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The present study investigates the wave propagation and attenuation in catalytic converters. The relationships for wave propagation in a catalytic monolith are derived first and then coupled to the wave propagation in tapered ducts. Analytical predictions are compared with experimental results to validate the theory.

Intake and exhaust valve control has been combined with engine calibration control by an on-board computer to achieve a Variable Displacement Engine with improved BSFC during part throttle operation. The advent of the on-board computer, with its ability to provide integrated algorithms for the fast accurate flexible control of the entire powertrain, has allowed practical application of the valve disabler mechanism. The engine calibration basis and the displacement selection criteria are discussed, as are the fuel economy, emissions and behavior of a research vehicle on selected drive cycles ( Metro, Highway and Steady State ). Additionally, the impact upon vehicle driveability and other related subsystems ( e.g., transmission ) is addressed.

A series of tests were conducted to determine the potential for reducing vehicle underhood temperatures by either 1) diverting the radiator fan air flow from the engine compartment or 2) by forced air cooling of the exhaust manifold in conjunction with shielding it or 3) by a combination of the two methods. The test vehicle was a Ford F-250 Light Truck with a 7.5L V-8 engine. The vehicle was tested in a dynamometer cell equipped with cell blowers to simulate road speed conditions. It was found that diverting the outlet air from the radiator will reduce underhood component temperatures when the vehicle is in motion and also at normal idle. However, if the vehicle is to be used for power takeoff applications requiring a “kicked” idle, then forced cooling of the exhaust manifolds is also required to maintain reduced underhood temperatures. A combination of these two techniques maximized the reduction of underhood temperatures for all operating conditions tested.

Exhaust pressures (P3) are hard parameters to measure and can be readily estimated, the cost of the sensors and the temperature in the exhaust system makes the implementation of an exhaust pressure sensor in a vehicle control system a costly endeavor. The contention with measured P3 is the accuracy required for proper engine and vehicle control can sometimes exceed the accuracy specification of market available sensors and existing models. A turbine inlet exhaust pressure observer model based on isentropic expansion and heat transfer across a turbocharger turbine was developed and investigated in this paper. The model uses 4 main components; an open loop P3 orifice flow model, a model of isentropic expansion across the turbine, a turbine and pipe heat transfer models and an integrator with the deviation in the downstream turbine outlet parameter.

The objective of this study is to investigate the removal of methane (CH4), nitric oxide (NO), and carbon monoxide (CO) from simulated natural gas vehicle (NGV) exhaust over a palladium catalyst. The effects of changes in space velocity and natural gas sulfur (S) content were studied. The study suggests that the NGV has to be operated slightly rich of stoichiometry to achieve simultaneous removal of the three constituents. The CH4 conversion decreases with an increase in the space velocity. The CO and NO conversions remain unaffected over the space velocity range (10,000 hr-1 to 100,000 hr-1) investigated. The presence of sulfur dioxide in the exhaust lowers the CH4 conversion and increases the CO conversion in the rich region. The NO conversion remains unaffected. Studies were conducted over model catalysts to investigate the modes of CH4 removal from the simulated NGV exhaust.

Speciated HC emissions from the exhaust system of a production engine without an active catalyst have been obtained with 3 sec time resolution during a 70°F cold start using two control strategies. For the conventional cold start, the emissions were initially enriched in light fuel alkanes and depleted in heavy aromatic species. The light alkanes fell rapidly while the lower vapor pressure aromatics increased over a period of 50 sec. These results indicate early retention of low vapor pressure fuel components in the intake manifold and exhaust system. Loss of higher molecular weight HC species does occur in the exhaust system as shown by experiments in which the exhaust system was preheated to 100° C. The atmospheric reactivity of the exhaust HC emissions for photochemical smog formation increases as the engine warms.

The recent development of TiAl-based alloys by the aerospace community has provided an excellent material alternative for hot components in automotive engines. The low density combined with an elevated temperature strength similar to that of Ni-base superalloys make TiAl-based alloys very attractive for exhaust valve applications. Lighter weight valvetrain components improve performance and permit the use of lower valve spring loads which reduce noise and friction and enhance fuel economy. However, difficult fabricability and a perception that TiAl alloys are high cost, low volume aerospace materials must be overcome in order to permit consideration for use in high-volume automotive applications. This paper provides a comparison of properties for several exhaust valve alternative materials. The density of TiAl alloys is lower than Ti alloys with creep and fatigue properties equivalent to IN-751, a current high performance exhaust valve material.

