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Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.

Biodiesel use is increasing around the world. Vehicle failures due to filter clogging issues have been reported in the field with use of biodiesel blended fuels in winter months. In certain instances, filter clogging was caused by precipitate formation above the cloud point of the fuel. Minor contaminants in biodiesel such as sterol glucosides and saturated monoglycerides are suspected to cause precipitation above the cloud point. ASTM has added a requirement to test biodiesel fuel for cold soak filtration test to prevent occurrences of this phenomenon of precipitation above the cloud point. This study focuses on understanding the correlation between cold soak filtration test results and presence of contaminants such as sterol glucosides and saturated monoglycerides in biodiesel fuels. Test samples were also subjected to thermal cycling at temperatures below the cloud point of fuel to co-correlate the cold soak filtration test results to visual observation of precipitate formation.