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Technical Paper

Washcoat Technology and Precious Metal Loading Study Targeting the California LEV MDV2 Standard

1996-10-01
961904
Meeting the California Medium-Duty truck emissions standards presents a significant challenge to automotive engineers due to the combination of sustained high temperature exhaust conditions, high flow rates and relatively high engine out emissions. A successful catalyst for an exhaust treatment system must be resistant to high temperature deactivation, maintain cold start performance and display high three-way conversion efficiencies under most operating conditions. This paper describes a catalyst technology and precious metal loading study targeting a California Medium-Duty truck LEV (MDV2) application. At the same time a direction is presented for optimizing toward the Federal Tier 1 standard through reduction of precious metal use. The paper identifies catalytic formulations for a twin substrate, 1.23 L medium-coupled converter. Two are used per vehicle, mounted 45 cm downstream of each manifold on a 5.7 L V8 engine.
Technical Paper

The Potential of Highly Premixed Combustion for Pollutant Control in an Automotive Two-Stroke HSDI Diesel Engine

2012-04-16
2012-01-1104
An innovative alternative to overcome the load limits of the early injection highly premixed combustion concept consists of taking advantage of the intrinsic characteristics of two-stroke engines, since they can attain the full load torque of a four-stroke engine as the addition of two medium load cycles, where the implementation of this combustion concept could be promising. In this frame, the main objective of this investigation focuses on evaluating the potential of the early injection HPC concept using a conventional diesel fuel combined with a two-stroke poppet valves engine architecture for pollutant control, while keeping a competitive engine efficiency. On a first stage, the HPC concept was implemented at low engine load, where the concept is expected to provide the best results, by advancing the start of injection towards the compression stroke and it was confirmed how it is possible to reduce NOX and soot emissions, but increasing HC and CO emissions.
Technical Paper

System Approach for NOx Reduction: Double LNT Diesel After-Treatment Architecture

2011-04-12
2011-01-1300
This paper presents an after-treatment architecture combining a close coupled NOx trap and an under floor NOx trap. Instead of simply increasing the volume of the catalyst, we propose to broaden the active temperature window by splitting the LNT along the exhaust line. In order to design this architecture, a complete 1D model of NOx trap has been developed. Validated with respect to experimental data, this model has been useful to define the two volumes of LNT, making significant savings on the test bench exploitation. However, one of the main difficulties to operate the proposed architecture is the NOx purge and sulfur poisoning management. In order to optimize the NOx and sulfur purge launches, we have developed a control strategy based on an embedded reduced LNT model. These strategies have been validated on different driving cycles, by the means of simulation and of vehicle tests using rapid prototyping tools.
Technical Paper

Optimal Control of Mass Transport Time-Delay Model in an EGR

2020-04-14
2020-01-0251
This paper touches on the mass transport phenomenon in the exhaust gas recirculation (EGR) of a gasoline engine air path. It presents the control-oriented model and control design of the burned gas ratio (BGR) transport phenomenon, witnessed in the intake path of an internal combustion engine (ICE), due to the redirection of burned gases to the intake path by the low-pressure EGR (LP-EGR). Based on a nonlinear AMESim® model of the engine, the BGR in the intake manifold is modeled as a state-space (SS) output time-delay model, or alternatively as an ODE-PDE coupled system, that take into account the time delay between the moment at which the combusted gases leave the exhaust manifold and that at which they are readmitted in the intake manifold. In addition to their mass transport delay, the BGRs in the intake path are also subject to state and input inequality constraints.
Technical Paper

Non-Thermal Plasma Assisted Catalytic NOx Remediation from a Lean Model Exhaust

2001-09-24
2001-01-3508
No efficient catalyst presently exists for deNOx in lean burn conditions. Furthermore, actual catalysts generally deactivate during reaction. A cylindrical DBD non-thermal plasma reactor was coupled with a stable three-function catalyst in order to verify the nature of the effect of the plasma on the catalytic process. A mixture of NO/O2/C3H6 in N2 was used as a lean model exhaust. The plasma was found to perform two of the three functions: NO oxidation to NO2 and propene activation through the partial oxidation of the hydrocarbon to aldehyde or alcohol. A complete catalyst containing the first two previous functions and the associative chemisorption of NO (third function) was used, as well as a simplified catalyst containing only the third function. Results suggest an advantageous plasma-catalyst coupling effect on NOx remediation in accordance with the proposed catalytic model.
Technical Paper