Carbon dioxide (CO2)-based refrigeration systems have been proposed as environmentally benign alternatives to current automotive air conditioners. The CO2 vapor-compression system requires very high operating pressures and complicated control strategies. Recent experimental results indicate that operating pressures comparable to those of current automotive air conditioners can be attained by the inclusion of a secondary carrier fluid (a “co-fluid”), with solution and desolution of the CO2 from the co-fluid substituting for condensation and vaporization of pure CO2. In this work, modeling tools have been developed to optimize the CO2/co-fluid cycle, including the selection of a co-fluid, the CO2/co-fluid ratio (the “loading”), and the operating conditions.

Thermal reactor systems have been designed to assist in the development of a low emission concept vehicle to meet exhaust emission goals of 0.82 gm/mile hydrocarbon, 7.1 gm/mile carbon monoxide, and 0.68 gm/mile nitrogen oxides established by the Inter-Industry Emission Control (IIEC) Program. The reactor includes design features required for acceptable life characteristics, together with the quick warm-up necessary to achieve the emission targets. Exhaust gas recirculation and enrichened carburetion are used to reduce the oxides of nitrogen. Associated problems defined during development of several thermal reactor systems are described. The primary problem was achieving durability at the typically high operating exhaust gas temperatures (1600-1800 F) necessary for concurrent HC, CO, and NOx control.

As the compliance with noise legislation became more difficult, Ford exhaust system development engineers increasingly encountered variances not only from vehicle-to-vehicle, but on the same vehicle tested in different locations. As a result, a series of tests were conducted to establish the correlation among various sites for vehicle exterior noise measurements. The purpose of this paper is to present the results and the method developed to achieve the correlation in terms of the following: 1. Ford and site equipment differences 2. Driver differences 3. Differences between site physical qualities Seven sites were evaluated in the program where seven vehicles were used with a good spread in exterior noise levels. A representative correlation plot is also presented which can be used to predict the expected noise level of any vehicle at any one of these test sites knowing the level obtained at the Ford site.

New European emissions legislation (Euro5) specifies a limit for Particle Number (PN) emissions and therefore drives measurement of PN during vehicle development and homologation. Concurrently, the use of biofuel is increasing in the marketplace, and Euro5 specifies that reference fuel must contain a bio-derived portion. Work was carried out to test the effect of fuels containing different levels of Fatty Acid Methyl Ester (FAME) on particle number, size, mass and composition. Measurements were conducted with a Cambustion Differential Mobility Spectrometer (DMS) to time-resolve sub-micron particles (5-1000nm), and a Horiba Solid Particle Counting System (SPCS) providing PN data from a Euro5-compliant measurement system. To ensure the findings are relevant to the modern automotive business, testing was carried out on a Euro4 compliant passenger car fitted with a high-pressure common-rail diesel engine and using standard homologation procedures.

A laboratory study was performed to assess the effects of sulfur poisoning and desulfation temperature on the NO conversion of a LNT+(Cu/SCR) in-situ system. Four LNT+(Cu/SCR) systems were aged for 4.5 hours without sulfur at 600, 700, 750, and 800°C using A/F ratio modulations to represent 23K miles of desulfations at different temperatures. NO conversion tests were performed on the LNT alone and on the LNT+SCR system using a 60 s lean/5 s rich cycle. The catalysts were then sulfur-poisoned at 400°C and desulfated four times and re-evaluated on the 60/5 tests. This test sequence was repeated 3 more times to represent 100K miles of desulfations. After simulating 23K miles of desulfations, the Cu-based SCR catalysts improved the NO conversion of the LNT at low temperatures (e.g., 300°C), although the benefit decreased as the desulfation temperature increased from 600°C to 800°C.

The variation in the decoupling effect of exhaust flexible couplings under a vertical preload caused by changes in the direction of the exhaust pipe routing was investigated. Both self-supporting and underbody flexible couplings were tested. The results indicate that, in general, a preload decreases the decoupling efficiency of both types of flexible couplings. In addition, the results indicate that the efficiency of the flexible coupling is effected by the following three conditions: the direction of preload with respect to gravity, the location of the preload relative to the coupling, and the stiffness of the various components of the flexible coupling.

Sound attenuation and flow loss reduction are often two competing demands in vehicle breathing systems. The present study considers a full vehicle exhaust system and investigates both the sound attenuation and the flow performance of production configurations including the catalyst, the resonator, and the muffler. Dynamometer experiments have been conducted with a firing Ford 3.0L, V-6 engine at wide-open throttle with speeds ranging from 1000 to 5000 rpm. Measurements including the flow rates, the temperatures and the absolute dynamic pressures of the hot exhaust gases at key locations (upstream and downstream of every component) with fast-response, water-cooled piezo-resistive pressure transducers facilitate the calculation of acoustic performance of each component, as well as the determination of flow losses caused by these elements and their influence on the engine performance.

