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The influence of fuel aromatics type on the particulate matter (PM) and NOx exhaust emissions of a heavy-duty, single-cylinder, DI diesel engine was investigated. Eight fuels were blended from conventional and oil sands crude oil sources to form five fuel pairs with similar densities but with different poly-aromatic (1.6 to 14.6%) or total aromatic (14.3 to 39.0%) levels. The engine was tuned to meet the U.S. EPA 1994 emission standards. An eight-mode, steady-state simulation of the U.S. EPA heavy-duty transient test procedure was followed. The experimental results show that there were no statistically significant differences in the PM and NOx emissions of the five fuel pairs after removing the fuel sulphur content effect on PM emissions. However, there was a definite trend towards higher NOx emissions as the fuel density, poly-aromatic and total aromatic levels of the test fuels increased.

The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and1H/13C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT™) apparatus.

The exhaust emissions from a single-cylinder version of a heavy-duty diesel engine with exhaust gas recirculation (EGR) were studied using 12 diesel fuels derived from oil sands and conventional sources. The test fuels were blended from 22 refinery streams to produce four fuels (two from each source) at three different total aromatic levels (10, 20, and 30% by mass). The cetane numbers were held constant at 43. Exhaust emissions were measured using the AVL eight-mode steady-state test procedure. PM emissions were accurately modeled by a single regression equation with two predictors, total aromatics and sulphur content. Sulphate emissions were found to be independent of the type of sulphur compound in the fuel. NOx emissions were accurately modeled by a single regression equation with total aromatics and density as predictor variables. PM and NOx emissions were significantly significantly affected by fuel properties, but crude oil source did not play a role.

The effects of cetane number, aromatics content and 90% distillation temperature (T90) on HCCI combustion were investigated using a fuel matrix designed by the Fuels for Advanced Combustion Engines (FACE) Working Group of the Coordinating Research Council (CRC). The experiments were conducted in a single-cylinder, variable compression ratio, Cooperative Fuel Research (CFR) engine. The fuels were atomized and partially vaporized in the intake manifold. The engine was operated at a relative air/fuel ratio of 1.2, 60% exhaust gas recirculation (EGR) and 900 rpm. The compression ratio was varied over the range of 9:1 to 15:1 to optimize the combustion phasing for each fuel, keeping other operating parameters constant. The results show that cetane number and T90 distillation temperature significantly affected the combustion phasing. Cetane number was clearly found to have the strongest effect.