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For better understanding of soot formation and oxidation processes in a biodiesel spray flame, the morphology, microstructure and sizes of soot particles directly sampled in a spray flame fuelled with soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at different axial locations in the spray flame, 40, 50 and 70 mm from injector nozzle, which correspond to soot formation, peak, and oxidation zones, respectively. The biodiesel spray flame was generated in a constant-volume combustion chamber under a diesel-like high pressure and temperature condition (6.7 MPa, 1000K). Density, diameter of primary particles and radius of gyration of soot aggregates reached a peak at 50 mm from the injector nozzle and was lower or smaller in the formation or oxidation zones of the spray.

Laser plasma ignition has been pursued by engine researchers as an alternative to electric spark-ignition systems, potentially offering benefits by avoiding quenching surfaces and extending breakdown limits at higher boost pressure and lower equivalence ratio. For this study, we demonstrate another potential benefit: the ability to control the timing of ignition with short, nanosecond pulses, thereby optimizing the type of mixture that burns in rapidly changing, stratified fuel-air mixtures. We study laser ignition at various timings during single and double injections at simulated gasoline engine conditions within a controlled, high-temperature, high-pressure vessel. Laser ignition is accomplished with a single low-energy (10 mJ), short duration (8 ns) Nd:YAG laser beam that is tightly focused (0.015 mm average measured 1/e₂ diameter) at a typical GDI spark plug location.

It is common practice to validate diesel spray models against experimental diesel-spray images based on elastic light scattering, but the metric used to define the liquid boundary in a modeled spray can be physically inconsistent with the liquid boundary detected by light scattering measurements. In particular, spray models typically define liquid penetration based on a liquid mass threshold, while light scattering signal intensities are based on droplet size and volume fraction. These metrics have different response characteristics to changes in ambient conditions and fuel properties. Thus, when spray models are “tuned” or calibrated to match these types of measurements, the predictive capabilities of these models can be compromised. In this work, we compare two different liquid length metrics of an evaporating, non-reacting n-dodecane spray under diesel-like conditions using KIVA-3V.