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The use of advanced electron microscopy techniques to characterize both the bulk and near-atomic level microstructural evolution of catalyst materials during different dynamometer/vehicle aging cycles is an integral part of understanding catalyst deactivation. The study described here was undertaken to evaluate thermally-induced microstructural changes which caused the progressive loss of catalyst performance in a three-way automotive catalyst. Several different catalyst processing variables, for example changing the washcoat ceria content, were also evaluated as a function of aging cycle and thermal history. A number of thermally-induced microstructural changes were identified using high resolution electron microscopy techniques that contributed to the deactivation of the catalyst, including sintering of all washcoat constituents, γ-alumina transforming to α-, β-, and δ-alumina, precious metal redistribution, and constituent encapsulation.

This paper presents a simplified thermal model for round catalytic converters in steady state operation. Using this model, the analytic solution for the temperature distribution in the monolithic substrate is obtained. This analytic solution in the substrate is, then, combined with those in the intumescent mat [1] and the metal shell to obtain the temperature profile in the radial direction of the converter except for three unknown temperatures at the three material interfaces, which can be solved using an Excel application program. This analytical temperature solution facilitates the studies of the effects of various design parameters such as the exhaust gas temperature, exhaust gas flow rate, substrate cell geometry, converter dimensions, and ambient temperature and flow, etc.

Accurately predicting converter assembly deformation and mat pressure is essential in converter packaging design and manufacturing. In stuffing packaging, the annulus between the deformed shell and the catalyst is larger than that between the stuffing cone and the catalyst. As a result, the mat expands and undergoes unloading process. Tests show that the mat exhibits different loading and unloading characteristics. Using such a hysteresis mat pressure vs density curve in finite element analysis, the computed converter deformations closely agree with test data. Conversly, neglecting the mat hysteresis behavior may overestimate the deformation and pressure by a factor of three to four.

Delphi Automotive Systems and BMW are jointly developing Solid Oxide Fuel Cell (SOFC) technology for application in the transportation industry primarily as an on-board Auxiliary Power Unit (APU). In the first application of this joint program, the APU will be used to power an electric air conditioning system without the need for operating the vehicle engine. The SOFC based APU technology has the potential to provide a paradigm shift in the supply of electric power for passenger cars. Furthermore, by supplementing the conventional fuel with reformate in the internal combustion engine, extremely low emissions and high system efficiencies are possible. This is consistent with the increasing power demands in automobiles in the new era of more comfort and safety along with environmental friendliness. Delphi Automotive Systems and BMW were successful in demonstrating an Auxiliary Power Unit (APU) based on Solid Oxide Fuel Cell (SOFC) technology in February, 2001.

Onboard diagnostic regulations require performance monitoring of diesel particulate filters used in vehicle aftertreatment systems. Delphi has developed a particulate matter (PM) sensor to perform this function. The objective of this sensor is to monitor the soot (PM) concentration in the exhaust downstream of the diesel particulate filter which provides a means to calculate filter efficiency. The particulate matter sensor monitors the deposition of soot on its internal sensing element by measuring the resistance of the deposit. Correlations are established between the soot resistance and soot mass deposited on the sensing element. Currently, the sensor provides the time interval between sensor regeneration cycles, which, with the knowledge of the exhaust gas flow parameters, is correlated to the average soot concentration.

Tomorrow's winning powertrain solutions reside in those technology combinations providing optimized propulsion systems with zero emissions and no cost or performance penalty compared with today's vehicles. The recent Kyoto Protocol for CO2 reduction and the California Air Resources Board (CARB) thrust for zero emission vehicles along with the European Regulatory community, motivate car manufacturers to adopt new light body structures with low aerodynamic drag coefficients, low-rolling resistance and the highest efficiency powertrains. The environmental equation expresses car manufacturers aptitude and desire to create zero emission vehicles at acceptable levels of performance unlike limited range electrical powered vehicle products. The cheapest solution to the environmental equation remains the conventional internal combustion engine ($30 to $50 per kW).

Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.

Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) are effective emission solutions for both close-coupled and underfloor LEV/ULEV applications due to optimal hydrocarbon light-off, NOx control, and balance of precious metal (PGM) usage. Dual-brick [Pd +Pt/Rh] systems on 3.8L V-6 LEV-calibrated vehicles were characterized as a function of PGM loading, catalyst technology, converter volumes, and substrate cell density. While hydrocarbon emissions improve with increasing Pd loading, decreasing the front catalyst volume at constant Pd content (resulting in higher Pd density) improved light-off emissions. Use of 600cpsi substrates improved underfloor NMHC emissions on a 3.8L vehicle by ∼ 6-10mg/mi compared to 400cpsi catalysts, and thus allowing reduction of catalyst volume while achieving ULEV emission levels without air addition.

Optimization of the mechanical aspects of a heated conical oxygen sensor for desired performances, such as low heater power, good poison resistance, fast light-off, and broad temperature range, etc. was achieved with computer modeling. CFD analysis was used to model the flow field in and around a sensor in an exhaust pipe to predict the convection coefficients, poisoning, and switching time. Heat transfer analysis coupled with electrical heating was applied to predict temperature and light-off time. Results of the optimization are illustrated, with good agreements between modeling and testing.

Mean Value Engine Models (MVEMs) are simplified, dynamic engine models which are physically based. Such models are useful for control studies, for engine control system analysis and for model based engine control systems. Very few published MVEMs have included the effects of Exhaust Gas Recirculation (EGR). The purpose of this paper is to present a modified MVEM which includes EGR in a physical way. It has been tested using newly developed, very fast manifold pressure, manifold temperature, port and EGR mass flow sensors. Reasonable agreement has been obtained on an experiemental engine, mounted on a dynamometer.

