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The potential peaking of world conventional oil production and the possible imperative to reduce carbon emissions will put great pressure on vehicle manufacturers to produce more efficient vehicles, on vehicle buyers to seek them out in the marketplace, and on energy suppliers to develop new fuels and delivery systems. Four cases for stabilizing or reducing light vehicle fuel use, oil use, and/or carbon emissions over the next 50 years are presented. Case 1 - Improve mpg so that the fuel use in 2020 is stabilized for the next 30 years. Case 2 - Improve mpg so that by 2030 the fuel use is reduced to the 2000 level and is reduced further in subsequent years. Case 3 - Case 1 plus 50% ethanol use and 50% low-carbon fuel cell vehicles by 2050. Case 4 - Case 2 plus 50% ethanol use and 50% low-carbon fuel cell vehicles by 2050. The mpg targets for new cars and light trucks require that significant advances be made in developing cost-effective and very efficient vehicle technologies.

The National Renewable Energy Laboratory (NREL) collaborated with Millennium Cell and DaimlerChrysler to study heat and water management in a sodium borohydride (NaBH4) storage/processor used to supply hydrogen to a fuel cell in an automotive application. Knowledge of heat and water flows in this system is necessary to maximize the storage concentration of NaBH4, which increases vehicle range. This work helps evaluate the NaBH4 system's potential to meet the FreedomCAR program technical target of 6 wt% hydrogen for hydrogen storage technologies. This paper also illustrates the advantages of integrating the NaBH4 hydrogen processor with the fuel cell.

The impacts of fuel cell system power response capability on optimal hybrid and neat fuel cell vehicle configurations have been explored. Vehicle system optimization was performed with the goal of maximizing fuel economy over a drive cycle. Optimal hybrid vehicle design scenarios were derived for fuel cell systems with 10 to 90% power transient response times of 0, 2, 5, 10, 20, and 40 seconds. Optimal neat fuel cell vehicles where generated for responses times of 0, 2, 5, and 7 seconds. DIRECT, a derivative-free optimization algorithm, was used in conjunction with ADVISOR, a vehicle systems analysis tool, to systematically change both powertrain component sizes and the vehicle energy management strategy parameters to provide optimal vehicle system configurations for the range of response capabilities.

As part of a U.S. Department of Energy supported study, the National Renewable Energy Laboratory has benchmarked a Toyota Prius hybrid electric vehicle from three aspects: system analysis, auxiliary loads, and battery pack thermal performance. This paper focuses on the testing of the battery back out of the vehicle. More recent in-vehicle dynamometer tests have confirmed these out-of-vehicle tests. Our purpose was to understand how the batteries were packaged and performed from a thermal perspective. The Prius NiMH battery pack was tested at various temperatures (0°C, 25°C, and 40°C) and under driving cycles (HWFET, FTP, and US06). The airflow through the pack was also analyzed. Overall, we found that the U.S. Prius battery pack thermal management system incorporates interesting features and performs well under tested conditions.

A key to the success of the national hydrogen and fuel cell codes and standards developments efforts to date was the creation and implementation of national templates through which the U.S. Department of Energy (DOE), the National Renewable Energy Laboratory (NREL), and the major standards development organizations (SDOs) and model code organizations coordinate the preparation of critical standards and codes for hydrogen and fuel cell technologies and applications and maintain a coordinated national agenda for hydrogen and fuel cell codes and standards

Electrifying transportation can reduce or eliminate dependence on foreign fuels, emission of green house gases, and emission of pollutants. One challenge is finding a pathway for vehicles that gains wide market acceptance to achieve a meaningful benefit. This paper evaluates several approaches aimed at making plug-in electric vehicles (EV) and plug-in hybrid electric vehicles (PHEVs) cost-effective including opportunity charging, replacing the battery over the vehicle life, improving battery life, reducing battery cost, and providing electric power directly to the vehicle during a portion of its travel. Many combinations of PHEV electric range and battery power are included. For each case, the model accounts for battery cycle life and the national distribution of driving distances to size the battery optimally. Using the current estimates of battery life and cost, only the dynamically plugged-in pathway was cost-effective to the consumer.

Today's hybrid electric vehicle (HEV) controls do not necessarily provide maximum fuel savings over all drive cycles. An approach that employs route-based control could improve HEV efficiency at potentially minimal additional cost. This paper evaluates a range of route-based control approaches and identifies look-ahead strategies (using input from “on-the-fly” route predictions) as an area meriting further analysis. A novel implementation approach is developed and discussed, and a comparison with simulation results using an optimized general control setting indicates that fuel savings of approximately 2% to 4% can be obtained with route-based control. Given the increasing prevalence of GPS systems in vehicles, this advance has the potential to provide considerable aggregate fuel savings if applied across the entire national fleet. For instance, a 3% across-the-board reduction in HEV fuel use would save nearly 6.5 million gallons of fuel annually in the United States.

