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Technical Paper

Validity of Low Ventilation for Accident Processing with Hydrogen Leakage from Hydrogen-Fuelled Vehicle

2013-04-08
2013-01-0211
Appropriate emergency response information is required for first responder before hydrogen fuel cell vehicles will become widespread. This paper investigates experimentally the hydrogen dispersion in the vicinity of a vehicle which accidentally releases hydrogen horizontally with a single volumetric flow of 2000 NL/min in the under-floor section while varying cross and frontal wind effects. This hydrogen flow rate represents normally a full throttle power condition. Forced wind was about maximum 2 m/s. The results indicated that the windward side of the vehicle was safe but that there were chiefly two areas posing risks of fire by hydrogen ignition. One was the leeward side of the vehicle's underbody where a larger region of flammable hydrogen dispersion existed in light wind than in windless conditions. The other was the area around the hydrogen leakage point where most of the leaked hydrogen remained undiffused in an environment with a wind of no stronger than 2 m/s.
Journal Article

Validation of the Localized Fire Test Method for On-Board Hydrogen Storage Systems

2014-04-01
2014-01-0421
The localized fire test provided in the Global Technical Regulation for Hydrogen Fuel Cell Vehicles gives two separate test methods: the ‘generic installation test - Method 1′ and the ‘specific vehicle installation test - Method 2′. Vehicle manufacturers are required to apply either of the two methods. Focused on Method 2, the present study was conducted to determine the characteristics and validity of Method 2. Test results under identical burner flame temperature conditions and the effects of cylinder protection covers made of different materials were compared between Method 1 and Method 2.
Technical Paper

Thermal Behavior in Hydrogen Storage Tank for Fuel Cell Vehicle on Fast Filling

2007-04-16
2007-01-0688
The current hydrogen storage systems for fuel-cell vehicles are mainly a compressed hydrogen storage type, but it is known that the temperature inside the tank commonly increases while the tank is being filled with hydrogen. This study examines filling methods that prevent the temperature from exceeding the designed temperature of the tank. In order to propose a filling method that suppresses the temperature rise inside the tank and achieves filling within a short time, fast-filling tests were conducted on test tanks designed for fast filling of fuel cell vehicles. The detailed influences of the differences in type of tank and filling pressure on the rate of the internal temperature increase were investigated. Thermal responses were measured at various parts inside and outside the tank while varying the filling pressure, type of tank, tank capacity, filling time, and filling pattern, using a test tank that allows multi-point measurement of the internal temperature.
Technical Paper

Techno-Economic Analysis of Solar Hybrid Vehicles Part 1: Analysis of Solar Hybrid Vehicle Potential Considering Well-to-Wheel GHG Emissions

2016-04-05
2016-01-1287
In recent years, automakers have been developing various types of environmentally friendly vehicles such as hybrid (HV), plug-in hybrid (PHV), electric (EV), and fuel cell (FCV) vehicles to help reduce greenhouse gas (GHG) emissions. However, there are few commercial solar vehicles on the market. One of the reasons why automakers have not focused attention on this area is because the benefits of installing solar modules on vehicles under real conditions are unclear. There are two difficulties in measuring the benefits of installing solar modules on vehicles: (1) vehicles travel under various conditions of sunlight exposure and (2) sunlight exposure conditions differ in each region. To address these problems, an analysis was performed based on an internet survey of 5,000 people and publically available meteorological data from 48 observation stations in Japan.
Journal Article

Study of Oxide Supports for PEFC Catalyst

2017-03-28
2017-01-1179
Polymer electrolyte membrane fuel cell (PEFC) systems for fuel cell vehicles (FCVs) require both performance and durability. Carbon is the typical support material used for PEFC catalysts. However, hydrogen starvation at the anode causes high electrode potential states (e.g., 1.3 V with respect to the reversible hydrogen electrode) that result in severe carbon support corrosion. Serious damage to the carbon support due to hydrogen starvation can lead to irreversible performance loss in PEFC systems. To avoid such high electrode potentials, FCV PEFC systems often utilize cell voltage monitor systems (CVMs) that are expensive to use and install. Simplifying PEFC systems by removing these CVMs would help reduce costs, which is a vital part of popularizing FCVs. However, one precondition for removing CVMs is the adoption of a durable support material to replace carbon.
Technical Paper