The electric power required in automotive systems is quickly reaching a level that significantly impacts costs and fuel consumption. This drives the need to reconsider an electric energy management function. Fast evolving factors such as increasing power usage, and stricter engine management and reliability requirements necessitate a global vehicle approach to energy management. Innovations such as new powernet concepts (42 volt or dual voltage systems), new component technologies (high-performance energy storage, high efficiency and controllable generators), and global electronic and software architecture concepts will enable this new energy management concept. This paper describes key issues to maximize energy availability with reasonable components.

In this paper we discuss in detail an algorithm that addresses cylinder-to-cylinder imbalance issues. Maintaining even equivalence-ratio (ϕ) control across all the cylinders of an engine is confounded by imbalances which include fuel-injector flow variations, fresh-air intake maldistribution and uneven distribution of Exhaust Gas Re-circulation (EGR). Moreover, in markets that are growing increasingly cost conscious, with ever tightening emissions regulations, correcting for such mismatches must not only be done, but done at little or no additional cost. To address this challenge, we developed an Individual Cylinder Fuel Control (ICFC) algorithm that estimates each cylinder's individual ϕ and then compensates to correct for any imbalance using only existing production hardware. Prior work in this area exists1,2, yet all disclosed production-intent work was performed using wide-range oxygen sensors, representing cost increases.

Performance of two types of NOx adsorber catalysts, one based on Ba and the other based on Ba with alkali metals, was compared fresh and after thermal aging. Incorporation of sodium(Na), potassium(K) and cesium(Cs) into NOx adsorber washcoat containing barium significantly increases the NOx conversions in the temperature range of 350-600°C over that of the alkali metal free NOx adsorber catalysts. NOx performance benefit and HC performance penalty were observed on both engine dynamometer and vehicle tests for the “Ba+alkali metals” NOx adsorber catalysts. “Ba+alkali metals” NOx adsorber catalysts also demonstrate superior sulfur resistance with better NOx performance after repeated sulfur poisonings and desulfations over the “Ba based” NOx adsorber catalysts.

Most large automobile manufacturers are considering adding hybrid electric vehicles (HEV) to their product portfolio for environmental reasons. Some, like Toyota, Nissan and Honda, have already begun producing or have plans for producing hybrids. Skeptics in the industry see these efforts as mostly intended to enhance the automaker's environmental image at a cost that is not recoverable in the marketplace. Few in the automotive industry claim a sound economic basis for hybrids, and furthermore are repelled by the disruption of existing systems they promise. To test the validity of the industry's generally negative view of HEV economics, this paper establishes a logical, mission-based classification for HEV system architecture and performs a present value analysis for the three classes.

This paper describes recent progress in our program to develop a gasoline-fueled vehicle with an on-board reformer to provide near-zero tailpipe emissions. An on-board reformer converts gasoline (or another hydrocarbon-containing fuel) into reformate, containing hydrogen (H2) and carbon monoxide (CO). Reformate has very wide combustion limits to enable SI engine operation under very dilute conditions (either ultra-lean or with heavy exhaust gas recirculation (EGR) concentrations). In previous publications, we have presented engine dynamometer results showing very low emissions with bottled reformate. This paper shows results from an engine linked to an experimental, fast start-up reformer. We present both performance data for the reformer as well as engine emissions and performance results. Program results continue to show an on-board reforming system to be an attractive option for providing near-zero tailpipe emissions to meet low emission standards.

With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.

This paper summarizes the results of an investigation of high risk, high potential technologies for hybrid vehicle drive applications and investigate potential solutions for the technical risk items associated with these technologies. The study consisted of the design, build, and test of different types of electric machines to understand their performance, efficiency, and manufacturability to develop hybrid vehicles with cost and performance similar to the present day IC engine based vehicles, but with lower emissions and better fuel economy. Machine technologies examined include synchronous reluctance, permanent magnet, and switched reluctance. Test data for various machine technologies is presented along with a discussion of the technical risk associated with each technology.

Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system.

In vehicular mobility context, it is extremely important for the environmental sustainability that the available energy will be used as efficiently as possible, both in the use of internal combustion engines (ICE) as powertrain, as well in the application of Hybrid and Electric Vehicle Motors (HEV/EV). In this comparison, ICE has a lower efficiency when compared to electric motors, wasting much of the potential energy of the fuel in form of heat and noise. On the other hand, the electric vehicles face limitation in autonomy and recharge time, demanding for a more efficient use of energy stored in batteries. This study aims to present emerging technologies for reuse of energy within the automotive context, originally known as “Energy Harvesting” and “Renewable Energies”.

Engine tests were conducted to study the effect of fuel-air mixture preparation on the combustion and emission performance of a two-stroke direct-injection engine. The in-cylinder mixture distribution was altered by changing the injection system, injection timing, and by substituting the air in an air-assisted injector with nitrogen. Two injection systems which produce significantly different mixtures were investigated; an air-assisted injector with a highly atomized spray, and a single-fluid high pressure-swirl injector with a dense penetrating spray. The engine was operated at overall A/F ratios of 30:1, where stratification was necessary to ensure stable combustion; and at 20:1 and 15:1 where it was possible to operate in a nearly homogeneous mode. Moderate engine speeds and loads were investigated. The effects of the burning-zone A/F ratio were isolated by using nitrogen as the working fluid in the air-assist injector.