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Vegetable oils have energy content suitable to be used as compression ignition (CI) engine fuel. However, several operational and durability problems of using straight vegetable oils in CI engines are reported in the literature, which are primarily caused by their higher viscosity and low volatility compared to mineral diesel. The viscosity can be brought in acceptable range by (i) chemical process of transesterification, (ii) blending of oil with mineral diesel or (iii) by heating the vegetable oil using exhaust gas waste heat. Reduction of viscosity by blending or exhaust gas heating saves the chemical processing cost of transesterification. Present experimental investigations were carried out for evaluating combustion, performance and emission behavior of Jatropha oil blends in unheated conditions in a direct injection CI engine at different load and constant engine speed (1500 rpm).

Poor oxidation stability is the central problem associated with the commercial acceptance of the biodiesel. The EU standard (EN14214) specifies a minimum value of 6 h for biodiesel induction period at 110°C, measured with Rancimat instrument. Most of the freshly prepared biodiesel generally have lower induction periods than prescribed by the standards. Anti-oxidants are therefore added to enhance the oxidation/ storage stability of biodiesel. Oxidation is an exothermic process, and the reaction heat evolved makes it possible to use thermo gravimetric analysis (TGA). In the present study, the oxidation stability of methyl esters derived from Karanja oil and Neem oil, stabilized with anti-oxidant pyrogalol (PY) was studied by DSC. Onset temperature of freshly prepared Karanja biodiesel (KOME) and Neem biodiesel (NOME) was observed to be 148 and 153°C respectively. The stability increases with increasing anti-oxidant dosage.

Mono alkyl esters of long-chain fatty acids derived from renewable lipid feedstock, such as vegetable oils or animal fats, also known as biodiesel are well positioned to replace mineral diesel. The outstanding technical problem with biodiesel is that it is more susceptible to oxidation owing to its exposure to oxygen present in the air and high temperature. This happens mainly due to the presence of varying numbers of double bonds in the free fatty acid molecules. The chemical reactivity of esters can therefore be divided into oxidative and thermal instability, which can be determined by the amount and configuration of the olefinic unsaturation in the fatty acid chains. Many of the plant-derived fatty oils contain polyunsaturated fatty acids that are more prone to oxidation. Increasing production of biodiesel from vegetable oils (edible) places strain on food production, availability and price and leads to food versus fuel conflict.

Fuel injection pressure (FIP) is one of the most important factors affecting diesel engine performance and particulate emissions. Higher FIP improves the fuel atomization, which results in lower soot formation due to superior fuel-air mixing. The objective of this spray study was to investigate macroscopic and microscopic spray parameters in FIP range of 500-1500 bar, using a solenoid injector for biodiesel blends (KB20 and KB40) and baseline mineral diesel. For these test fuels, effect of ambient pressure on macroscopic spray characteristics such as spray penetration, spray area and cone angle were investigated in a constant volume spray chamber (CVSC). Microscopic spray characteristics such as velocity distribution of droplets and spray droplet size distribution were measured in the CVSC at atmospheric pressure using Phase Doppler Interferometry (PDI).

Diesel engines are very efficient prime movers in their power range. Fuel is directly injected into the combustion chamber. Performance and emission characteristics of diesel engines are highly influenced by the fuel spray parameters and atomization of the injected fuel. As the emission regulations become stringent, it is very important to optimize the combustion in internal combustion engines for different fuels including alternative fuels. Spray visualization using optical techniques play a very important role to analyze macroscopic spray parameters and fuel atomization behavior. In the present experimental study, an important alternative CI engine fuel, Karanja oil and its blends with diesel have been investigated for their spray parameters and fuel atomization relative to mineral diesel. These parameters are different for the two fuels because of difference in the viscosity and density of the fuels.

Several experimental studies have been conducted for evaluating coefficient of friction and wear in simulated engine conditions using a piston ring segment and a liner piece rubbing against each other in reciprocating mode under load and lubricated conditions. In the present experimental investigation, a non-firing engine simulator has been developed in order to simulate engine conditions to a much closer extent. This machine can operate at similar linear speed, stroke, and load and can simulate almost similar engine operating conditions except firing pressures. This machine can also be used for comparing liners with different surface properties and the effects of surface texture on wear and oil consumption. One cylinder liner has been used for experimentation and the wear and surface properties behaviour were evaluated at several locations in the liner. Surface profile, roughness parameters are evaluated at several locations in the liner and at the top compression ring.

