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Technical Paper

Thermal Behavior in Hydrogen Storage Tank for FCV on Fast Filling (2nd Report)

2008-04-14
2008-01-0463
If a compressed hydrogen tank for vehicles is filled with hydrogen gas more quickly, the gas temperature in the tank will increase. In this study, we conducted hydrogen gas filling tests using the TYPE 3 and TYPE 4 tanks. During the tests, we measured the temperature of the internal liner surface and investigated its relationship with the gas temperature in the tank. We found that the gas temperature in the upper portion of the TYPE 4 tank rose locally during filling and that the temperature of the internal liner surface near that area also rose, resulting in a temperature higher than the gas temperature at the center of the tank. To keep the maximum temperature in the tank below the designed temperature (85°C) during filling and examine the representative tank internal temperatures, it is important to examine filling methods that can suppress local rises of tank internal temperature.
Technical Paper

Safety Evaluation on Fuel Cell Stacks Fire and Toxicity Evaluation of Material Combustion Gas for FCV

2007-04-16
2007-01-0435
Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.
Technical Paper

Regional Trade and Emission Gas in Asian Automobile Industry

2001-11-12
2001-01-3761
This paper is an attempt to estimate the traffic demand of private vehicles in the Philippines and Thailand toward 2030. Estimation of road traffic volume is one of the most important elements for determining fuel consumption and emission gas levels. The level of passenger car ownership is still low, but there has been a distinct shift toward passenger cars due to the lack of mass transport. In Asian countries, inspection and maintenance and emission standards are the most important policy measures. The projections of car stock are evaluated as the emissions of PM, CO and NOx by applying these policy measures in the case of Thailand.
Journal Article

Prediction of Spray Behavior in Injected by Urea SCR Injector and the Reaction Products

2017-10-08
2017-01-2375
In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.
Technical Paper

Potential of Nanoparticle Formation by Vehicles

2006-04-03
2006-01-0622
For the better understanding of nanoparticles observed on the rode side, adding to the emission test on the chassis dynamometer and engine dynamometer test, possible factors for formation of nanoparticles are investigated. As other possible factors, cold starting of transient test cycle, blow-by gas from heavy duty diesel engine without a positive crankcase ventilation, exhaust braking, and plume mixing of vehicle exhausts were investigated. Nuclei mode particles under the transient test cycles formed during fuel cut period, fuel enrichment period and idling period. Concentration of nuclei mode particles during the idling period are depends on exhaust temperature. The higher exhaust temperature courses the lower number concentration but variation range is within twice. Emission rate of nanoparticles from blow-by gas is one thousandth of tail pipe emissions rate and was found to be negligible.
Technical Paper

Lubricity of Liquefied Gas Assessment of Multi-Pressure/Temperature High-Frequency Reciprocating Rig (MPT-HFRR) -DME Fuel for Diesel

2004-06-08
2004-01-1865
In this study, a MPT-HFRR (Multi-Pressure/Temperature High-Frequency Reciprocating Rig) was manufactured based on a diesel fuel lubricity test apparatus. The MPT-HFRR was designed to be used for conventional test methods as well as for liquefied gas fuel tests. Lubricity tests performed on a calibration standard sample under both atmospheric pressure and high pressure produced essentially constant values, so it was determined that this apparatus could be used for assessing the lubricity of fuel. Using this apparatus, the improvement of lubricity due to the addition of a DME (Dimethyl Ether) fuel additive was investigated. It was found that when 50ppm or more of a fatty acid lubricity improver was added, the wear scar diameter converged to 400μm or less, and a value close to the measured result for Diesel fuel was obtained. The lubricity obtained was considered to be generally satisfactory.
Technical Paper

Internal and Near-Nozzle Flow in a Multi-Hole Gasoline Injector Under Flashing and Non-Flashing Conditions