Intake System Diagnosis for Diesel Engine with Dual-Loop EGR

2012-04-16
2012-01-0904
This paper proposes a method to detect an intake manifold leakage for a Diesel engine with a dual loop EGR system. The intake manifold leak has a strong impact on the engine performances by changing the intake manifold burned gas ratio. This fault is analyzed according to the control structure used and also according to the EGR operating mode. The paper proposes a diagnosis algorithm to detect the intake manifold leak in sequential or simultaneous use of the two EGR paths. The sensors considered are the mass air flow meter, the intake manifold pressure sensor, the exhaust equivalence ratio sensor and the differential pressure sensor (across the HP EGR valve). The diagnosis is based on a criteria that uses the redundancy between these sensors and air system models or estimators. The diagnosis threshold depends on the engine operating conditions as well as the sensor or model dispersions.
Technical Paper

Influence of Both Catalyst Geometry and Fuel Sulfur Content on NOX Adsorber Poisoning

2001-05-07
2001-01-1934
NOx adsorbers are very sensitive to sulfur poisoning and future fuel standards are unlikely to be sufficient to prevent the system from requiring periodic desulfation procedures. The purpose of this paper is to present the effects of low fuel sulfur content such as 50 ppm and 10 ppm on the NOx adsorber efficiency for a diesel application. Through this study, the influence of the substrate cell geometry has also been assessed. The use of a 10 ppm sulfur fuel is not enough to maintain, at a high level, the NOx adsorber performance during a 40,000 km aging test. The desulfation criterion (efficiency loss of 30%) is reached after the first 16,000 km. However, the desulfation operation is not enough to recover the initial catalyst performance and the poisoning velocity increases as the catalyst ages. The hexagonal cell substrate catalyst is less sensitive to sulfur poisoning than a square cell substrate catalyst so that its desulfation frequency is much lower.
Technical Paper

Improvement on Cylinder-to-Cylinder Variation Using a Cylinder Balancing Control Strategy in Gasoline HCCI Engines

2010-04-12
2010-01-0848
Homogenous Charge Compression Ignition (HCCI) combustion offers significant efficiency improvements compared to conventional gasoline engines. However, due to the nature of HCCI combustion, traditional HCCI engines show some degree of sensitivity to in-cylinder thermal conditions; thus higher cylinder-to-cylinder variation was observed especially at low load and high load operating conditions due to different injector characteristics, different amount of reforming as well as non-uniform EGR distribution. To address these issues, a cylinder balancing control strategy was developed for a multi-cylinder engine. In particular, the cylinder balancing control strategy balances CA50 and AF ratio at high load and low load conditions, respectively. Combustion noise was significantly reduced at high load while combustion stability was improved at low load with the cylinder balancing control.
Technical Paper

Impact of Sulphur on the NOx Trap Catalyst Activity-Poisoning and Regeneration Behaviour

2000-06-19
2000-01-1874
This presented paper deals with NOx trap sulphur poisoning and its regeneration. Sulphur poisoning has been studied with different SO2 gas concentrations under laboratory and engine test bench conditions. The sulphur poisoning studies have shown that the different NOx-traps available in the market have different behaviours toward SO2 poisoning and are all very sensitive to it. The results outline a non linear relationship of the NOx trap sulphur poisoning as a function of SO2 concentration. For instance, engine bench tests show that with a 50 and a 110ppm sulphur containing gasoline, a decrease of 50% in the NOx-trap storage capacity is respectively observed after 20 and 15 hours. With a gasoline containing 20ppm of sulphur, the same deactivation level is observed after 90 hours.
Technical Paper

Fuel Economy Trends and Catalytic Devices

1974-02-01
740594
In 1968, a major oil company cancelled its annual automobile economy run after sponsoring it for 18 consecutive years -presumably due to lack of interest from the public and the press. Almost coincident with that cancellation was the beginning of production automobile exhaust emission control on a national basis and a downward inflection in the historic trend of automobile fuel economy. In contrast, the past year has seen a major revival of interest, by both the public and the press, in fuel economy. In the next few weeks, the nation will be introduced to a new direction in automotive exhaust emission control which will profoundly affect the fuel economy trend. Perhaps equally, or even more important, the next few months are expected to see major national decisions on future automobile emission control which will likely have a significant influence on the direction taken by automobile fuel economy a few years hence.
Technical Paper

French Program on the Impact of Engine Technology on Particulate Emissions, Size Distribution and Composition Heavy Duty Diesel Study

2005-04-11
2005-01-0190
An extensive research program involving the French passenger car and heavy-duty (HD) vehicles manufacturers, sponsored by ADEME and realized by IFP, aimed to characterize in terms of size and composition the particulate emitted by the different engine technologies currently or soon available. The impact of engine settings and fuel composition was also studied. Numerous information was collected in this HD study revealing that fuel composition and particularly non-conventional fuels and engine settings strongly impact the particulate concentration and size distribution. Nucleation is likely to occur when there is less adsorption matter, for instance when post-injection is used or EGR is removed. Particulate composition, particularly PAH and sulfates content, is weakly bound to the size. Mineral elements distribution depends on their origin, lubrication oil or engine wear.
Technical Paper

