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Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.

A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.

Measurements were made of exhaust histories of the following species: unburned hydrocarbons (HC), carbon monoxide, carbon dioxide, oxygen, and nitric oxide (NO). The measurements show that the exhaust flow can be divided into two distinct phases: a leading gas low in HC and high in NO followed by a trailing gas high in HC and low in NO. Calculations of time resolved equivalence ratio throughout the exhaust process show no evidence of a stratified combustion. The exhaust mass flow rate is time resolved by forcing the flow to be locally quasi-steady at an orifice placed in the exhaust pipe. The results with the quasi-steady assumption are shown to be consistent with the measurements. Predictions are made of time resolved mass flow rate which compare favorably to the experimental data base. The composition and flow histories provide sufficient information to calculate the time resolved flow rates of the individual species measured.

The paper considers the thermodynamic irreversibility in Stirling cycle machines at the interface between components with different thermodynamic characteristics. The approach of the paper is to consider the simplest possible cases and to focus on the factors that influence the thermodynamic losses. For example, an ideal adiabatic cylinder facing an ideal isothermal heat exchanger is considered. If there is no mixing in the cylinder (gas remains one dimensionally stratified), there will be no loss (irreversibility) if the gas motion is in phase with the gas pressure changes. If there is a phase shift, as required to have a network for the cylinder, there will be a loss (entropy generation) because the gas will not match the heat exchanger temperature. There will also be a loss if the gas in the cylinder is mixed rather than stratified. Similar simple interface conditions can be considered between components and interconnecting open volumes and between heat exchangers and regenerators.

Semi-solid metal (SSM) casting has long been identified as a high-volume process for producing safety-critical and structural automotive castings, but cost and complexity issues have limited its widespread commercial acceptance. Rheocasting, an SSM process that creates semi-solid slurry directly from liquid metal, eliminates the cost disadvantages of the process. However, the majority of rheocasting processes are complex and difficult to operate in the foundry environment. Recent work at MIT has led to the fundamental discovery that application of heat removal and convection as a molten alloy cools through the liquidus creates a non-dendritic, semi-solid slurry. A new process based on this understanding, S.S.R.™ (Semi-Solid Rheocasting), simplifies the rheocasting process by controlling heat removal and convection of an alloy during cooling using an external device. Solution heat treatable castings have been produced in a horizontal die casting machine with the S.S.R.™ process.

Recent studies have shown that for a given RON, fuels with a higher sensitivity (RON-MON) tend to have better antiknock performance at most knock-limited conditions in modern engines. The underlying chemistry behind fuel sensitivity was therefore investigated to understand why this trend occurs. Chemical kinetic models were used to study fuels of varying sensitivities; in particular their autoignition delay times and chemical intermediates were compared. As is well known, non-sensitive fuels tend to be paraffins, while the higher sensitivity fuels tend to be olefins, aromatics, diolefins, napthenes, and alcohols. A more exact relationship between sensitivity and the fuel's chemical structure was not found to be apparent. High sensitivity fuels can have vastly different chemical structures. The results showed that the autoignition delay time (τ) behaved differently at different temperatures. At temperatures below 775 K and above 900 K, τ has a strong temperature dependence.

In a recent paper (Hoult & Meador, [1]) a novel method of estimating the costs of parts, and assemblies of parts, was presented. This paper proposed that the metric for increments of cost was the function log (dimension/tolerance). Although such log functions have a history,given in [1], starting with Boltzman and Shannon, it is curious that it arises in cost models. In particular, the thermodynamic basis of information theory, given by Shannon [2], seems quite implausible in the present context. In [1], we called the cost theory “Complexity Theory”, mainly to distinguish it from information theory. A major purpose of the present paper is to present a rigorous argument of how the log function arises in the present context. It happens that the agrument hinges on two key issues: properties of the machine making or assembling the part, and a certain limit process. Neither involves thermodynamic reasoning.

Gear profile deviation is the difference in gear tooth profile from the ideal involute geometry. There are many causes that result in the deviation. Deflection under load, manufacturing, and thermal effects are some of the well-known causes that have been reported to cause deviation of the gear tooth profile. The profile deviation caused by gear tooth profile deformation due to interference-fit assembly has not been discussed previously. Engine timing gear trains, transmission gearboxes, and wind turbine gearboxes are known to use interference-fit to attach the gear to the rotating shaft. This paper discusses the interference-fit joint design and the mechanism of tooth profile deformation due to the interference-fit assembly in gear trains. A new analytical method to calculate the profile slope deviation change due to interference-assembly of parallel axis spur gears is presented.

This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.