Both hydrogen and plug-in electric vehicles offer significant social and environmental benefits to enhance energy security and reduce criteria and greenhouse gas emissions from the transportation sector. However, the rollout of electric vehicle supply equipment (EVSE) and hydrogen retail stations (HRS) requires substantial investments with high risks due to many uncertainties. We compare retail infrastructure costs on a common basis - cost per mile, assuming fueling service to 10% of all light-duty vehicles in a typical 1.5 million person city in 2025. Our analysis considers three HRS sizes, four distinct types of EVSE and two distinct EVSE scenarios. EVSE station costs, including equipment and installation, are assumed to be 15% less than today's costs. We find that levelized retail capital costs per mile are essentially indistinguishable given the uncertainty and variability around input assumptions.

The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).

Hydrogen fuel cell vehicles (FCVs) appear to be a promising solution for the future of clean and efficient personal transportation. Issues of how to generate the hydrogen and then store it on-board to provide satisfactory driving range must still be resolved before they can compete with conventional vehicles. Alternatively, FCVs could obtain hydrogen from on-board reforming of gasoline or other fuels such as methanol or ethanol. On-board reformers convert fuel into a hydrogen-rich fuel stream through catalytic reactions in several stages. The high temperatures associated with fuel processing present an engineering challenge to warm up the reformer quickly and efficiently in a vehicle environment. Without a special warmup phase or vehicle hybridization, the reformer and fuel cell system must provide all power to move the vehicle, including ¼ power in 30 s, and ½ power in 3 min to satisfy the Federal Test Procedure (FTP) cycle demands.

We have conducted experiments on 16 lunar soils and 3 lunar volcanic glass samples to study the extraction of oxygen, an important resource for future lunar bases. The samples were chosen to span the range of composition and mineralogy represented in the Apollo collection. Each sample was reduced in flowing hydrogen for 3 hours at 1050°C. The dominant effect was reduction of Fe2+ (as FeO) in minerals and glass to iron metal, with concomitant release of oxygen. Oxygen extraction was strongly correlated with initial Fe2+ abundance but varied among mineral and glass phases. The experimental reduction of lunar soil and glass provides a method for assessing the oxygen production potential for sites on the lunar surface from lunar orbit. Our results show that oxygen yield from lunar soils can be predicted from knowledge of only one parameter, total iron content. This parameter can be measured from orbit by gamma ray spectrometry or multispectral imaging.

Battery electric vehicles possess great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Characterized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations are well positioned to leverage the low operating costs of battery electric vehicles. Unfortunately, the range limitation of commercially available battery electric vehicles acts as a barrier to widespread adoption. This paper describes the National Renewable Energy Laboratory's collaboration with the U.S. Department of Energy and industry partners to analyze the use of small hydrogen fuel-cell stacks to extend the range of battery electric vehicles as a means of improving utility, and presumably, increasing market adoption.

The Major Constituent Analyzer (MCA) was activated on-orbit on 2/13/01 and provided essentially continuous readings of partial pressures for oxygen, nitrogen, carbon dioxide, methane, hydrogen and water in the ISS atmosphere. The MCA plays a crucial role in the operation of the Laboratory ECLSS and EVA operations from the airlock. This paper discusses the performance of the MCA as compared to specified accuracy requirements. The MCA has an on-board self-calibration capability and the frequency of this calibration could be relaxed with the level of instrument stability observed on-orbit. This paper also discusses anomalies the MCA experienced during the first year of on-orbit operation. Extensive Built In Test (BIT) and fault isolation capabilities proved to be invaluable in isolating the causes of anomalies. The process of fault isolation is discussed along with development of workaround solutions and implementation of permanent on-orbit corrections.

Polymers are one of the major constituents in electrical components. A study investigating pre-combustion off-gassing and particle release by polymeric materials over a range of temperatures can provide an understanding of thermal degradation prior to failure which may result in a fire hazard. In this work, we report simultaneous measurements of pre-combustion vapor and particle release by heated polymeric materials. The polymer materials considered for the current study are silicone and Kapton. The polymer samples were heated over the range 20 to 400°C. Response to vapor releases were recorded using the JPL Electronic Nose (ENose) and Industrial Scientific's ITX gas monitor configured to detect hydrogen chloride (HCl), carbon monoxide (CO) and hydrogen cyanide (HCN). Particle release was monitored using a TSI P-TRAK particle counter.