Effect of Flow Distribution on Emissions Performance of Catalytic Converters

1998-02-23
980936
The emissions performance of catalytic converters under different conditions of flow distribution was investigated. Computational Fluid Dynamics methods were utilised to model the maldistribution effects of different inlet cones. The effects of maldistribution on ageing, light-off and conversion were investigated using steady state tests on an engine bench. Emission testing was also conducted on a vehicle throughout ECE and EUDC test cycles. Maldistribution was found to have a significant effect on the efficiency of the catalyst during the early stages of the ECE cycle for both fresh and aged catalysts. The effects were less significant over later stages of the ECE cycle and throughout the EUDC except NOx where maldistribution did have an effect on the conversion at higher flow rates during the later stages of the test.
Technical Paper

Diurnal Emissions from In-Use Vehicles

1999-05-03
1999-01-1463
One hundred fifty-one vehicles were recruited from the I/M lane in Mesa, AZ during the summer of 1996, and their 24 hour diurnal emissions were measured in a variable temperature SHED (VT-SHED). The fleet selection included the earliest applications of evaporative emission control, and later technologies that had at least 5 years of exposure. Model years 1971 through 1991 were tested. Fifty-three percent of the sample tested had daily emissions of more than 10 grams. Five of the 151 were over 50 grams per day, and had significant liquid leaks. Twenty-six (17%) of the vehicles had emissions exceeding one gram per hour. Thirty-two of the 151 tested (21%) had identifiable liquid leaks. Carburetor systems had higher emissions than fuel injection systems. The highest emitters had resting losses of more than 0.8 g/hr. These eight highest emitters were considered outliers for the purposes of general analysis, and were not used, as is noted in the report.
Technical Paper

Development of an Improved Gravimetric Method for the Mass Measurement of Diesel Exhaust Gas Particles

2005-05-11
2005-01-2145
The Particulate Measurement Programme (PMP) works on the identification of a method to replace or complete the existing particle mass (PM) measurement method. The French PMP subgroup, composed by IFP, PSA Peugeot-Citroën, Renault and UTAC, proposes an improved gravimetric method for the measurement of emitted particles, and conducted an inter-laboratory test to evaluate its performances. The technical programme is based on tests carried out on a Euro3 Diesel passenger car (PC), tested on the New European Driving Cycle (NEDC). To achieve low particulate matter (PM) emissions, the EGR is disconnected and a paraffinic fuel is used. The regulated pollutants are also measured. It is shown that the multiple filter weighing and a 0.1 μg balance instead of a 1 μg one are not necessary, as the first weighing and the 1 μg balance performances are satisfactory for type-approval purposes.
Journal Article

Development and Validation of a New Zero-Dimensional Semi-Physical NOx Emission Model for a D.I. Diesel Engine Using Simulated Combustion Process

2015-04-14
2015-01-1746
Reducing NOx tailpipe emissions is one of the major challenges when developing automotive Diesel engines which must simultaneously face stricter emission norms and reduce their fuel consumption/CO2 emission. In fact, the engine control system has to manage at the same time the multiple advanced combustion technologies such as high EGR rates, new injection strategies, complex after-treatment devices and sophisticated turbocharging systems implemented in recent diesel engines. In order to limit both the cost and duration of engine control system development, a virtual engine simulator has been developed in the last few years. The platform of this simulator is based on a 0D/1D approach, chosen for its low computational time. The existing simulation tools lead to satisfactory results concerning the combustion phase as well as the air supply system. In this context, the current paper describes the development of a new NOx emission model which is coupled with the combustion model.
Technical Paper

An Investigation into the Influence of LPG (Autogas) Composition on the Exhaust Emissions and Fuel Consumption of 3 Bi-Fuelled Renault Vehicles

1996-05-01
961170
Studies using a bi-fuelled (autogas/gasoline) Renault Laguna vehicle meeting °the 1996 European exhaust emission legislation has demonstrated that over the European test cycle at 25°C the LPG operated vehicle provides substantial benefits of reduced emissions compared to unleaded reference gasoline. At lower test temperatures (i.e. 5°C) even larger reduction in emissions have been observed. Lower CO (up to 95% at -5°C and 65% at 25°C), HC (90% at -5°C and 40% at 25°C) emissions and lower ozone HC reactivity have been observed and could all offer significant environmental air-quality benefits for LPG. Various autogas mixtures have been tested including 70/30, 30/70 and 49/30/21 (% mass propane / butane / propene). Results show that NOx emissions for this vehicle appear dependent on autogas composition. The two gas mixtures containing only 30% butane gave about 50% more NOx at +25°C than the 70% butane autogas mixture.
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