2015-04-14
2015-01-0944
A computational and experimental study was performed to characterize the flow within a gasoline injector and the ensuing sprays. The computations included the effects of turbulence, cavitation, flash-boiling, compressibility, and the presence of non-condensible gases. The flow domain corresponded to the Engine Combustion Network's Spray G, an eight-hole counterbore injector operating in a variety of conditions. First, a rate tube method was used to measure the rate of injection, which was then used to define inlet boundary conditions for simulation. Correspondingly, injection under submerged conditions was simulated for direct comparison with experimental measurements of discharge coefficient. Next, the internal flow and external spray into pressurized nitrogen were simulated under the base spray G conditions. Finally, injection under flashing conditions was simulated, where the ambient pressure was below the vapor pressure of the fuel.
Technical Paper

Fast Gas Analyzer Observations of Stochastic Preignition Events

2019-04-02
2019-01-0254
The goal of this study was to generate exhaust fast gas data that could be used to identify phenomena that occur before, during, and after stochastic preignition (SPI), also called low-speed preignition (LSPI), events. Crank angle resolved measurement of exhaust hydrocarbons, NO, CO, and CO2 was performed under engine conditions prone to these events. Fuels and engine operating strategies were varied in an attempt to understand similarities and differences in SPI-related behavior that may occur between them. Several different uncommon (typically occurring in less than 1% of engine cycles) features of the fast gas data were identified, and the correlations between them and SPI events were explored. Although the thresholds used to define and identify these observations were arbitrary, they provided a practical means of identifying behavior in the fast gas data and correlating it to SPI occurrence.
Journal Article

Comparison of Fires in Lithium-Ion Battery Vehicles and Gasoline Vehicles

2014-04-01
2014-01-0428
Electric vehicles have become more popular and may be involved in fires due to accidents. However, characteristics of fires in electric vehicles are not yet fully understood. The electrolytic solution of lithium-battery vehicles is inflammable, so combustion characteristics and gases generated may differ from those of gasoline cars. Therefore, we conducted fire tests on lithium-ion battery vehicles and gasoline vehicles and investigated the differences in combustion characteristics and gases generated. The fire tests revealed some differences in combustion characteristics. For example, in lithium-ion battery vehicles, the battery temperature remained high after combustion of the body. However, there was almost no difference in the maximum CO concentration measured 0.5 to 1 m above the roof and 1 m from the side of the body. Furthermore, HF was not detected in either type of vehicle when measured at the same positions as for CO.
Technical Paper

Comparison of Computed and Measured High-Pressure Conical Diesel Sprays

2000-03-06
2000-01-0951
To model sprays from pintle type nozzles with large hollow cone angle and high injection pressure, the correct flow field in the near region must be predicted. A new model was implemented in KIVA-3V code, which adopts the theory of steady gas jet to correct the relative velocities between the drop and gas phases, based on the existence of quasi-steady part of the conical spray and an assumption of equivalent gas jet. Accordingly, the structure of the sprays is defined into three parts: 1. initial part that the gas phase velocity is set to the assumed gas injection velocity; 2. quasi-steady part where the component of velocity in the symmetric line direction of the spray is corrected; 3. stagnation part which is left unchanged. This new model is referred to as the Relative Velocity Correction (RVC) model, and is a set of empirical equations that calculate the sectional distribution of the gas-phase velocity along the symmetric line of the sprays.
Technical Paper

Analysis of Spray Feature Injected by Tailpipe Injector for Aftertreatment of Diesel Engine Emissions

2017-10-08
2017-01-2373
Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.
Technical Paper

Analysis of Low Concentration Aldehyde and Ketone Compounds in Automotive Exhaust Gas by New Collection Reagent.

2005-05-11
2005-01-2152
Acidified 2,4-dinitrophenylhydrazine (DNPH) solution, or DNPH-impregnated cartridges are commonly used for the collection of automotive exhaust carbonyl compounds. There are some DNPH-carbonyl compounds in not in use DNPH cartridges and DNPH solution. Furthermore, concentrations of automotive exhaust carbonyl compounds are decreasing according to improvement of the purification technology for automotive exhaust. Automotive exhaust carbonyl compounds become to be difficult to be analyzed with DNPH collection method, because of these two reasons. It is thought that reliable analysis of acrolein in automotive exhaust is very difficult because concentration of DNPH-acrolein in extracted solution is not stable. Furthermore, it is found out that DNPH-acrolein in DNPH-cartridge is disappeared for short time storage in this research.
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