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In order to provide effective cooling for astronauts during extravehicular activities (EVAs), a liquid cooling and ventilation garment (LCVG) is used to remove heat by a series of tubes through which cooling water is circulated. To better predict the effectiveness of the LCVG and determine possible modifications to improve performance, computer simulations dealing with the interaction of the cooling garment with the human body have been run using the Wissler Human Thermal Model. Simulations have been conducted to predict the heat removal rate for various liquid cooled garment configurations. The current LCVG uses 48 cooling tubes woven into a fabric with cooling water flowing through the tubes. The purpose of the current project is to decrease the overall weight of the LCVG system. In order to achieve this weight reduction, advances in the garment heat removal rates need to be obtained.

Spacecraft thermal control systems are essential to provide the necessary thermal environment for the crew and to ensure that the equipment functions adequately on space missions. The Ultralight Fabric Reflux Tube (UFRT) was developed by the Pacific Northwest National Laboratory as a lightweight radiator concept to be used on planetary surface-type missions (e.g., Moon, Mars). The UFRT consists of a thin-walled tube (acting as the fluid boundary), overwrapped with a low-mass ceramic fabric (acting as the primary pressure boundary). The tubes are placed in an array in the vertical position with the evaporators at the lower end. Heat is added to the evaporators, which vaporizes the working fluid. The vapor travels to the condenser end section and condenses on the inner wall of the thin-walled tube. The resulting latent heat is radiated to the environment. The fluid condensed on the tube wall is then returned to the evaporator by gravity.

The Trace Gas Analyzer (TGA, Figure 1) is a self-contained, battery-powered mass spectrometer that is designed for use by astronauts during extravehicular activities (EVA) on the International Space Station (ISS). The TGA contains a miniature quadrupole mass spectrometer array (QMSA) that determines the partial pressures of ammonia, hydrazines, nitrogen, and oxygen. The QMSA ionizes the ambient gas mixture and analyzes the component species according to their charge-to-mass ratio. The QMSA and its electronics were designed, developed, and tested by the Jet Propulsion Laboratory (1,2). Oceaneering Space Systems supported JPL in QMSA detector development by performing 3D computer for optimal volumetric integration, and by performing stress and thermal analyses to parameterize environmental performance.

The Orbiting Carbon Observatory (OCO) instrument is scheduled for launch onboard an Orbital Sciences Corporation LEOStar-2 architecture spacecraft in December 2008. The instrument will collect data to identify CO2 sources and sinks and quantify their seasonal variability. OCO observations will permit the collection of spatially resolved, high resolution spectroscopic observations of CO2 and O2 absorption in reflected sunlight over both continents and oceans. OCO has three bore-sighted, high resolution, grating spectrometers which share a common telescope with similar optics and electronics. A 0.765 μm channel will be used for O2 observations, while the weak and strong CO2 bands will be observed with 1.61 μm and 2.06 μm channels, respectively. The OCO spacecraft circular polar orbit will be sun-synchronous with an inclination of 98.2 degrees, mean altitude of 705 km and 98.9 minute orbit period.

Flexible fiber-reinforced aerogel composites were studied for use as insulation materials of a future space suit for Moon and Mars exploration. High flexibility and good thermal insulation properties of fiber-reinforced silica aerogel composites at both high and low vacuum conditions make it a promising insulation candidate for the space suit application. This paper first presents the results of a durability (mechanical cycling) study of these aerogels composites in the context of retaining their thermal performance. The study shows that some of these Aerogels materials retained most of their insulation performance after up to 250,000 cycles of mechanical flex cycling. This paper also examines the problem of integrating these flexible aerogel composites into the current space suit elements.

A Small Loop Heat Pipe (SLHP) featuring a wick of only 1.27 cm (0.5 inches) in diameter has been designed for use in spacecraft thermal control. It has several features to accommodate a wide range of environmental conditions in both operating and non-operating states. These include flexible transport lines to facilitate hardware integration, a radiator capable of sustaining over 100 freeze-thaw cycles using ammonia as a working fluid and a structural integrity to sustain acceleration loads up to 30 g. The small LHP has a maximum heat transport capacity of 120 Watts with thermal conductance ranging from 17 to 21 W/°C. The design incorporates heaters on the compensation chamber to modulate the heat transport from full-on to full-stop conditions. A set of start up heaters are attached to the evaporator body using a specially designed fin to assist the LHP in starting up when it is connected to a large thermal mass.