Safety Evaluation on Fuel Cell Stacks Fire and Toxicity Evaluation of Material Combustion Gas for FCV

2007-04-16
2007-01-0435
Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.
Journal Article

Research on Ultra-High Viscosity Index Engine Oil: Part 1 - “Flat Viscosity” Concept and Contribution to Carbon Neutrality

2022-03-29
2022-01-0525
In recent years, the realization of carbon neutrality has become an activity to be tackled worldwide, and automobile manufacturers are promoting electrification of power train by HEV, PHEV, BEV and FCEV. Although interest in BEV is currently growing, vehicles equipped with internal combustion engines (ICE) including HEV and PHEV will continue to be used in areas where conversion to BEV is not easy due to lack of sufficient infrastructures. For such vehicles, low-viscosity engine oil will be one of the most important means to contribute to further reduction of CO2 emissions. Since HEV requires less work from the engine, the engine oil temperature is lower than that of conventional engine vehicles. Therefore, the reduction of viscous resistance in the mid-to-low temperature range below 80°C is expected to contribute more to fuel economy. On the other hand, the viscosity must be kept above a certain level to ensure the performance of hydraulic devices in the high oil temperature range.
Journal Article

PEFC Performance Improvement Methodology for Vehicle Applications

2012-04-16
2012-01-1232
For over a decade and a half, Toyota Motor Corporation has been developing fuel cell vehicles (FCVs) and is continuing various approaches to enable mass production. This study used new methods to quantitatively observe some of the mass transfer phenomena in the reaction field, such as oxygen transport, water drainage, and electronic conductivity. The obtained results are applicable to the design requirements of ideal reaction fields, and have the potential to assist to reduce the size of the fuel cell.
Journal Article

In-Situ Liquid TEM Study on the Degradation Mechanism of Fuel Cell Catalysts

2016-04-05
2016-01-1192
Electrode catalyst (platinum) degradation represents a major challenge to the performance and durability of polymer electrolyte membrane fuel cells (PEMFCs) in Fuel Cell Vehicles (FCVs). While various mechanisms have been proposed and investigated previously, there is still a need to develop in situ imaging techniques that can characterize and provide direct evidence to confirm the degradation process. In the present study, we report an in situ transmission electron microscopy (TEM) method that enables real time, high-resolution observation of carbon-supported platinum nanoparticles in liquid electrolyte under working conditions. By improving the design of the Micro Electro Mechanical Systems (MEMS) sample holder, the migration and aggregation of neighboring platinum nanoparticles could be visualized consistently and correlated to applied electrode potentials during aging process (i.e., cyclic voltammetry cycles).
Technical Paper

High-Pressure Hydrogen-Absorbing Alloy Tank for Fuel Cell Vehicles

2010-04-12
2010-01-0851
Multi-cylinder hydrogen-absorbing alloy tanks for fuel cell vehicles have 10 to 40 metallic cylinders that are bundled and filled with hydrogen-absorbing alloy. In this system, the cylinders themselves act as a heat exchanger and the working pressure is lowered to 10 to 20 MPa compared with high-pressure MH tanks. Moreover, both heat conduction and mass reduction can be achieved by reducing the wall thickness of the cylinders. A model verification experiment was conducted using a one-quarter-scale prototype of a full size tank, and a conduction simulation model verified in the experiment was used to predict the performance of the full size tank. Results showed that it is possible to fill the tank with hydrogen to 80% of its capacity in a five-minute filling time, although issues related to heat conductivity performance require improvement. Accordingly, it may be possible to adopt this tank as part of a system if the storage amount of the hydrogen-absorbing alloy can be increased.
Technical Paper

Establishing Localized Fire Test Methods and Progressing Safety Standards for FCVs and Hydrogen Vehicles

