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Compressed Natural Gas (CNG) is a promising alternative fuel for internal combustion engines as its combustion is fuel-efficient and lean in carbon dioxide compared to gasoline. The high octane number of methane gives rise to significant increase of the thermodynamic efficiency due to higher possible compression ratios. In order to use this potential, new stratified mixture formation concepts for CNG are investigated by means of numerical fluid simulations. For decades RANS methods have been the industry standard to model three-dimensional flows. Indeed, there are well-known deficiencies of the widely used eddy viscosity turbulence models based on the applied Boussinesq hypothesis. Reynolds stress turbulence models as well as scale resolving simulation approaches can be appealing alternative choices since they offer higher accuracy. However, due to their large computing effort, they are still mostly impractical for the daily use in industrial product development processes.