For planetary exploration, new thermal insulation materials are needed to deal with unique environmental conditions presented to extravehicular activity (EVA). The thermal insulation material and system used in the existing space suit were specifically designed for low orbit environment. They are not adequate for low vacuum condition commonly found in planetary environments with a gas atmosphere. This study attempts to identify the types of lofty nonwoven thermal insulation materials and the construction parameters that yield the best performance for such application. Lofty nonwovens with different construction parameters are evaluated for their thermal conductivity performance. Three different types of fiber material: solid round fiber, hollow fiber, and grooved fiber, with various denier, needling intensity, and web density were evaluated.

This paper presents the analysis findings of a study reducing the overall mass of the lightweight liquid cooling garment (LCG). The LCG is a garment worn by crew to actively cool the body, for spacesuits and launch/entry suits. A mass reduction of 66% was desired for advanced missions. A thermal math model of the LCG was developed to predict its performance when various mass-reducing changes were implemented. Changes included varying the thermal conductivity and thickness of the garment or of the coolant tubes servicing the garment. A second model was developed to predict behavior of the suit when the cooling tubes were to be removed, and replaced with a highly-conducting (waterless) material. Findings are presented that show significant reductions in weight are theoretically possible by improving conductivity in the garment material.

A porous plate sublimator (based on an existing Lunar Module LM-209 design) is baselined as a heat rejection device for the X-38 vehicle due to its simplicity, reliability, and flight readiness. The sublimator is a passive device used for rejecting heat to the vacuum of space by sublimating water to obtain efficient heat rejection in excess of 1,000 Btu/lb of water. It is ideally suited for the X-38/CRV mission as it requires no active control, has no moving parts, has 100% water usage efficiency, and is a well-proven technology. Two sublimators have been built and tested for the X-38 program, one of which will fly on the NASA V-201 space flight demonstrator vehicle in 2001. The units satisfied all X-38 requirements with margin and have demonstrated excellent performance. Minor design changes were made to the LM-209 design for improved manufacturability and parts obsolescence.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

Hamilton Sundstrand has developed a scalable evaporative heat rejection system called the Multi-Fluid Evaporator (MFE). It was designed to support the Orion Crew Module and to support future Constellation missions. The MFE would be used from Earth sea level conditions to the vacuum of space. This system combines the functions of the Space Shuttle flash evaporator and ammonia boiler into a single compact package with improved freeze-up protection. The heat exchanger core is designed so that radial flow of the evaporant provides increasing surface area to keep the back pressure low. The multiple layer construction of the core allows for efficient scale up to the desired heat rejection rate. A full-scale unit uses multiple core sections that, combined with a novel control scheme, manage the risk of freezing the heat exchanger cores. A four-core MFE prototype was built in 2007.

Hamilton Sundstrand is under contract with the NASA Johnson Space Center to develop a scalable, evaporative heat rejection system called the Multi-Fluid Evaporator (MFE). It is being designed to support the Orion Crew Module and to support future Constellation missions. A MFE would be used from Earth sea level conditions to the vacuum of space. The current Space Shuttle configuration utilizes an ammonia boiler and flash evaporator system to achieve cooling at all altitudes. With the MFE system, both functions are combined into a single compact package with significant weight reduction and improved freeze-up protection. The heat exchanger core is designed so that radial flow of the evaporant provides increasing cross-sectional area to keep the back pressure low. Its multiple layer construction allows for efficient scale up to the desired heat rejection rate.

