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Appropriate emergency response information is required for first responder before hydrogen fuel cell vehicles will become widespread. This paper investigates experimentally the hydrogen dispersion in the vicinity of a vehicle which accidentally releases hydrogen horizontally with a single volumetric flow of 2000 NL/min in the under-floor section while varying cross and frontal wind effects. This hydrogen flow rate represents normally a full throttle power condition. Forced wind was about maximum 2 m/s. The results indicated that the windward side of the vehicle was safe but that there were chiefly two areas posing risks of fire by hydrogen ignition. One was the leeward side of the vehicle's underbody where a larger region of flammable hydrogen dispersion existed in light wind than in windless conditions. The other was the area around the hydrogen leakage point where most of the leaked hydrogen remained undiffused in an environment with a wind of no stronger than 2 m/s.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

If a compressed hydrogen tank for vehicles is filled with hydrogen gas more quickly, the gas temperature in the tank will increase. In this study, we conducted hydrogen gas filling tests using the TYPE 3 and TYPE 4 tanks. During the tests, we measured the temperature of the internal liner surface and investigated its relationship with the gas temperature in the tank. We found that the gas temperature in the upper portion of the TYPE 4 tank rose locally during filling and that the temperature of the internal liner surface near that area also rose, resulting in a temperature higher than the gas temperature at the center of the tank. To keep the maximum temperature in the tank below the designed temperature (85°C) during filling and examine the representative tank internal temperatures, it is important to examine filling methods that can suppress local rises of tank internal temperature.

The distribution of concentrations of hydrogen leaking into the front compartment and the dispersion after the leak was stopped were investigated to obtain basic data for specifying the mounting positions of hydrogen leak detecting sensors and the threshold values of alarms for compressed hydrogen vehicles. Ignition tests were also conducted to investigate the flammability and the environmental impact (i.e. the impact on human bodies). These tests were also conducted with methane to evaluate the protection against hydrogen leaks in vehicles in comparison with natural gas (methane). We found that the concentration of hydrogen in the front compartment reached 23.7 vol% maximum when hydrogen gas was allowed to leak for 600 sec from the center of the bottom of the wheelbase at a rate of 131 NL/min, which is the allowable limit for a fuel leak at the time of collision of compressed hydrogen vehicles in Japan.

Instantaneous temperature of in-cylinder gas provides a lot of useful and local information for analyzing the combustion process in an internal combustion engine. From the standpoint of applicability to a practical engine, the infrared monochromatic radiation pyrometry required only a single optical window is considered to be more suitable comparing with the conventional infrared absorption-emission pyrometry with two optical windows. Then, the former pyrometer is used to measure the mean gas temperatures averaged on an optical path (or cylinder diameter) of a spark ignition engine connected to a prechamber with a torch nozzle of various area sizes. These measured temperature-crankangle diagrams not only clarify the influences of torch jet flow on the combustion processes, but also correspond well to the heat release rates calculated from the pressure diagrams.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.

Ultra-low energy consumption and ultra-low emission vehicle technologies have been developed by combining petroleum-alternative clean energy with a hybrid electric vehicle (HEV) system. Their component technologies cover a wide range of vehicle types, such as passenger cars, delivery trucks, and city buses, adsorbed natural gas (ANG), compressed natural gas (CNG), and dimethyl ether (DME) as fuels, series (S-HEV) and series/parallel (SP-HEV) for hybrid types, and as energy storage systems (ESSs), flywheel batteries (FWBs), capacitors, and lithium-ion (Li-ion) batteries. Evaluation tests confirmed that the energy consumption of the developed vehicles is 1/2 of that of conventional diesel vehicles, and the exhaust emission levels are comparable to Japan's ultra-low emission vehicle (J-ULEV) level.

This work investigated the mechanism of oil dilution by post injection to remove accumulated particulate matter on the diesel particulate filter of diesel engines. We developed a model to simulate post injection spray under low ambient gas pressure conditions. The model can predict the quantity of fuel mass adhered on the cylinder wall. The adhered fuel enters oil sump through the piston ring and cause oil dilution. The fuel in diluted oil evaporates during normal engine operations. We focus on the mechanism of fuel evaporation from diluted oil. The effects of engine speed and oil temperature on the evaporation were investigated. The results showed that the fuel evaporation rate increases with increasing engine speed and oil temperature. Furthermore, we developed an empirical model to predict the fuel evaporation rate of diluted oil through regression analysis with measured data.

For the better understanding of nanoparticles observed on the rode side, adding to the emission test on the chassis dynamometer and engine dynamometer test, possible factors for formation of nanoparticles are investigated. As other possible factors, cold starting of transient test cycle, blow-by gas from heavy duty diesel engine without a positive crankcase ventilation, exhaust braking, and plume mixing of vehicle exhausts were investigated. Nuclei mode particles under the transient test cycles formed during fuel cut period, fuel enrichment period and idling period. Concentration of nuclei mode particles during the idling period are depends on exhaust temperature. The higher exhaust temperature courses the lower number concentration but variation range is within twice. Emission rate of nanoparticles from blow-by gas is one thousandth of tail pipe emissions rate and was found to be negligible.

