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This paper summarizes the validation testing of the Horiba Instruments OBS-2200 gaseous portable emissions measurement system (PEMS) for in-use compliance testing per Title 40 of the Code of Federal Regulations (CFR) Part 1065.920 (Section 1065.920). The qualification process included analyzer verifications as well as engine testing on a model-year 2007 heavy-duty diesel engine produced by Volvo Powertrain. The measurements of brake-specific emissions with the OBS-2200 were compared to those of a CFR Part 1065-compliant CVS test cell over a series of not-to-exceed (NTE) events. The OBS-2200 passed all linearity verifications and analyzer checks required of PEMS. Engine test validation was achieved for all three regulated gaseous emissions (CO, NMHC, and NOX) per 40 CFR Part 1065.920(b)(5)(i), which requires a minimum of 91 percent of the measurement allowance adjusted deltas to be less than or equal to zero.

Diesel fuel is a blend of various middle distillate components separated at the refinery. The composition and characteristics of the diesel fuel blend changes daily if not hourly because of normal process variation, changing refinery processing conditions, changing crude oil diet or changing diesel fuel and kerosene market conditions. Regardless of the situation going on at the refinery or the market, the resultant diesel fuel must consistently meet established cloud point specifications. To consistently meet the cloud point specifications, refiners are forced to blend their diesel fuels in such a way that the resultant blend is always on the low side of the cloud point specification even when the refining process adversely changes the fuel characteristics. This practice has the effect of producing several degrees of cloud point “giveaway” when the refinery is not experiencing adverse swings in product quality.

The Exhaust Composition Transient Operation LaboratoryTM (ECTO-LabTM) is a burner system developed at Southwest Research Institute (SwRI) for simulation of IC engine exhaust. The current system design requires metering and combustion of nitromethane in conjunction with the primary fuel source as the means of NOX generation. While this method affords highly tunable NOX concentrations even over transient cycles, no method is currently in place for dictating the speciation of nitric oxide (NO) and nitrogen dioxide (NO2) that constitute the NOX mixture. NOX generated through combustion of nitromethane is dominated by NO, and generally results in an NO2:NOX ratio of < 5 %. Generation of any appreciable quantities of NO2 is therefore dependent on an oxidation catalyst to oxidize a fraction of the NO to NO2.

The use of alcohol as a supplemental fuel for a medium-speed diesel engine was investigated using a two-cylinder, two-stroke test engine. Both stabilized and unstabilized emulsions of methanol-in-diesel fuel and ethanol-in-diesel fuel were tested. Also, anhydrous ethanol/diesel fuel solutions were evaluated. Maximum alcohol content of the emulsions and solutions was limited by engine knocking due to a reduction in fuel cetane number. Engine power and thermal efficiency were slightly below baseline diesel fuel levels in the high and mid-speed ranges, but were somewhat improved at low speeds during tests of the unstabilized emulsions and the ethanol solutions. However, thermal efficiency of the stabilized emulsions fell below baseline levels at virtually all conditions.

Beginning June 1, 2006, 80% of the highway diesel fuel produced in the United States had to contain 15 ppm sulfur or less. To account for sulfur test method variability, the United States Environmental Protection Agency (US EPA) allowed a 2 ppm compliance margin, meaning that in an EPA enforcement action fuel measuring 17 ppm or less would still be deemed compliant since the true sulfur level could still be 15 ppm. Concern was voiced over the appropriateness of the 2 ppm compliance margin, citing recent American Society for Testing and Materials (ASTM) round-robin and crosscheck test program results that showed sulfur test lab-to-lab variability (reproducibility) on the order of 4 to 5 ppm depending on test method.

Results from work focusing on the development of an ultra low emissions, high efficiency, natural gas-fueled heavy- duty engine are discussed in this paper. The engine under development was based on a John Deere 8.1L engine; this engine was significantly modified from its production configuration during the course of an engine optimization program funded by the National Renewable Energy Laboratory. Previous steady-state testing indicated that the modified engine would provide simultaneous reductions in nonmethane hydrocarbon emissions and fuel consumption while maintaining equivalent or lower NOx levels. Federal Test Procedure transient tests confirmed these expectations. Very low NOx emissions, averaging 1.0 g/bhp-hr over hot-start cycles, were attained; at these conditions, reductions in engine-out nonmethane hydro-carbons emissions (NMHC) were approximately 30 percent, and fuel consumption over the cycle was also reduced relative to the baseline.

