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Since 2005, Alcoa Fastening Systems (AFS) and Lockheed Martin have been partnering to identify a Cadmium (Cd) plating replacement for threaded fasteners. Previously reported Phase I, II and III studies resulted in alternative coatings that indicated promise as suitable plating materials. Phase IV and V studies continued the program by testing two different fasteners (NAS1580 and NAS4452) manufactured in AFS facilities. Testing included plating material characterization such as coating thickness, torque-tension relationships, locking and breakaway torque measurements, salt spray (fog) corrosion, stress corrosion, and push-in and interference properties. Additionally, mechanical properties of the plated fasteners were tested (tensile, double shear, durability, and fatigue). Candidates included two electroplated zinc-nickel coating systems (Zn-Ni and Zn-Ni2) and an electrodeposited aluminum coating (AI).

Cadmium electroplating is coming under increasing pressure due to both environmental and worker safety issues. Since 2005, Alcoa Fastening Systems (AFS) and Lockheed Martin have been conducting a collaborative research program to identify the most appropriate fastener coating materials for a Cadmium (Cd) plating replacement. Four candidate coatings were selected for the initial Phase I evaluation: electroless nickel (EN), electroless nickel composite (EN-PTFE), electrodeposited surface mineralization based zinc-nickel (Zn-Ni), and electroplated aluminum (Al). The Phase I testing results indicated that the Zn-Ni and Al coatings were the best of the four candidates for Cd replacement. However, it is hard to conduct direct comparisons with different coating thicknesses, surface treatments, and lubrication among various Cd alternatives. Thus, further evaluation with more careful control of these parameters would be necessary.

Cadmium (Cd) plating offers good corrosion resistance, lubricity, solderability, adhesion, and ductility, as well as consistent torque-tension and uniform thickness on components with complex geometries. However, the intrinsic Environmental, Health, and Safety issues associated with Cd have driven many users to seek alternatives. Currently, various Cd replacement teams/programs such as the Joint Group on Pollution Prevention (JG-PP)/Boeing, the Joint Cadmium Alternatives Team (JCAT), the Canadian Cadmium Replacement Program (CCRP), and the REFOCUS Program (AEA Technology, European) have been investigating alternatives to Cd plating. Some of the current coatings being considered in the aerospace industry include Zn-Ni alloy plating, electrodeposited aluminum, electroless nickel, nickel composite, and molten salt aluminum manganese (Al-Mn). Each option has its own particular characteristics; however, most experiments have been conducted on aerospace structural panels or components.