2011-04-12
2011-01-0251
The SAE Fuel Cell Vehicle (FCV) Safety Working Group has been addressing FCV safety for over 11 years. In the past couple of years, significant attention has been directed toward a revision to the standard for vehicular hydrogen systems, SAE J2579(1). In addition to streamlining test methodologies for verification of Compressed Hydrogen Storage Systems (CHSSs) as discussed last year,(2) the working group has been considering the effect of vehicle fires, with the major focus on a small or localized fire that could damage the container in the CHSS and allow a burst before the Pressure Relief Device (PRD) can activate and safely vent the compressed hydrogen stored from the container.
Technical Paper

Enhancing PtCo Electrode Catalyst Performance for Fuel Cell Vehicle Application

2016-04-05
2016-01-1187
While carbon supported PtCo alloy nanoparticles emerged recently as the new standard catalyst for oxygen reduction reaction in polymer membrane electrolyte fuel cells, further improvement of catalyst performance is still of great importance to its application in fuel cell vehicles. Herein, we report two examples of such efforts, related to the improvements of catalyst preparation and carbon support design, respectively. First, by lowering acid treatment voltage, the effectiveness for the removal of unalloyed Co was enhanced significantly, leading to less Co dissolution during cell operation and about 40% higher catalyst mass activity. It has been also found that the use of nonporous carbon support material promoted mass transfer and resulted in substantial drop of overpotential at high current and low humidity. This result may suggest an effective strategy towards the development of fuel cell systems that operate without additional humidification.
Technical Paper

Development of the Fuel Cell System in the Mirai FCV

2016-04-05
2016-01-1185
Toyota Motor Corporation (TMC) has been developing fuel cell (FC) system technology since 1992. In 2008 the Toyota "FCHV-adv" was released as part of a demonstration program. It established major improvements in key performance areas such as cold start/drive capability, efficiency, driving range, and durability. However, in order to facilitate the commercial widespread adoption of fuel cell vehicles (FCVs), improvements in performance and further reductions in size and cost were required.In December 2014, Toyota launched the world’s first commercially available fuel cell vehicle (FCV) the "Mirai" powered by the Toyota Fuel Cell System (TFCS). Simplicity, reliability and efficiency have been significantly improved within the Toyota TFCS. As a result, the Mirai has become an attractive vehicle which could lead the way towards full-scale popularization of FCVs.
Journal Article

Development of Transaxle Fluid for Electrification Vehicles: Design of Novel Additive Formulation

2022-08-30
2022-01-1102
To achieve carbon neutrality by reducing carbon dioxide (CO2) emissions, vehicles with an internal combustion engine have started to be replaced by electrification vehicles such as hybrid electric vehicles (HEVs), plug-in HEVs (PHEVs), and battery EVs (BEVs) worldwide, which have motors in their transaxles (T/As). Reducing transmission torque loss in the transaxles is effective to reduce CO2 emissions, and lowering the viscosity of lubrication fluids in T/As is a promising method for reducing churning and drag loss. However, lowering viscosity generally leads to thin oil films and makes the lubrication condition severe, resulting in worse anti-fatigue and anti-seizure performance. To deal with these issues, we made improvements on the additive formulation of fluid, such as the addition of an oil-film-forming polymer, chemical structure change of calcium detergents, and an increase of anti-wear additives including phosphorus and sulfur.
Technical Paper

Development of Thermoplastic CFRP for Stack Frame

2016-04-05
2016-01-0532
Weight reduction for a fuel cell vehicle (FCV) is important to contribute a long driving range. One approach to reduce vehicle weight involves using a carbon fiber reinforced plastic (CFRP) which has a high specific strength and stiffness. However, a conventional thermoset CFRP requires a long chemical reaction time and it is not easy to introduce into mass production vehicles. In this study, a new compression-moldable thermoplastic CFRP material for mass production body structural parts was developed and applied to the stack frame of the Toyota Mirai.
Technical Paper

