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Second generation biomass is an attractive renewable feedstock for transport fuels. Its sulfur content is generally negligible and the carbon cycle is reduced from millions to tens of years. One hitherto non-valorized feedstock are so-called humins, a residual product formed in the conversion of sugars to platform chemicals, such as hydroxymethylfurfural and methoxymethylfurfural, intermediates in the production of FDCA, a building block used to produce the polyethylene furanoate (PEF) bottle by Avantium. The focus of this study is to investigate the spray combustion behavior of humins as a renewable alternative for heavy fuel oil (HFO) under large two-stroke engine-like conditions in an optically accessible constant volume chamber.

The LEV/ULEV emission standards pose challenging problems on automotive exhaust gas treatment. This increases the need for good catalytic converter models, which can be applied for control. A dynamic converter model was made on the basis of first principles, accounting for the accumulation of mass in the bulk gas phase, in pores of the washcoat and on the catalytic surface, as well as for the energy accumulation in the gas and solid phase. The basis for the model is the elementary step kinetics of the individual global reactions. The main purpose of the model is to describe the low temperature behavior of the converter, when the majority of the emissions occur. The light-off process is analyzed in detail with different inputs. The biggest improvement occurs when secondary air is injected in front of the converter. The converter model is also coupled with a simple SI engine model to investigate the dynamic behavior of the whole system.

Diesel spray mixture formation is investigated at target conditions using multiple diagnostics and laboratories. High-speed Particle Image Velocimetry (PIV) is used to measure the velocity field inside and outside the jet simultaneously with a new frame straddling synchronization scheme. The PIV measurements are carried out in the Engine Combustion Network Spray A target conditions, enabling direct comparisons with mixture fraction measurements previously performed in the same conditions, and forming a unique database at diesel conditions. A 1D spray model, based upon mass and momentum exchange between axial control volumes and near-Gaussian velocity and mixture fraction profiles is evaluated against the data.

The modeling of fuel sprays under well-characterized conditions relevant for heavy-duty Diesel engine applications, allows for detailed analyses of individual phenomena aimed at improving emission formation and fuel consumption. However, the complexity of a reacting fuel spray under heavy-duty conditions currently prohibits direct simulation. Using a systematic approach, we extrapolate available spray models to the desired conditions without inclusion of chemical reactions. For validation, experimental techniques are utilized to characterize inert sprays of n-dodecane in a high-pressure, high-temperature (900 K) constant volume vessel with full optical access. The liquid fuel spray is studied using high-speed diffused back-illumination for conditions with different densities (22.8 and 40 kg/m3) and injection pressures (150, 80 and 160 MPa), using a 0.205-mm orifice diameter nozzle.

Existing gasoline DI injection equipment has been modified to generate single hole pulsed gas jets. Injection experiments have been performed at combinations of 3 different pressure ratios (2 of which supercritical) respectively 3 different hole geometries (i.e. length to diameter ratios). Injection was into a pressure chamber with optical access. Injection pressures and injector hole geometry were selected to be representative of current and near-future DI natural gas engines. Each injector hole design has been characterized by measuring its discharge coefficient for different Re-levels. Transient jets produced by these injectors have been visualized using planar laser sheet Mie scattering (PLMS). For this the injected gas was seeded with small oil droplets. The corresponding flow field was measured using particle image velocimetry (PIV) laser diagnostics.

This paper first compares strengths and weaknesses of different options for performing optical diagnostics on HD diesel sprays. Then, practical experiences are described with the design and operation of a constant volume test cell over a period of more than five years. In this test rig, pre-combustion of a lean gas mixture is used to generate realistic gas mixture conditions prior to fuel injection. Spray growth, vaporization are studied using Schlieren and Mie scattering experiments. The Schlieren set-up is also used for registration of light emitted by the combustion process; this can also provide information on ignition delay and on soot lift-off length. The paper further describes difficulties encountered with image processing and suggests methods on how to deal with them.

Partially Premixed Combustion has shown the potential of high efficiency, emissions of nitrogen oxides (NOx) and soot below future emissions regulations, and acceptable acoustic noise. Low-octane-number gasoline fuels were shown to be most suitable for this concept, with the reactivity determining the possible load range. Other researchers have used several refinery streams, which might be produced by a refinery if they were required to do so without additional investment. Some of refinery streams are, however, not expected to be commercially available on the short term. For the present investigation, n-butanol (BuOH) has been selected as a blend component in diesel, and is used from 50 - 100%. The blends then have a reactivity range similar to the refinery streams, so single-cylinder engine tests for their emission and efficiency performance can also be used to determine their applicable load range.

In-cylinder visualization, combustion stratification, and engine-out particulate matter (PM) emissions were investigated in an optical engine fueled with Haltermann straight-run naphtha fuel and corresponding surrogate fuel. The combustion mode was transited from homogeneous charge compression ignition (HCCI) to conventional compression ignition (CI) via partially premixed combustion (PPC). Single injection strategy with the change of start of injection (SOI) from early to late injections was employed. The high-speed color camera was used to capture the in-cylinder combustion images. The combustion stratification was analyzed based on the natural luminosity of the combustion images. The regulated emission of unburned hydrocarbon (UHC), carbon monoxide (CO) and nitrogen oxides (NOX) were measured to evaluate the combustion efficiency together with the in-cylinder rate of heat release.