds on a 486-66 MHz PC.