Development of Safety Performance for FC Stack in the New Toyota FCEV

2022-03-29
2022-01-0686
The new Toyota Mirai hydrogen fuel cell electric vehicle (FCEV) was launched in December 2020. Achieving a low-cost, high-performance FC stack is an important objective in FCEV development. At the same time, it is also necessary to ensure vehicle safety. This paper presents an overview of the safety requirements for onboard FC stacks. It also describes the simulation and evaluation methods for the following matters related to the FC stack. i) Impact force resistance: The FC stack was designed to prevent cell layer slippage due to impact. Constraint force between the cell layers is provided by the frictional force between the cells and an external constraint. A simulation of the behavior of the cell layers under impact force was developed. The impact force resistance was confirmed by an impact loading test. ii) Hydrogen safety: The FC stack was designed so that permeated hydrogen is ventilated and the hydrogen concentration is kept below the standard.
Technical Paper

Development of Next Generation Fuel-Cell Hybrid System - Consideration of High Voltage System -

2004-03-08
2004-01-1304
Toyota Motor Corporation began leasing a new generation fuel cell vehicle the FCHV (Fuel Cell Hybrid Vehicle) in December 2002. That vehicle includes a new variable voltage power electronics system and uses the Nickel Metal Hydride (Ni-MH) battery system from the Prius hybrid gasoline electric vehicle. This paper describes on-going efforts to model optimum secondary storage systems for future vehicles. Efficiency modeling is presented for the base Ni-MH storage system, an ultra capacitor system and a Lithium ion (Li-ion) battery system. The Li-ion system in combination with a new high efficiency converter shows a 4% improvement in fuel economy relative to the base system. The ultra capacitor system is not as efficient as the base system.
Technical Paper

Development of New Motor for Electric Vehicles

2024-04-09
2024-01-2206
The world is currently facing environmental issues such as global warming, air pollution, and high energy demand. To mitigate these challenges, the electrification of vehicles is essential as it is effective for efficient fuel utilization and promotion of alternative fuels. The optimal approach for electrification varies across different markets, depending on local energy conditions and current circumstances. Consequently, Toyota has taken the initiative to offer a comprehensive lineup of battery electric vehicles (BEV), hybrid electric vehicles (HEV), plug-in hybrid electric vehicles (PHEV), and fuel cell electric vehicles (FCEV), aiming to provide sustainable solutions tailored to the unique situations and needs of each region. As part of this effort, Toyota has developed the 5th generation of hybrid electric vehicles. This paper describes the electric motor used in the new Toyota Camry which achieves high torque, high power, low losses, and compact design.
Technical Paper

Development of High-Performance FC Stack for the New MIRAI

2021-04-06
2021-01-0740
The first MIRAI was launched in 2014 as the world’s first commercial fuel cell vehicle (FCV) [1]. Compared to the FC stack used in the first MIRAI, the FC stack in the new MIRAI achieved one of the highest volumetric power densities in the world (5.4 kW/L, excluding end plates, 1.5 times higher than the FC stack in the first MIRAI) by adopting a new flow channel for the bipolar plate and an improved electrode [2]. Enhancing the current density is an important means of increasing power performance and reducing size. The bipolar plate functions to distribute gas and drain water inside the cells to stabilize current generation. However, a conventional straight flow channel tends to cause flooding, which makes it difficult to maintain stable current generation. A partially narrow flow channel was developed to enhance oxygen diffusion without the 3D fine-mesh flow field that was adopted in the previous FC stack.
Technical Paper

Development of Fuel Consumption Measurement Methods for Hydrogen Fuel Cell Vehicles

2006-04-03
2006-01-0217
Japan Automobile Research Institute has devised and evaluated the various fuel consumption measurement methods for fuel cell vehicles (FCVs). The examination covers the methods based on measurement of electrical current, hydrogen pressure/temperature, weight and flow rate that are expected to be the same accuracy and convenience as conventional measurement methods such as carbon balance method or fuel flow measurement method. As a result of examining the measurement accuracy for each method with a sonic nozzle used as a standard, it is found that both the pressure method and the weight method fulfill the target accuracy of ±1% and that the flow method is able to improve the accuracy by means of calibration with hydrogen. Also, as a result of applying each method to the fuel consumption test of FCVs, the relative error between the pressure method and weight method is within ±1%.
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