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In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

If a compressed hydrogen tank for vehicles is filled with hydrogen gas more quickly, the gas temperature in the tank will increase. In this study, we conducted hydrogen gas filling tests using the TYPE 3 and TYPE 4 tanks. During the tests, we measured the temperature of the internal liner surface and investigated its relationship with the gas temperature in the tank. We found that the gas temperature in the upper portion of the TYPE 4 tank rose locally during filling and that the temperature of the internal liner surface near that area also rose, resulting in a temperature higher than the gas temperature at the center of the tank. To keep the maximum temperature in the tank below the designed temperature (85°C) during filling and examine the representative tank internal temperatures, it is important to examine filling methods that can suppress local rises of tank internal temperature.

Since in-cylinder flame temperature has a direct effect on an engine's NOx characteristics, these phenomena have been studied in detail in a DI diesel engine using a newly developed method allowing the in-cylinder temperature distribution to be measured by the two color method. The flame light introduced from the visualized combustion chamber of the engine is divided into two colors by filters. The images of combustion phenomena using the two wavelengths are recorded with a framing streak camera which includes a CCD camera. The flame temperature is immediately calculated by a computer using two color images from the CCD camera. A parameter study was then carried out to determine the influence of intake valve number of the engine, and fuel injection rate (pilot injection) on the in-cylinder temperature distribution.

To reduce ultra fine particle number concentration from a heavy-duty diesel engine, the effects of diesel fuel property and after-treatment systems were studied. The reduction of ultra fine particle number concentration over steady state mode using an 8 liter turbocharged and after-cooled diesel engine was evaluated. PM size distribution was measured by a scanning mobility particle sizer (SMPS). The evaluation used a commercially available current diesel fuel (Sulfur Content: 0.0036 wt%), high sulfur diesel fuel (Sulfur Content: 0.046 wt%) and low sulfur diesel fuel (Sulfur Content: 0.007 wt%). The after-treatment systems were an oxidation catalyst, a wire-mesh type DPF (Diesel Particle Filter) and a wall-flow type catalyzed DPF. The results show that fine particle number concentration is reduced with a low sulfur fuel, an oxidation catalyst, a wire-mesh type DPF (Diesel Particulate Filter) and wall flow type catalyzed DPF, respectively.

To reduce NOx and Particulate Matter (PM) emissions from a heavy-duty diesel engine, the effects of urea selective catalytic reduction (SCR) systems were studied. Proto type urea SCR system was composed of NO oxidation catalyst, SCR catalyst and ammonia (NH3) reduction catalyst. The NOx reduction performance of urea SCR system was improved by a new zeolite type catalyst and mixer for urea distribution at the steady state operating conditions. NOx and PM reduction performance of the urea SCR system with DPF was evaluated over JE05 mode of Japan. The NOx reduction efficiency of the urea SCR catalyst system was 72% at JE05 mode. The PM reduction efficiency of the urea SCR catalyst system with DPF was 93% at JE05 mode. Several kinds of un-regulated matters were detected including NH3 and N2O leak from the exhaust gas. It is necessary to have further study for detailed measurements for un-regulated emissions from urea solution.

To reduce NOx emissions from a heavy-duty engine at low exhaust temperature conditions, the plasma-assisted SCR (Selective Catalytic Reduction) system was evaluated. The plasma-assisted SCR system is mainly composed of an ammonia gas supply system and a plasma reactor including a pellet type SCR catalyst. The preliminary test with simulated gases of diesel exhaust showed an improvement in the NOx reduction performance by means of the plasma-assisted SCR system, even below 150°C conditions. Furthermore, NOx reduction ratio was improved up to 77% at 110°C with increase in the catalyst volume. Also NOx emissions from a heavy-duty diesel engine over the transient test mode in Japan (JE05) were reduced by the plasma-assisted SCR system. However, unregulated emissions, e.g., aldehydes, were increased with the plasma environment. This paper reports the advantages and disadvantages of the plasma-assisted SCR system for a heavy-duty diesel engine.

A newly developed viscous-rubber damper, which employed an innovative structure and a new heat resistant rubber, solved some tough problems. This paper dealt more closely with the features of the new viscous-rubber damper and the new calculation method for the viscous-rubber damper. This damper has been employed for Hino new K13C (K-II) higher boost turbocharged and air to air charge-cooled diesel engine, which has extreme severity on the torsional vibration.

Since in-cylinder flame temperature has a direct effect on an engine's NOx characteristics, this phenomena has been studied in detail in a multi-cylinder DI diesel engine using a new method allowing the in-cylider temperature distribution to be measured by the two color method. An endoscope is installed in the combustion chamber and flame light introduced from the endoscope is divided into two colors by filters. The images of combustion phenomena using the two wavelengths are recorded with a framing streak camera which includes a CCD camera. The flame temperature and KL factor are immediately calculated by a computer using the two color images from the CCD camera. In the case of EGR, the test was conducted under 75% load conditions. The flame temperature was reduced according to an increase of EGR rate.

Instantaneous temperature of in-cylinder gas provides a lot of useful and local information for analyzing the combustion process in an internal combustion engine. From the standpoint of applicability to a practical engine, the infrared monochromatic radiation pyrometry required only a single optical window is considered to be more suitable comparing with the conventional infrared absorption-emission pyrometry with two optical windows. Then, the former pyrometer is used to measure the mean gas temperatures averaged on an optical path (or cylinder diameter) of a spark ignition engine connected to a prechamber with a torch nozzle of various area sizes. These measured temperature-crankangle diagrams not only clarify the influences of torch jet flow on the combustion processes, but also correspond well to the heat release rates calculated from the pressure diagrams.

