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Diesel NOx emissions control utilizing combined Lean NOx Trap (LNT) and so-called passive or in-situ Selective Catalytic Reduction (SCR) catalyst technologies (i.e. with reductant species generated by the LNT) has been the subject of several previous papers from our laboratory [ 1 - 2 ]. The present study focuses on hydrocarbon (HC) emissions control via the same LNT+SCR catalyst technology under FTP driving conditions. HC emissions control can be as challenging as NOx control under both current and future federal and California/Green State emission standards. However, as with NOx control, the combined LNT+SCR approach offers advantages for HC emission control over LNT-only aftertreatment. The incremental conversion obtained with the SCR catalyst is shown, both on the basis of vehicle and laboratory tests, to result primarily from HC adsorbed on the SCR catalyst during rich LNT purges that reacts during subsequent lean engine operation.

A detailed study is undertaken to examine how 2010+ diesel engine exhaust emissions change when a soybean-derived B20 biodiesel fuel is used instead of a conventional ultra-low sulfur diesel fuel and to investigate how these changes impact the aftertreatment system. Particulate matter (PM) emissions for each fuel are characterized in terms of mass emissions, size distributions, organic versus soot fraction, metals content, and particle morphology. PM mass recorded by Dekati Mass Monitor, thermal analysis of quartz filters, and calculated from particle size distributions consistently shows a 2 - 3 fold decrease in engine-out soot emissions over a wide mid-load range when changing from ULSD to B20 fuel. This is partly due to a decrease in particle number and partly to a decrease in average size. HC and NO emissions, in contrast, exhibit little change with fuel type.

New emissions certification requirements for medium duty vehicles (MDV) meeting chassis dynamometer regulations in the 8,500 lb to 14,000 lb weight classes as well as heavy duty (HD) engine dynamometer certified applications in both the under 14,000 lb and over 14,000 lb weight classes employing large diameter exhaust pipes (up to 4″) have created new exhaust stream sampling concerns. Current On-Board-Diagnostic (OBD) dyno certified particulate matter (PM) requirements were/are 7x the standard for 2010-2012 applications with a planned phase in down to 3x the standard by 2017. Chassis certified applications undergo a similar reduction down to 1.75x the standard for 2017 model year (MY) applications. Failure detection of a Diesel Particulate Filter (DPF) at these low detection limits facilitates the need for a particulate matter sensor.

Emissions sample probes are widely used in engine and vehicle emissions development testing. Tailpipe bag summary data is used for certification, but the time-resolved (or modal) emissions data at various points along the exhaust system is extremely important in the emission control technology development process. Exhaust gas samples need to be collected at various locations along the exhaust aftertreatment system. Typically, a tube with a small diameter is inserted inside the exhaust pipe to avoid any significant effect on flow distribution. The emissions test equipment draws a gas sample from the exhaust stream at a constant volumetric flow rate (typically around 10 SLPM). The sample probe tube delivers exhaust gas from the exhaust pipe to emissions test equipment through multiple holes on the surface of tube. There can be multiple rows of holes at different axial planes along the length of the sample probe as well as multiple holes on a given axial plane of the sample probe.