In a crewed spacecraft environment, atmospheric carbon dioxide (CO2) and moisture control are crucial. Hamilton Sundstrand has developed a stable and efficient amine-based CO2 and water vapor sorbent, SA9T, that is well suited for use in a spacecraft environment. The sorbent is efficiently packaged in pressure-swing regenerable beds that are thermally linked to improve removal efficiency and minimize vehicle thermal loads. Flows are all controlled with a single spool valve. This technology has been baselined for the new Orion spacecraft. However, more data was needed on the operational characteristics of the package in a simulated spacecraft environment. A unit was therefore tested with simulated metabolic loads in a closed chamber at Johnson Space Center during the last third of 2006. Tests were run at a variety of cabin temperatures and with a range of operating conditions varying cycle time, vacuum pressure, air flow rate, and crew activity levels.

This paper reports several slow reversible and quasi-reversible processes which occur in the porous electrode/solid electrolyte combination at AMTEC operating temperatures. These processes help to elucidate the evolution of the electrode and electrolyte characteristics with time. They also demonstrate that the atomic constituents of the electrode/electrolyte engage in significant dynamic motion. We report the stability of the sodium beta“-alumina phase in low pressure sodium vapor at 1173K up to 3000 hours, and the decomposition of the sodium meta-aluminate (NaAlO2) phase present at about 1% in the BASE ceramic, which gives rise to transient local increases in the solid electrolyte resistivity due to local micro-cracking. We also report slow apparent morphological changes, possibly surface or grain boundary reconstruction, in TiN and RhW electrodes driven by changes in the local sodium activity.

As a result of the Viking missions in 1970s, the presence of a strong oxidant in Martian soil was suggested. Here we present a testable, by near-term missions, hypothesis that iron(VI) contributes to that oxidizing pool. Ferrate(VI) salts were studied for their spectral and oxidative properties and biological activities. Ferrate(VI) has distinctive spectroscopic features making it available for detection by remote sensing reflectance spectra and contact measurements via Mössbauer spectroscopy. The relevant miniaturized instrumentation has been developed or is underway, while XANES spectroscopy is shown to be a method of choice for the returned samples. Ferrate(VI) is capable of splitting water to yield oxygen, and oxidizing organic carbon to CO2. Organic oxidation was strongly abated after pre-heating ferrate, similar to the observations with Mars soil samples.

The overall goal of this program was the development of a 10 m. diameter, self-deployable antenna based on an open-celled rigid polyurethane foam system. Advantages of such a system relative to current inflatable or self-deploying systems include high volumetric efficiency of packing, high restoring force, low (or no) outgassing, low thermal conductivity, high dynamic damping, mechanical isotropy, infinite shelf life, and easy fabrication with methods amenable to construction of large structures (i.e., spraying). As part of a NASA Phase II SBIR, Adherent Technologies and its research partners, Temeku Technologies, and NASA JPL/Caltech, conducted activities in foam formulation, interdisciplinary analysis, and RF testing to assess the viability of using open cell polyurethane foams for self-deploying antenna applications.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

Mixing controlled compression ignition, i.e., diesel engines are efficient and are likely to continue to be the primary means for movement of goods for many years. Low-net-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could have advantageous properties for combustion, such as high cetane number and reduced engine-out particle and NOx emissions. We developed a list of over 400 potential biomass-derived diesel blendstocks and populated a database with the properties and characteristics of these materials. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a blendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number ≥40, flashpoint ≥52°C, and boiling point or T90 ≤338°C.

The NASA Johnson Space Center has plans to integrate a Solid Amine Water Desorbed (SAWD II) carbon dioxide removal subsystem into the Variable Pressure Growth Chamber (VPGC). The SAWD II subsystem will be used to remove any excess carbon dioxide (CO2) input into the VPGC which is not assimilated by the plants growing in the chamber. An analysis of the integrated VPGC-SAWD II system was performed using a mathematical model of the system implemented in the Computer-Aided System Engineering and Analysis (CASE/A) package. The analysis consisted of an evaluation of the SAWD II subsystem configuration within the VPGC, the planned operations for the subsystem, and the overall performance of the subsystem and other VPGC subsystems. Based on the model runs, recommendations were made concerning the SAWD II subsystem configuration and operations, and the chambers' automatic CO2 injection control subsystem.

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.