Comparative emission measurements were made in two dynamometer-based diesel engines using protocol specified by the U.S. Environmental Protection Agency (EPA) and the California Air Resources Board (CARB). A single JP-8 fuel with a sulfur level of 0.06 weight percent (wt%) was adjusted to sulfur levels of 0.11 and 0.26 wt%. The emission characteristics of the three fuels were compared to the 1994 EPA certification low-sulfur diesel fuel (sulfur level equal to 0.035 wt%) in the Detroit Diesel Corporation (DDC) 1991 prototype Series 60 diesel engine and in the General Motors (GM) 6.2L diesel engine. Comparisons were made using the hot-start transient portion of the heavy-duty diesel engine Federal Test Procedure. Results from the Army study show that the gaseous emissions for the DDC Series 60 engine using kerosene-based JP-8 fuel are equivalent to values obtained with the 0.035 wt% sulfur EPA certification diesel fuel.

The use of compressed natural gas as an alternative to conventional fuels has received a great deal of attention as a strategy for reducing air pollution from motor vehicles. In many cases, regulatory action has been taken to displace diesel fuel with natural gas in truck and bus applications. Emissions results of heavy-duty transient FTP testing of two Cummins L10-240G natural gas engines are presented. Regulated emissions of non-methane hydrocarbons, total hydrocarbons, CO, NOx, and particulate were characterized, along with emissions of formaldehyde. The effects of air/fuel ratio adjustments on these emissions were explored, as well as the effectiveness of catalytic aftertreatment in reducing exhaust emissions. Compared to typical heavy-duty diesel engine emissions, CNG-fueled engines using exhaust aftertreatment have great potential for meeting future exhaust emission standards, although in-use durability is unproven.

Small engines which are friendly toward the environment are needed all over the world, whether the need is expressed in terms of energy efficiency, useful engine life, health benefits for the user, or emission regulations enacted to protect a population or an ecologically-sensitive area. Progress toward the widespread application of lower-impact small engines is being made through engine design, matching of engine to equipment and task, aftertreatment technology, alternative and reformulated fuels, and improved lubricants. This paper describes three research and development projects, focused on the interrelationships of fuels, lubricants, and emissions in Otto-cycle engines, which were conducted by Southwest Research Institute. All the work reported was funded internally as part of a commitment to advance the state of small engine technology and thus enhance human utility.

Injuries produced by standard three point restraint systems with retractors will be compared between cadavers in laboratory simulated collisions at 30 mph barrier equivalent speed and lap and shoulder belted front seat occupants in real world frontal collisions of '73-'75 full sized cars. Tests conducted at SwRI with belted, unembalmed, fresh cadavers have resulted in extremely severe thoracic and cervical injuries, including multiple rib fractures, fractures of the sternum, clavicle and cervical vertebrae. On the other hand, injury data from a national accident investigation study to evaluate the effectiveness of restraints in late model passenger cars indicates that such injuries in real world crashes of equivalent severity are not always observed. The reasons possible for these differences are discussed. Both programs at SwRI are funded by the National Highway Traffic Safety Administration.

Life Cycle Assessment (LCA) is a methodology used to determine quantitatively the environmental impacts of a range of options. The environmental community has used LCA to study all of the impacts of a product over its life cycle. This analysis can help to prevent instances where a greater degree of environmental harm results when changes are made to products based on consideration of impacts in only part of the life cycle. This study applies the methodology to engine lubricants, and in particular chlorine limits in engine lubricant specifications. Concern that chlorine in lubricants might contribute to emissions from vehicle exhausts of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF), collectively called PCDD/F, led to the introduction of chlorine limits in lubricant specifications. No direct evidence was available linking chlorine in lubricants to PCDD/F formation, but precautionary principles were used to set lubricant chlorine limits.

The Texas Department of Transportation (TxDOT) began using an ultra-low-sulfur, low aromatic, high cetane number diesel fuel (TxLED, Texas Low Emission Diesel) in June 2003. They initiated a simultaneous study of the effectiveness to reduce emissions and influence fuel economy of this fuel in comparison to 2D on-road diesel fuel used in both their on-road and off-road equipment. The study incorporated analyses for the fleet operated by the Association of General Contractors (AGC) in the Houston area. Some members of AGC use 2D off-road diesel in their equipment. One off-road engine, two single-axle dump trucks, and two tandem-axle dump trucks were tested. The equipment tested included newer electronically-controlled diesels. The off-road engine was tested over the TxDOT Telescoping Boom Excavator Cycle. The dump trucks were tested using the “route” technique over the TxDOT Single-Axle Dump Truck Cycle or the TxDOT Tandem-Axle Dump Truck Cycle.

The Texas Department of Transportation began using an emulsified diesel fuel in 2002. They initiated a simultaneous study of the effectiveness of this fuel in comparison to 2D on-road diesel fuel and 2D off-road diesel. The study included comparisons of fuel economy and emissions for the emulsion, Lubrizol PuriNOx®, relative to conventional diesel fuels. Two engines and eight trucks, four single-axle dump trucks, and four tandem-axle dump trucks were tested. The equipment tested included both older mechanically-controlled diesels and newer electronically-controlled diesels. The two engines were tested over two different cycles that were developed specifically for this project. The dump trucks were tested using the “route” technique over one or the other of two chassis dynamometer cycles that were developed for this project In addition to fuel efficiency, emissions of NOx, PM, CO, and HCs were measured. Additionally, second-by-second results were obtained for NOx and HCs.

