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The aim of this research was to investigate the mechanism causing autoignition and the effect of exhaust gas recirculation (EGR) on combustion by detecting the behavior of the OH radical and other excited molecules present in the flame in a spark ignition engine. The test equipment used was a 2-cycle engine equipped with a Schnürle scavenging system. Using emission spectroscopy, the behavior of the OH radical was measured at four locations in the end zone of the combustion chamber. The OH radical plays an important role in the elemental reactions of hydrocarbon fuels. When a certain level of EGR was applied according to the engine operating conditions, the unburned gas became active owing to heat transfer from residual gas near the measurement positions on the exhaust port side and the influence of excited species in the residual gas, and autoignition tended to occur.

We have investigated combustion characteristics of lean gasoline-air pre-mixture ignited by gas-oil injection using a high compression D.I. diesel engine. Gasoline was supplied as an uniform lean mixture by using carburetors, and gas-oil was directly injected into the cylinder. Two different types of combustion chamber were attempted. It was confirmed that the lean mixture of air-fuel ratio between 150 and 35 could be ignited and burned by this ignition method. An engine with the re-entrant type combustion chamber had an advantage for combustion and ignition. The brake mean effective pressure increased when relatively rich mixture was provided with a small amount of the gas-oil injection. As the gas-oil injection increased, HC concentration decreased, and NO and CO concentration increased. The exhaust gas emission of pollutants could be reduced when lean mixture was ignited by an optimum gas-oil injection.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).