Single cylinder engine testing was carried out to clearly understand the test results of multi-cylinder engines reported by the Diesel WG in JCAP (Japan Clean Air Program) (1), (2), (3) and (4). In this tests, engine specifications such as fuel injection pressure, nozzle hole diameter, turbo-charging pressure, EGR rate, and fuel properties such as 1-, 2-, 3-ring aromatics content, n-,i-paraffins content, and T90 were parametrically changed and their influence on the emissions were studied. PM emission generally increased in each engine condition with increased aromatic contents and T90. In particular, multi ring aromatics brought about large increases in PM regardless of the engine conditions. The influence of fuel properties on NOx emission is smaller than the influence on PM emission. Some other fuels that have various side chain structures of 1-ring aromatics, normal paraffins only and various naphthene contents were also investigated.

Compared with diesel fuel, FAME is relatively unstable and readily generates acids such as acetic acid and propionic acid. When FAME-blended diesel fuel is used in existing diesel vehicles, it is important to maintain the concentration of FAME-origin acid in the fuel at an appropriately low level to assure vehicle safety. In the present study, the oxidation of diesel fuel containing 5% FAME is investigated. Several kinds of FAMEs were examined, including reagents such as methyl linoleate and methyl linolenate, as well as commercially available products. The level of acid, peroxide, water, and methanol and the pressure of the testing vessel were measured. The result shows that unsaturated FAMEs that have two or more double bonds are unstable. Also, water is generated by oxidation of FAME blended diesel fuel, accelerating corrosion of the terne sheet.

The Advanced Clean Energy Vehicle Project (ACE Project) has been initiated to develop the vehicles which can utilize oil-alternative and clean fuels and achieve twice the energy efficiency of conventional vehicles. To achieve the project objectives, Japanese automobile manufactures are developing six types of hybrid vehicles. Technologies of the developing vehicles include many kinds of hybrid elements, such as series and series/parallel types, alternative fuels (natural gas, DME, methanol) internal combustion engines and a fuel cell, as well as flywheels, ultra-capacitors and Li-ion batteries. This paper introduces the outline of ACE project.

In recent research, decreasing oil consumption and using a synthetic oil have been shown to be effective methods of reducing smoke emissions. However, the investigation of the constituents of white smoke and its environmental effect on humans have not been undertaken. The purpose of this investigation is to clarify the characteristics and compositions of white smoke and to analyze its environmental effect on humans using Ames test, and to evaluate a control for reduction of emitted matter by steady-state engine tests. Emitted matters(EM) from synthetic oil is less than that of semi-synthetic and mineral oils under the same test conditions. Emission after treatment resulted in the lowest EM when simulating the results of the ISO 6460 test, which results showed a decrease to about 1/10. EM from two-stroke engine mainly consists of unburned engine-oil and more than 95 % of EM is soluble organic fraction (SOF).

A methodology for simulating effect of international variations in fuel compositions on spray combustion is proposed. The methodology is validated with spray combustion experiments with real fuels from three different countries. The compositions of those fuels were analyzed through GC×GC and H-NMR. It was found that ignition delay times, flame region and flame luminosity were significantly affected by the compositional variations. For the simulation, an evaporation surrogate consisting of twenty two species, covering basic molecular types and a wide range of carbon numbers, is developed. Each species in the evaporation surrogate is then virtually converted to a reaction surrogate consisting of n-hexadecane, methylcyclohexane and 1,2,4-trimethyl benzene so that combustion reactions can be calculated with a published kinetic model. The virtual species conversion (VSC) is made so as to take over combustion-related properties of each species of evaporation surrogates.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

This paper proposes a new mixing-controlled, low temperature combustion (LTC) approach for high-speed direct injection (HSDI) diesel engines. The purpose of this approach is to avoid the excessively high pressure-rise rate (PRR) of premixed, kinetics-controlled LTC and to enable the low nitrogen oxides (NOx) combustion to operate over the wide speed and load range of the engine. To address the soot/noise trade-off at high load LTC operating conditions, the pressure modulated multiple-injection coupled with swirl control was applied. This injection strategy enables the injection of high pressure (HP) main spray into the local high temperature region of the already burning low pressure (LP) pilot spray injected from the neighboring injection hole. By employing this injection strategy, the equivalence ratio (φ) distribution of mixture is drastically varied during main combustion processes.

A new combustion system targeting a drastic decrease in NOx emission and a brake specific energy consumption equivalent to that of a DI diesel engine has been developed. In this new combustion system, a lean burn system using early injection was employed to reduce NOx emission and an auto-ignition DI engine system was employed to achieve the low energy consumption. Methanol was used as the fuel for reducing NOx emission. The objective of this study is to clarify the possibility of the system for the auto-ignition of a premixed lean mixture of methanol fuel. This study shows that the gas temperature at ignition, Tig, is the predominant factor affecting auto-ignition. Auto-ignition occurs when Tig exceeds approximately 1000K. The methanol lean burn system in an auto-ignition DI engine drastically decreased NOx emission with almost the same brake specific energy consumption as a diesel engine in the middle load region.

To achieve high-accuracy measurements of fuel consumption in testing on natural gas vehicles, a method for measuring the absolute value of fuel consumption by the gravimetric method using certificated reference weights and an electric platform scale has been developed. By performing a flow-meter test and a chassis dynamometer test using the gravimetric method, the measurement accuracy of the value of fuel flow rate and fuel consumption obtained by the fuel flow meters, carbon balance method, and air-to-fuel ratio method was evaluated. As a result, a highly accurate method for measuring fuel consumption in chassis dynamometer tests has been confirmed.