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This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

A linearized lumped parameter heat balance model was developed and is discussed for the general case of resistance welding to see the effects of each parameter on the lobe shape. The parameters include material properties, geometry of electrodes and work piece, weld time and current, and electrical and thermal contact characteristics. These are then related to heat dissipation in the electrodes and the work piece. The results indicate that the ratio of thermal conductivity and heat capacity to electrical resistivity is a characteristic number which is representative of the ease of spot weldability of a given material. The increases in thermal conductivity and heat capacity of the sheet metal increase the lobe width while increases in electrical resistivity decrease the lobe width. Inconsistencies in the weldability of thin sheets and the wider lobe width at long welding times can both be explained by the heat dissipation characteristics.

Lubricant viscosity along the engine cylinder liner varies by an order of magnitude due to local temperature variation and vaporization effects. Tremendous potential exists for fuel economy improvement by optimizing local viscosity variations for specific operating conditions. Methods for analytical estimation of friction and wear in the power-cylinder system are reviewed and used to quantify opportunities for improving mechanical efficiency and fuel economy through lubricant formulation tailored specifically to liner temperature distributions. Temperature dependent variations in kinematic viscosity, density, shear thinning, and lubricant composition are investigated. Models incorporating the modified Reynolds equation were used to estimate friction and wear under the top ring and piston skirt of a typical 11.0 liter diesel engine.

The Wankel rotary engine is more compact than conventional piston engines, but its oil and fuel consumption must be reduced to satisfy emission standards and customer expectations. A key step toward this goal is to develop a better understanding of the apex seal lubrication to reduce oil injection while reducing friction and maintaining adequate wear. This paper presents an apex seal dynamics model capable of estimating relative wear and predicting friction, by modeling the gas and oil flows at the seal interfaces with the rotor housing and groove flanks. Model predictions show that a thin oil film can reduce wear and friction, but to a limited extent as the apex seal running face profile is sharp due to the engine kinematics.

This paper presents tribological modeling, experimental work, and validation of tribology parameters of a single cylinder turbocharged diesel engine run at various loads, speeds, intake boost pressures, and cylinder liner temperatures. Analysis were made on piston rings and liner materials, rings mechanical and thermal loads, contact pressure between rings and liner, and lubricant conditions. The engine tribology parameters were measured, and used to validate the engine tribology models. These tribology parameters are: oil film thickness, coefficient of friction between rings and liner, friction force, friction power, friction torque, shear rate, shear stress and wear of the sliding surfaces. In order to measure the oil film thickness between rings and liner, a single cylinder AVL turbocharged diesel engine was instrumented to accept the difference in voltage drop method between rings, oil film, and liner.

Lowering lubricant viscosity to reduce friction generally carries a side-effect of increased metal-metal contact in mixed or boundary lubrication, for example near top ring reversal along the engine cylinder liner. A strategy to reduce viscosity without increased metal-metal contact involves controlling the local viscosity away from top-ring-reversal locations. This paper discusses the implementation of insulation or thermal barrier coating (TBC) as a means of reducing local oil viscosity and power cylinder friction in internal combustion engines with minimal side-effects of increased wear. TBC is selectively applied to the outside diameter of the cylinder liner to increase the local oil temperature along the liner. Due to the temperature dependence of oil viscosity, the increase in temperature from insulation results in a decrease in the local oil viscosity.

The extent of oxidation of hydrocarbons desorbing from the oil layer has been measured directly in a hydrogen-fueled, spark-ignited engine in which the lubricant oil was doped with a single component hydrocarbon. The amount of hydrocarbon desorbed and oxidized could be measured simultaneously as the dopant was only source of carbon-containing species. The fraction oxidized was strongly dependent on engine load, hydrogen fuel-air ratio and dopant chemical reactivity, but only modestly dependent on spark timing and nitrogen dilution levels below 20 percent. Fast FID measurements at the cylinder exit showed that the surviving hydrocarbons emerge late in the exhaust stroke.