A gasoline engine with an electronically controlled fuel injection system has substantially better fuel economy and lower emissions than a carburetted engine. In general, the stability of engine operation is improved with fuel injector, but the stability of engine operation at idle is not improved compared with a carburetted gasoline engine. In addition, the increase in time that an engine is at idle due to traffic congestion has an effect on the engine stability and vehicle reliability. Therefore, in this research, we will study the influence of fuel injection timing, spark timing, dwell angle, and air-fuel ratio on engine stability at idle.

The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties

In internal combustion engines, the majority of the friction loss associated with the piston takes place on the thrust side in early expansion stroke. Research has shown that the Friction Mean Effective Pressure (FMEP) of the engine can be reduced if proper modifications to the piston skirt, which is traditionally barrel-shaped, are made. In this research, an existing model was applied for the first time to study the effects of different oil supply strategies for the piston assembly. The model is capable of tracking lubricating oil with the consideration of oil film separation from full film to partial film. It is then used to analyze how the optimized piston skirt profile investigated in a previous study reduces friction.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Ground impact caused by road debris can result in very severe fire accident of Electric Vehicles (EV). In order to study the ground impact accidents, a Finite Element model of the battery pack structure is carefully set up according to the practical designs of EVs. Based on this model, the sequence of the deformation process is studied, and the contribution of each component is clarified. Subsequently, four designs, including three enhanced shield plates and one enhanced housing box, are investigated. Results show that the BRAS (Blast Resistant Adaptive Sandwich) shield plate is the most effective structure to decrease the deformation of the battery cells. Compared with the baseline case, which adopts a 6.35-mm-thick aluminum sheet as the shield plate, the BRAS can reduce the shortening of cells by more than 50%. Another type of sandwich structure, the NavTruss, can also improve the safety of battery pack, but not as effectively as the BRAS.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

Determining the fundamental role of gravity in vital biological systems in space is one of six science and research areas that provides the philosophical underpinning for why NASA exists. The study of cells, tissues, and microorganisms in a spaceflight environment holds the promise of answering multiple intriguing questions about how gravity affects living systems. To enable these studies, specimens must be maintained in an environment similar to that used in a laboratory. Cell culture studies under normal laboratory conditions involve maintaining a highly specialized environment with the necessary temperature, humidity control, nutrient, and gas exchange conditions. These same cell life support conditions must be provided by the International Space Station (ISS) Cell Culture Unit (CCU) in the unique environment of space. The CCU is a perfusion-based system that must function in microgravity, at unit gravity (1g) on earth, and from 0.1g up to 2g aboard the ISS centrifuge rotor.

A reciprocating test apparatus was constructed in which the friction of a single piston ring against a liner segment was measured. The lubrication oil film thickness was also measured simultaneously at the mid stroke of the ring travel using a laser fluorescence technique. The apparatus development and operation are described. Results are presented from a test matrix consisting of five different lubrication oils of viscosity (at 30°C) ranging from 49 to 357 cP; at three mean piston speeds of 0.45, 0.89 and 1.34 m/s; and at three ring normal loading of 1.4, 2.9 and 5.7 MPa. At mid stroke, the oil film thickness under the ring was ∼0.5 to 4 μm; the frictional coefficient was ∼0.02 to 0.1. The frictional coefficient for all the lubricants tested increased with normal load, and decreased with piston velocity. Both mixed and hydrodynamic lubrication regimes were observed. The friction behaviors were consistent with the Stribeck diagram.

Current CJ-4 lubricant specifications place chemical limits on diesel engine oil formulations to minimize the accumulation of lubricant-derived ash in diesel particulate filters (DPF). While lubricant additive chemistry plays a strong role in determining the amount and type of ash accumulated in the DPF, a number of additional factors play important roles as well. Relative to soot particles, whose residence time in the DPF is short-lived, ash particles remain in the filter for a significant fraction of the filter's useful life. While it is well-known that the properties (packing density, porosity, permeability) of soot deposits are primarily controlled by the local exhaust conditions at the time of particle deposition in the DPF, the cumulative operating history of the filter plays a much stronger role in controlling the properties and distribution of the accumulated ash.

Topology of liner finish is critical to the performance of internal combustion engines. Proper liner finish simulation processes lead to efficient engine design and research. Fourier methods have been well studied to numerically generate liner topology. However, three major issues wait to be addressed to make the generation processes feasible and reliable. First, in order to simulate real plateau honed liners, approaches should be developed to calculate accurate liner geometric parameters. These parameters are served as the input of the generation algorithm. Material ratio curve, the common geometry calculation method, should be modified so that accurate root mean square of plateau height distribution could be obtained. Second, the set of geometric parameters used in generating liner finish (ISO 13565-2) is different from the set of parameters used in manufacturing industry (ISO 13565-3). Quantitative relations between these two sets should be studied.

Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.