The Texas Department of Transportation (TxDOT) began using an emulsified diesel fuel in July 2002. They initiated a simultaneous study of the effectiveness of this fuel in comparison to 2D on-road diesel fuel, which they use in both their on-road and off-road equipment. The study also incorporated analyses for the fleet operated by the Associated General Contractors (AGC) in the Houston area. Some members of AGC use 2D off-road diesel fuel in their equipment. The study included comparisons of fuel economy and emissions for the emulsified fuel relative to the conventional diesel fuels. Cycles that are known to be representative of the typical operations for TxDOT and AGC equipment were required for use in this study. Four test cycles were developed from data logged on equipment during normal service: 1) the TxDOT Telescoping Boom Excavator Cycle, 2) the AGC Wheeled Loader Cycle, 3) the TxDOT Single-Axle Dump Truck Cycle, and 4) the TxDOT Tandem-Axle Dump Truck Cycle.

The Port Fuel Injector (PFI) Deposit Test is a performance-based test procedure developed by the Coordinating Research Council and adopted by state and federal regulatory agencies for fuel qualification in the United States. To date, Southwest Research Institute (SwRI) has performed over 375 PFI tests between 1991 and 1998 for various clients. This paper details the analyses of these tests. Of the 375 tests, 199 were performed as keep-clean tests and 176 were performed as clean-up tests. The following areas of interest are discussed in this paper: Keep-clean versus clean-up test procedures Linearity of deposit formation Injector position effects as related to fouling Dirtyup / cleanup phenomena Seasonal effects This paper draws the conclusion that it is easier to keep new injectors from forming deposits than it is to clean up previously formed deposits. It was found that injector deposit formation is generally non-linear.

Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.

SwRI has developed a new technology concept involving the use of high EGR rates coupled with a high-energy ignition system in a gasoline engine to improve fuel economy and emissions. Based on a single-cylinder study [1], this study extends the concept of a high compression ratio gasoline engine with EGR rates > 30% and a high-energy ignition system to a multi-cylinder engine. A 2000 MY Isuzu Duramax 6.6 L 8-cylinder engine was converted to run on gasoline with a diesel pilot ignition system. The engine was run at two compression ratios, 17.5:1 and 12.5:1 and with two different EGR systems - a low-pressure loop and a high pressure loop. A high cetane number (CN) diesel fuel (CN=76) was used as the ignition source and two different octane number (ON) gasolines were investigated - a pump grade 91 ON ((R+M)/2) and a 103 ON ((R+M)/2) racing fuel.

The engine selected for this work was a Caterpillar 3176 engine. Engine exhaust emissions, performance, and heat release rates were measured as functions of engine configuration, engine speed and load. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to achieve a NOx emissions level of 2.5 gm/hp-hr. Measurements were performed at 7 different steady-state, speed-load conditions on thirteen different test fuels. The fuel matrix was statistically designed to independently examine the effects of the targeted fuel properties. Cetane number was varied from 40 to 55, using both natural cetane number and cetane percent improver additives. Aromatic content ranged from 10 to 30 percent in two different forms, one in which the aromatics were predominantly mono-aromatic species and the other, where a significant fraction of the aromatics were either di- or tri-aromatics.

Fuel additives are being used more frequently to meet “premium diesel fuel” requirements. Although these additives improve performance, they also affect the water separation characteristics. This program was designed to determine the effects of various additives on fuel/water separation in low- and ultra-low sulfur diesel fuel. The additives studied include detergents and lubricity additives. A soy-based biofuel is also considered. The fuel/water separation tests conducted with coalescer filter technology generally produced higher efficiencies while the addition of a detergent additive package at 175-ppm generally produced lower water separation efficiencies.

The use of biodiesel fuels derived from vegetable oils or animal fats as a substitute for conventional petroleum fuel in diesel engines has received increased attention. This interest is based on a number of properties of biodiesel including the fact that it is produced from a renewable resource, its biodegradability, and its potential beneficial effects on exhaust emissions. As part of Tier 1 compliance requirements for EPA's Fuel Registration Program, a detailed chemical characterization of the transient exhaust emissions from three modern diesel engines was performed, both with and without an oxidation catalyst. This characterization included several forms of hydrocarbon speciation, as well as measurement of aldehydes, ketones, and alcohols. In addition, both particle-phase and semivolatile-phase PAH and nitro-PAH compounds were measured. Unregulated emissions were characterized with neat biodiesel and with a blend of biodiesel and conventional diesel fuel.