Aldehydes and ketones are known as one of the hazardous air pollutants. Usually, acidified 2,4-dinitrophenylhydrazine (DNPH) solution, or DNPH-impregnated cartridges are used for automotive exhaust carbonyls collection. Then, aldehydes and ketones combined with DNPH are analyzed by HPLC/UV (High Performance Liquid Chromatography/ Ultra Violet Detection). DNPH cartridge is used widely for a good point of the handling although handling of DNPH solution is not so convienient. However, the analytical result of acrolein using DNPH cartridge was known as the low reliability. Acrolein-DNPH is changed to acrolein-DNPH-DNPH in the cartridge with acid atmosphere before extraction. And then, acrorein-DNPH-DNPH is changed to acrorein-DNPH-DNPH-DNPH with an acid atmosphere. As a result of such chemical reaction before extraction, the acrolein-DNPH is detected to low concentration. We found that at the low temperature condition, acrolein-DNPH concentration decrease speed is held down.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

A 2-LEG NOx Storage-Reduction (NSR) catalyst system is one of potential after-treatment technology to meet stringent NOx and PM emissions standards as Post New Long Term (Japanese 2009 regulation) and US'10. Concerning NOx reduction using NSR catalyst, a secondary fuel injection is necessary to make fuel-rich exhaust condition during the NOx reduction, and causes its fuel penalty. Since fuel injected in the high-temperature (∼250 degrees Celsius) exhaust instantly reacts with oxygen in common diesel exhaust, the proportion of fuel consumption to reduce the NOx stored on NSR catalyst is relatively small. A 2-LEG NSR catalyst system has the decreasing exhaust flow mechanism during NOx reduction, and the potential to improve the NOx reduction and fuel penalty. Therefore, this paper studies the 2-LEG NSR catalyst system. The after-treatment system consists of NSR catalysts, a secondary fuel injection system, flow controlled valves and a Catalyzed Diesel Particulate Filter (CDPF).

In the Japanese heavy duty truck market, demands of improved fuel economy and lighter vehicles to increase load capacity, and further improvements in emissions are constantly increasing. To satisfy these requirements, basically a smaller sized and higher boosted diesel engine is effective, because such an engine has a compact size and light weight, and shows improved fuel consumption due to a relatively lower frictional loss. On the basis of this concept Hino introduced the original EP100 in 1981 as the first Japanese turbocharged and air to air charge-cooled engine. Since then Hino has made many efforts to improve the engines and develop new technologies.

Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.

An on board burner that enables DPF regeneration even when an engine is at standstill has been researched. By employing pre evaporative combustion with a wick burner, miniaturization of the burner system was successfully accomplished as well as stable ignition and combustion. Total heat necessary for DPF regeneration was reduced in comparison to the active DPF regeneration by means of engine control and an oxidation catalyst. Uneven temperature distribution in DPF and excessive temperature rise, which had been recognized as issues in the regeneration of a DPF while engine is at standstill, were solved by increase of combustion air amount and multi-step control of regeneration temperature and reliable regeneration was accomplished.

This paper is an attempt to estimate the traffic demand of private vehicles in the Philippines and Thailand toward 2030. Estimation of road traffic volume is one of the most important elements for determining fuel consumption and emission gas levels. The level of passenger car ownership is still low, but there has been a distinct shift toward passenger cars due to the lack of mass transport. In Asian countries, inspection and maintenance and emission standards are the most important policy measures. The projections of car stock are evaluated as the emissions of PM, CO and NOx by applying these policy measures in the case of Thailand.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

This work investigated the mechanism of oil dilution by post injection to remove accumulated particulate matter on the diesel particulate filter of diesel engines. We developed a model to simulate post injection spray under low ambient gas pressure conditions. The model can predict the quantity of fuel mass adhered on the cylinder wall. The adhered fuel enters oil sump through the piston ring and cause oil dilution. The fuel in diluted oil evaporates during normal engine operations. We focus on the mechanism of fuel evaporation from diluted oil. The effects of engine speed and oil temperature on the evaporation were investigated. The results showed that the fuel evaporation rate increases with increasing engine speed and oil temperature. Furthermore, we developed an empirical model to predict the fuel evaporation rate of diluted oil through regression analysis with measured data.

For the better understanding of nanoparticles observed on the rode side, adding to the emission test on the chassis dynamometer and engine dynamometer test, possible factors for formation of nanoparticles are investigated. As other possible factors, cold starting of transient test cycle, blow-by gas from heavy duty diesel engine without a positive crankcase ventilation, exhaust braking, and plume mixing of vehicle exhausts were investigated. Nuclei mode particles under the transient test cycles formed during fuel cut period, fuel enrichment period and idling period. Concentration of nuclei mode particles during the idling period are depends on exhaust temperature. The higher exhaust temperature courses the lower number concentration but variation range is within twice. Emission rate of nanoparticles from blow-by gas is one thousandth of tail pipe emissions rate and was found to be negligible.

The correlation between newly approved EN 15751 and the internal diesel injector deposits (IDID) due to fuel oxidative deterioration has not been made clear. In the present research, the Rancimat method was slightly modified to research the relationship between fuel oxidative deterioration and the deterioration products generated from the fuel. After heating fuel at 120 to 150°C for a set period, insoluble deterioration products (IDID-like substances) were generated and their weights were measured. At the same time, the shifts of the conductivity in trap water were analyzed from a new perspective, and its relationship with the deterioration products was investigated. At 120°C and 130°C, conductivity rising rates after the inflection point (this set of data represents the rate of organic acid generation in the fuel, and we named “Oxidation rate”) exhibited a strong correlation with the quantity of deterioration products.