Validation of the Ford General Engine SIMulation program (GESIM) with measured firing data from a modified single cylinder Ricardo HYDRA research engine is described. GESIM predictions for peak cylinder pressure and burn duration are compared to test results at idle operating conditions over a wide range of valve overlap. The calibration of GESIM was determined using data from only one representative world-wide operating point and left unchanged for the remainder of the study. Valve overlap was varied by as much as 36° from its base setting. In most cases, agreement between model and data was within the accuracy of the measurements. A cycle simulation computer model provides the researcher with an invaluable tool for acquiring insight into the thermodynamic and fluid mechanical processes occurring in the cylinder of an internal combustion engine.

An advanced diesel aftertreatment system utilizing Selective Catalytic Reduction (SCR) with urea for lean nitrogen oxides (NOx) control was tested on a 2.7L V6 Land Rover vehicle to demonstrate the capability of achieving Tier 2 Bin 5 and lower emission standards for light-duty trucks. SCR washcoat was applied to a diesel particulate filter (DPF) to perform NOx and particulate reduction simultaneously. Advanced SCR systems employed both traditional SCR catalysts and SCR-coated filters (SCRF) to improve the NOx reduction efficiency. The engine-out NOx level was adjusted by modifying the EGR (Exhaust Gas Recirculation) calibration. Cold start NOx performance was improved by SCR warm-up strategy and urea over injection. This study showed the advanced SCR system could tolerate higher NH₃ storage in the SCR catalyst, resulting in overall higher NOx conversion on the FTP-75 test cycle.

Lean NOx traps are being extensively examined (Ref. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 and 12) because they can be efficiently used to reduce the NOx emissions from port fuel injected and direct fuel injected spark ignited gasoline engines. A lean NOx trap (LNT) stores NOx during lean A/F engine operation. However, its storage capacity is limited and the LNT must be regenerated periodically by subjecting the LNT to momentary rich A/F operation for several seconds. The regeneration process releases the NOx that is chemically bonded to the washcoat and subsequently reduces it to N2 and O2. Fuel that contains a non-zero amount of sulfur will contaminate an LNT by significantly reducing its NOx storage capacity. Therefore, except for the case of a zero level of sulfur in the fuel, the LNT must be desulfated on a periodic basis. The desulfation process requires that the temperature of the LNT be raised to a temperature of about 650°C for several minutes.

Results of laboratory studies of the static characteristics of several different commercially available heated exhaust gas oxygen sensors are described. In these studies, the emf of the sensors was measured as a function of temperature and of the composition of calibrated gas mixtures. Several different binary gas mixtures (H2/N2, CO/N2, C3H6/N2, C3H8/N2, and CH4/N2) were used together with a variable amount of O2. In addition to laboratory studies, the same sensors were also studied in the exhaust gas of an engine. Whereas at high temperatures thermodynamic equilibrium appears to prevail, clear departures from thermodynamic equilibrium are observed at some lower temperatures (the value of which depends on the specific sensor and the specific gas mixture used). This behavior is manifested by shifts of the emf step away from stoichiometry, broadening of the step, abnormally high emf values in excess oxygen mixtures, and abnormally low emf values in reducing gas mixtures.

With the use of a simulated exhaust system, the sulfuric acid and sulfur dioxide emission from a monolith noble-metal oxidation catalyst (Engelhard IIB) is measured. It was found that the storage rate of sulfur onto an initially sulfur-free catalyst decreases to a few percent of the sulfur rejection rate within 3-4 h. The amount of sulfur on the catalyst when the catalyst is in equilibrium with 20 ppm sulfur in the gas phase varies between 0.3 weight percent of the catalyst at about 400°C to 0.1 weight percent at 600°C. The sulfur can readily desorb from the catalyst if the gas phase sulfur content is lowered or if the catalyst temperature is increased. It was found that the conversion of sulfur dioxide to sulfuric acid reaches thermodynamic equilibrium at temperatures of 400-500°C and space velocities of 30,000 h-1. These conditions correspond approximately to a small V8 engine at 20 mph cruise.

Stratified-charge DISI engines have been launched in the market by Mitsubishi, Toyota, and Nissan. This paper discusses the current production stratified-charge DISI systems and some alternative systems, including the system using air-forced fuel injection and a proposed system that uses a swirl flow in the piston bowl with a special shape to separate the fuel-rich mixture layer from the wall surface. New DISI concepts are proposed to overcome some drawbacks of current bowl-in-piston type stratified-charge DISI systems. Charge stratification can be realized by using a soft spray with proper spray penetration, droplet size, and cone angle, as shown by CFD simulation results. The drawbacks of fuel wall wetting, soot limited load with charge stratification, large surface to volume ratio, etc., of the bowl-in-piston type system can be minimized.