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The effects of hydrogen peroxide addition on iso-octane/air Homogeneous Charge Compression Ignition (HCCI) combustion have been investigated analytically. Particular attention was focused on the predications involving homogeneous gas-phase kinetics. Use was made of Peters' iso-octane mechanism in CHEMKIN and convective heat transfer was included in the analyses. This enabled the influences that H2O2 addition has on species concentration and ignition promotion and hence exhaust emissions to be determined. It was found that both CO and NOx emission levels could be ameliorated. The former effect is considered to be a result of the decomposition of H2O2 into OH intermediate species and hence reducing the time to ignition and the onset of combustion.

Empirical and analytical investigations are conducted to evaluate the thermal response of exhaust pipe plenums at different levels of exhaust gas recirculation and through a variety of fuel delivery strategies. The effectiveness of different combustion control techniques is evaluated for moderating the engine-out exhaust temperature. Comparison of the external fuel injection with in-cylinder post injection for enabling aftertreatment is provided which indicates the stronger temperature raising potential of the external fuel injection. This research attempts to quantify the thermal response of the exhaust pipe plenums and its effects on the gas temperature at the inlet of the aftertreatment devices. The measurement and modeling of the dynamic thermal response in this research intend to improve the performance of diesel aftertreatment devices.