This paper describes the design and construction of a fuel cell hybrid electric vehicle based on the conversion of a five passenger production sedan. The vehicle uses a relatively small fuel cell stack to provide average power demands, and a battery pack to provide peak power demands for varied driving conditions. A model of this vehicle was developed using ADVISOR, an Advanced Vehicle Simulator that tracks energy flow and fuel usage within the vehicle drivetrain and energy conversion components. The Virginia Tech Fuel Cell Hybrid Electric Vehicle was tested on the EPA City and Highway driving cycles to provide data for validation of the model. Vehicle data and model results show good correlation at all levels and show that ADVISOR has the capability to model fuel cell hybrid electric vehicles.

This paper presents multiple methods for predicting heavy/medium-duty vehicle fuel consumption based on driving cycle information. A polynomial model, a black box artificial neural net model, a polynomial neural network model, and a multivariate adaptive regression splines (MARS) model were developed and verified using data collected from chassis testing performed on a parcel delivery diesel truck operating over the Heavy Heavy-Duty Diesel Truck (HHDDT), City Suburban Heavy Vehicle Cycle (CSHVC), New York Composite Cycle (NYCC), and hydraulic hybrid vehicle (HHV) drive cycles. Each model was trained using one of four drive cycles as a training cycle and the other three as testing cycles. By comparing the training and testing results, a representative training cycle was chosen and used to further tune each method.

Currently, several cost-per-mile calculators exist that can provide estimates of acquisition and operating costs for consumers and fleets. However, these calculators are limited in their ability to determine the difference in cost per mile for consumer versus fleet ownership, to calculate the costs beyond one ownership period, to show the sensitivity of the cost per mile to the annual vehicle miles traveled (VMT), and to estimate future increases in operating and ownership costs. Oftentimes, these tools apply a constant percentage increase over the time period of vehicle operation, or in some cases, no increase in direct costs at all over time. A more accurate cost-per-mile calculator has been developed that allows the user to analyze these costs for both consumers and fleets. Operating costs included in the calculation tool include fuel, maintenance, tires, and repairs; ownership costs include insurance, registration, taxes and fees, depreciation, financing, and tax credits.

This research project compares the in-use and laboratory-derived fuel economy of a medium-duty hybrid electric drivetrain with “engine off at idle” capability to a conventional drivetrain in a typical commercial package delivery application. Vehicles in this study included eleven model year 2010 Freightliner P100H hybrids that were placed in service at a United Parcel Service (UPS) facility in Minneapolis, Minn., during the first half of 2010. These hybrid vehicles were evaluated for 18 months against eleven model year 2010 Freightliner P100D diesels that were placed in service at the same facility a couple months after the hybrids. Both vehicle study groups use the same model year 2009 Cummins ISB 200 HP engine. The vehicles of interest were chosen by comparing the average daily mileage of the hybrid group to that of a similar size and usage diesel group.

This research focuses on the technical issues that are critical to the adoption of high-energy-producing lithium Ion batteries. In addition to high energy density / high power density, this publication considers performance requirements that are necessary to assure lithium ion technology as the battery format of choice for electrified vehicles. Presentation of prime topics includes: • Long calendar life (greater than 10 years) • Sufficient cycle life • Reliable operation under hot and cold temperatures • Safe performance under extreme conditions • End-of-life recycling To achieve aggressive fuel economy standards, carmakers are developing technologies to reduce fuel consumption, including hybridization and electrification. Cost and affordability factors will be determined by these relevant technical issues which will provide for the successful implementation of lithium ion batteries for application in future generations of electrified vehicles.

In 2011, the United States imported almost half of its petroleum. Lightweighting vehicles reduces that dependency directly by decreasing the engine, braking and rolling resistance losses, and indirectly by enabling a smaller, more efficiently operating engine to provide the same performance. The Future Automotive Systems Technology Simulator (FASTSim) tool was used to quantify these impacts. FASTSim is the U.S. Department of Energy's (DOE's) high-level vehicle powertrain model developed at the National Renewable Energy Laboratory. It steps through a time versus speed drive cycle to estimate the powertrain forces required to meet the cycle. It simulates the major vehicle powertrain components and their losses. It includes a cost model based on component sizing and fuel prices. FASTSim simulated different levels of lightweighting for four different powertrains.