Radiocarbon and Hydrocarbon Analysis of PM Sources During WHTC Tests on a Biodiesel-Fueled Engine
PM in diesel exhaust has been given much attention due to its adverse effect on both climate and health. As the PM emission levels are tightened, the portion of particles originating from the lubrication oil is likely to increase. In this study, exhausts from a biodiesel-fueled Euro 5 engine were examined to determine how much of the carbonaceous particles that originated from the fuel and the lubrication oil, respectively. A combination of three methods was used to determine the PM origin: chain length analysis of the hydrocarbons, determination of organic and elemental carbon (OC and EC), and the concentration of 14C found in the exhausts. It was found that the standard method for measuring hydrocarbons in PM on a filter (chain length analysis) only accounted for 63 % of the OC, meaning that it did not account for all non-soot carbon in the exhausts.