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The present work is a continuation of the earlier published results by authors on the investigation of Hydrogenated Vegetable Oil (HVO) on a High Efficiency Diesel Combustion System (SAE Int. J. Fuels Lubr. Paper No. 2013-01-1677 and JSAE Paper No. 283-20145128). In order to further validate and interpret the previously published results of soot microstructure and its consequences on oxidation behavior, the test program was extended to analyze the impact of soot composition, optical properties, and physical properties such as size, concentration etc. on the oxidation behavior. The experiments were performed with pure HVO as well as with petroleum based diesel and today's biofuel (i.e. FAME) as baseline fuels. The soot samples for the different analyses were collected under constant engine operating conditions at indicated raw NOx emissions of Euro 6 level using closed loop combustion control methodology.

The current and future restrictions on pollutant emissions from internal combustion engines require a holistic investigation of the abilities of alternative fuels to optimize the combustion process and ensure cleaner combustion. In this regard, the Tailor-made Fuels from Biomass (TMFB) Cluster at Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen University aims at designing production processes for biofuels as well as fuels optimal for use in internal combustion engines. The TMFB Cluster's scientific approach considers the molecular structure of the fuels as an additional degree of freedom for the optimization of both the production pathways and the combustion process of such novel biofuels. Thus, the model-based specification of target parameters is of the utmost importance to improve engine combustion performance and to send feedback information to the biofuel production process.

In this work, a transport and mixing model that calculates mixing in thermodynamic phase space was derived and validated. The mixing in thermodynamic multizone space is consistent to the one in the spatially resolved physical space. The model is developed using a turbulent channel flow as simplified domain. This physical domain of a direct numerical simulation (DNS) is divided into zones based on the quantitative value of transported scalars. Fluxes between the zones are introduced to describe mixing from the transport equation of the probability density function based on the mixing process in physical space. The mixing process of further scalars can then be carried out with these fluxes instead of solving additional transport equations. The relationship between the exchange flux in phase space and the concept of scalar dissipation are shown and validated by comparison to DNS results.

Within a project of the Research Association for Combustion Engines e.V., different measures for rising the temperature of exhaust gas aftertreatment components of both a passenger car and an industrial/commercial vehicle engine were investigated on a test bench as well as in simulation. With the passenger car diesel engine and different catalyst configurations, the potential of internal and external heating measures was evaluated. The configuration consisting of a NOx storage catalyst (NSC) and a diesel particulate filter (DPF) illustrates the potential of an electrically heated NSC. The exhaust aftertreatment system consisting of a diesel oxidation catalyst (DOC) and a DPF shows in simulation how variable valve timing in combination with electric heated DOC can be used to increase the exhaust gas temperature and thus fulfill the EU6 emission limits.

To comply with the new regulations on particulate matter emissions, the manufacturers of light-duty as well as heavy-duty vehicles more commonly use diesel particulate filters (DPF). The regeneration of DPF depends to a significant extent on the properties of the soot stored. Within the Cluster of Excellence "Tailor-Made Fuels from Biomass (TMFB)" at RWTH Aachen University, the Institute for Combustion Engines carried out a detailed investigation program to explore the potential of future biofuel candidates for optimized combustion systems. The experiments for particulate measurements and analysis were conducted on a EURO 6-compliant High Efficiency Diesel Combustion System (HECS) with petroleum-based diesel fuel as reference and a today's commercial biofuel (i.e., FAME) as well as a potential future biomass-derived fuel candidate (i.e., 2-MTHF/DBE). Thermo gravimetric analyzer (TGA) was used in this study to evaluate the oxidative reactivity of the soot.

Liquefied Petroleum Gas direct injection (LPG DI) is believed to be the key enabler for the adaption of modern downsized gasoline engines to the usage of LPG, since LPG DI avoids the significant low end torque drop, which goes along with the application of conventional LPG port fuel injection systems to downsized gasoline DI engines, and provides higher combustion efficiencies. However, especially the high vapor pressure of C3 hydrocarbons can result in hot fuel handling issues as evaporation or even in reaching the supercritical state of LPG upstream or inside the high pressure pump (HPP). This is particularly critical under hot soak conditions. As a result of a rapid fuel density drop close to the supercritical point, the HPP is not able to keep the rail pressure constant and the engine stalls.

Due to their CO2 reduction potential and their high knock resistance gaseous fuels present a promising alternative for modern highly boosted spark ignition engines. Especially the direct injection of LPG reveals significant advantages. Previous studies have already shown the highest thermodynamic potential for the LPG direct injection concept and its advantages in comparison to external mixture formation systems. In the performed research study a comparison of different LPG fuels in direct injection mode shows that LPG fuels have better auto-ignition behavior than gasoline. A correlation between auto-ignition behavior and the calculated motor octane number could not be found. However, a significantly higher correlation of R2 = 0.88 - 0.99 for CR13 could be seen when using the methane number. One major challenge in order to implement the LPG direct injection concept is to ensure the liquid state of the fuel under all engine operating conditions.

Model-based control strategies along with an adapted calibration process become more important in the overall vehicle development process. The main drivers for this development trend are increasing numbers of vehicle variants and more complex engine hardware, which is required to fulfill the more and more stringent emission legislation and fuel consumption norms. Upcoming fundamental changes in the homologation process with EU 6c, covering an extended range of different operational and ambient conditions, are suspected to intensify this trend. One main reason for the increased calibration effort is the use of various complex aftertreatment technologies amongst different vehicle applications, requiring numerous combustion modes. The different combustion modes range from heating strategies for active Diesel Particulate Filter (DPF) regeneration or early SCR light-off and rich combustion modes to purge the NOx storage catalyst (NSC) up to partially premixed combustion modes.

This study investigated dual-fuel operation with a light duty Diesel engine over a wide engine load range. Ethanol was hereby injected into the intake duct, while Diesel was injected directly into the cylinder. At low loads, high ethanol shares are critical in terms of combustion stability and emissions of unburnt hydrocarbons. As the load increases, the rates of heat release become problematic with regard to noise and mechanical stress. At higher loads, an advanced injection of Diesel was found to be beneficial in terms of combustion noise and emissions. For all tests, engine-out NOx emissions were kept within the EU-6.1 limit.

Using a holistic 1D engine simulation approach for the modelling of full-transient engine operation, allows analyzing future engine concepts, including its exhaust gas aftertreatment technology, early in the development process. Thus, this approach enables the investigation of both important fields - the thermodynamic engine process and the aftertreatment system, together with their interaction in a single simulation environment. Regarding the aftertreatment system, the kinetic reaction behavior of state-of-the-art and advanced components, such as Diesel Oxidation Catalysts (DOC) or Selective Catalytic Reduction Soot Filters (SCRF), is being modelled. Furthermore, the authors present the use of the 1D engine and exhaust gas aftertreatment model on use cases of variable valve train (VVT) applications on passenger car (PC) diesel engines.