The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

The wear patterns of the rings and grooves of a diesel engine were analyzed by using a ring dynamics/gas flow model and a ring-pack oil film thickness model. The analysis focused primarily on the contact pressure distribution on the ring sides and grooves as well as on the contact location on the ring running surfaces. Analysis was performed for both new and worn ring/groove profiles. Calculated results are consistent with the measured wear patterns. The effects of groove tilt and static twist on the development of wear patterns on the ring sides, grooves, and ring running surfaces were studied. Ring flutter was observed from the calculation and its effect on oil transport was discussed. Up-scraping of the top ring was studied by considering ring dynamic twist and piston tilt. This work shows that the models used have potential for providing practical guidance to optimizing the ring pack and ring grooves to control wear and reduce oil consumption.

A one-dimensional model for crevice HC post-flame oxidation is used to calculate and understand the effect of operating parameters and fuel type (propane and isooctane) on the extent of crevice hydrocarbon and the product distribution in the post flame environment. The calculations show that the main parameters controlling oxidation are: bulk burned gas temperatures, wall temperatures, turbulent diffusivity, and fuel oxidation rates. Calculated extents of oxidation agree well with experimental values, and the sensitivities to operating conditions (wall temperatures, equivalence ratio, fuel type) are reasonably well captured. Whereas the bulk gas temperatures largely determine the extent of oxidation, the hydrocarbon product distribution is not very much affected by the burned gas temperatures, but mostly by diffusion rates. Uncertainties in both turbulent diffusion rates as well as in mechanisms are an important factor limiting the predictive capabilities of the model.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

The quest for higher efficiency and performance of automotive vehicles requires application of materials with high strength, stiffness and lower weight in their construction. Particulate-reinforced aluminum-matrix composites are cost-competitive materials, which can meet these requirements. MMCC, Inc. has been optimizing particulate-reinforced alloy systems and developing the Advanced Pressure Infiltration Casting (APIC™) process for the manufacture of components from these materials. This paper discusses the results of a recent study in which composites reinforced with 55 vol.% alumina were cast using two sizes of alumina particulate and eight different matrix alloys based on Al-4.5 wt.% Cu with varying amounts of silicon and magnesium. Optimum heat treatments for each alloy were determined utilizing microhardness studies. The tensile strength and fracture toughness were evaluated as a function of alloy chemistry, particulate size, and heat treatment.

A one-dimensional model has been developed for the species and energy transfer over a thin (0.1-0.5 mm) layer of liquid fuel present on the wall of a spark-ignition engine. Time-varying boundary conditions during compression and flame passage were used to determine the rate of methanol vaporization and oxidation over a mid-speed, mid-load cycle, as a function of wall temperature. The heat of vaporization and the boiling point of the fuel were varied about a baseline to determine the effect of these characteristics, at a fixed operating point and lean conditions (ϕ = 0.9). The calculations show that the evaporation of fuels from layers on cold walls starts during flame passage, peaking a few milliseconds later, and continuing through the exhaust phase.

Concept of a new decoupled cylinder liner design for internal combustion (IC) engines is presented from the framework of axiomatic design to improve friction and wear characteristics. In the current design, the piston rings fail to satisfy their functional requirements at the two dead centers of the piston stroke where lubrication is poor. It is proposed that by using undulated cylindrical surfaces selectively along the cylinder liner, much of the existing friction and wear problems of IC engines may be solved. The main idea behind undulated surface is to trap wear particles at the piston-cylinder interface in order to minimize plowing, and thus maintain low friction even in areas where lubrication fails to be hydrodynamic. In dry sliding tests using a modified engine motored at low speeds, undulated cylinders operated for significantly longer time than smooth cylinders without catastrophic increase in friction.

The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.

The oxidation chemistry of paraffins, aromatics, olefins and MTBE were examined. Detailed chemical kinetics calculations were carried out for oxidation of these compounds in the engine cycle. The oxidation rates are very sensitive to temperature. At temperatures of over 1400 K (depending on the fuel), all the hydrocarbons are essentially oxidized for typical residence time in the engine. Based on the kinetics calculations, a threshold temperature is defined for the conversion of the fuel species to CO, CO2, H2O and partially oxidized products. The difference in the survival fraction between aromatics and non-aromatics is attributed to the higher threshold temperature of the aromatics.

The adoption of turbine engines for automotive power plants has been hampered by the high cost, high leakage and high wear rate of present designs of ceramic-matrix regenerators. Proposals are made and analyzed here for design directions to achieve substantial improvements in all three areas. These include lower-cost extruded and pressed matrices; and clamping seals coupled with incremental movement of the rotary-regenerator matrix.