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There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.