Due to the increasingly stricter emission legislations and growing demand for lower fuel consumption, there have been significant efforts to improve combustion efficiency, while satisfying the emission requirements. Homogenous Charge Compression Ignition (HCCI) combustion offers significant efficiency improvements compared to conventional gasoline engines. However, due to the nature of HCCI, fully homogeneous charge HCCI combustion can be realized only in a limited operating range. Control of HCCI engines to obtain the desirable operation requires understanding of how different charge variables influence the cyclic variations in HCCI combustion. Under certain operating conditions, HCCI engines exhibit large cyclic variations in ignition timing. Cyclic variability ranging from stochastic to deterministic patterns can be observed. One important design goal for engine development is to minimize cyclic variability.

The development of vehicles continues to be determined by increasingly stringent emissions standards including CO2 emissions and fuel consumption. To fulfill the simultaneous emission requirements for near zero pollutant and low CO2 levels, which are the challenges of future powertrains, many research studies are currently being carried out world over on new engine combustion process, such as Controlled Auto Ignition (CAI) for gasoline engines and Homogeneous Charge Compression Ignition (HCCI) for diesel engines. In HCCI combustion engine, ignition timing and combustion rates are dominated by physical and chemical properties of fuel/air/residual gas mixtures, boundary conditions including ambient temperature, pressure, and humidity and engine operating conditions such as load, speed etc.

Biodiesel made from Jatropha oil by transesterification process has viscosity and other important physical properties comparable to mineral diesel hence it can be used as an alternate fuel in conventional diesel engines. It is important to investigate the spray characteristics of biodiesel because emissions from the engines are dependent on fuel atomization process and resulting fuel-air mixing. This study focuses on the Jatropha biodiesel spray investigations using Phase Doppler Interferometry (PDI) for measurement of various microscopic spray parameters such as Sauter mean diameter (SMD) and spray droplet size and velocity distributions. The spray and engine experiments were carried out for Jatropha biodiesel (JB100) and their 20% blends (JB20) with mineral diesel as baseline. Fuel injection pressure during the spray experiments was maintained at 200 bars for all tests, quite similar to small horse power agricultural engines, and the fuel injection quantity was varied.

The rising concerns of emissions have put enormous strain on the automotive industry. Industry is, therefore looking for next-generation engines and advanced combustion technologies with ultra-low emissions and high efficiency. To achieve this, more insights into the combustion and pollutant formation processes in IC engines is required. Since conventional measures have not been insightful, in-situ measurement of combustion and pollution formation through optical diagnostics is being explored. Gaining full optical access into the diesel engine combustion chamber is a challenging task. The late-compression flow dynamics is not well understood due to limited access into the engine combustion chamber. These flow structures contribute immensely to fuel-air mixing and combustion. The objective of this study is to understand the role of combustion chamber design on vertical plane air-flow structures.

Adverse health effects of particulate matter (PM) originating from diesel engine exhaust are largely attributed to the complex chemical composition of the exhaust species. This study was set out to characterize particulate emissions from a Euro-III-compliant modern automotive common rail direct injection (CRDI) sports utility vehicle (SUV) diesel engine operated at different loads at rated engine speed (1800 rpm), employing diesel and 20% biodiesel blends (B20) produced from Karanja oil. This study is mainly divided into two main sections, first one includes the gravimetric analysis in order to assess the amount of Benzene Soluble Organic Fraction (BSOF) and trace metals using Inductively Coupled Plasma-Optical Emission Spectrometer (ICPOES). The second section includes real-time measurements for Organic Carbon (OC), Elemental Carbon (EC) and total particle-bound Polycyclic Aromatic Hydrocarbons (PAHs).

Homogeneous charge compression ignition (HCCI) is an advanced combustion concept that is developed as an alternative to diesel engines with higher thermal efficiency along with ultralow NOx and PM emissions. To study the performance of this novel technique, experiments were performed in a two cylinder engine, in which one cylinder is modified to operate in HCCI mode while other cylinder operates in conventional CI mode. The quality of homogeneous mixture of air and fuel is the key feature of HCCI combustion. Low volatility of diesel is a major hurdle in achieving HCCI combustion because it is difficult to make a homogeneous mixture of air and fuel. This problem is resolved by external mixture preparation technique in uses a dedicated diesel vaporizer with an electronic control system. All the injection parameters such as fuel quantity, fuel injection timing, injection delay etc., are controlled by the injection driver circuit.