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The aim of this research was to investigate the mechanism causing autoignition and the effect of exhaust gas recirculation (EGR) on combustion by detecting the behavior of the OH radical and other excited molecules present in the flame in a spark ignition engine. The test equipment used was a 2-cycle engine equipped with a Schnürle scavenging system. Using emission spectroscopy, the behavior of the OH radical was measured at four locations in the end zone of the combustion chamber. The OH radical plays an important role in the elemental reactions of hydrocarbon fuels. When a certain level of EGR was applied according to the engine operating conditions, the unburned gas became active owing to heat transfer from residual gas near the measurement positions on the exhaust port side and the influence of excited species in the residual gas, and autoignition tended to occur.

The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.

In this study, optical measurements were made of the combustion chamber gas during operation of a Homogeneous Charge Compression Ignition (HCCI) engine in order to obtain a better understanding of the ignition and combustion characteristics. The principal issues of HCCI engines are to control the ignition timing and to optimize the combustion state following ignition. Autoignition in HCCI engines is strongly influenced by the complex low-temperature oxidation reaction process, alternatively referred to as the cool flame reaction or negative temperature coefficient (NTC) region. Accordingly, a good understanding of this low-temperature oxidation reaction process is indispensable to ignition timing control. In the experiments, spectroscopic measurement methods were applied to investigate the reaction behavior in the process leading to autoignition.

Attention has recently been focused on homogeneous charge compression ignition (HCCI) as an effective combustion process for resolving issues inherent to the nature of combustion. Dimethyl ether (DME; CH3OCH3) has attracted interest as a potential alternative fuel for compression ignition engines. We measured the HCCI process of DME in a test diesel engine by using a spectroscopic method. Simultaneous measurements were also done on exhaust emissions of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx). Based on the experimental data, this paper discusses the relationship between the equivalence ratio and the observed tendencies.

In this study, light emission and absorption spectroscopic measurement techniques were used to investigate the Homogeneous Charge Compression Ignition (HCCI) combustion process in detail, about which there have been many unclear points heretofore. The results made clear the formation behavior and wavelength bands of the chemical species produced during low-temperature reactions. Specifically, with a low level of residual gas, a light emission band was observed from a cool flame in a wavelength range of 370–470 nm. That is attributed to the light emission of formaldehyde (HCHO) produced in the cool-flame reactions. Additionally, it was found that these light emission spectra were no longer observable when residual gas was applied. The light emission spectra of the combustion flame thus indicated that residual gas has the effect of moderating cool-flame reactions.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest as a combustion system that offers the advantages of high efficiency and low exhaust emissions. However, it is difficult to control the ignition timing in an HCCI combustion system owing to the lack of a physical means of initiating ignition like the spark plug in a gasoline engine or fuel injection in a diesel engine. Moreover, because the mixture ignites simultaneously at multiple locations in the cylinder, it produces an enormous amount of heat in a short period of time, which causes greater engine noise, abnormal combustion and other problems in the high load region. The purpose of this study was to expand the region of stable HCCI engine operation by finding a solution to these issues of HCCI combustion.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest because it achieves high efficiency and can reduce particulate matter (PM) and nitrogen oxide (NOx) emissions simultaneously. However, because HCCI engines lack a physical means of initiating ignition, it is difficult to control the ignition timing. Another issue of HCCI engines is that the combustion process causes the cylinder pressure to rise rapidly. The time scale is also important in HCCI combustion because ignition depends on the chemical reactions of the mixture. Therefore, we investigated the influence of the engine speed on autoignition and combustion characteristics in an HCCI engine. A four-stroke single-cylinder engine equipped with a mechanically driven supercharger was used in this study to examine HCCI combustion characteristics under different engine speeds and boost pressures.

This study was conducted to investigate the influence of cooled recirculated exhaust gas (EGR) on abnormal combustion in a Homogenous Charge Compression Ignition (HCCI) engine. The condition of abnormal HCCI combustion accompanied by cylinder pressure oscillations was photographed with a high-speed camera using a 2-stroke optically accessible engine that enabled visualization of the entire bore area. Exhaust gas was cooled with a water-cooled intercooler for introducing cooled EGR. Experiments were conducted in which the quantity of cooled EGR introduced was varied and a comparison was made of the autoignition behavior obtained under each condition in order to investigate the influence of cooled EGR on abnormal HCCI combustion. The results revealed that cylinder pressure oscillations were reduced when cooled EGR was introduced. That reduction was found to be mainly ascribable to the effect of cooled EGR on changing the ignition timing.

Internal combustion engines today are required to achieve even higher efficiency and cleaner exhaust emissions. Currently, research interest is focused on premixed compression ignition (Homogeneous Charge Compression Ignition, HCCI) combustion. However, HCCI engines have no physical means of initiating ignition such as a spark plug or the fuel injection timing and quantity. Therefore, it is difficult to control the ignition timing. In addition, combustion occurs simultaneously at multiple sites in the combustion chamber. As a result, combustion takes place extremely rapidly especially in the high load region. That makes it difficult for the engine to operate stably at high loads. This study focused on the fuel composition as a possible means to solve these problems. The effect of using fuel blends on the HCCI operating region and combustion characteristics was investigated using a single-cylinder test engine.

Unresolved issues of Homogeneous Charge Compression Ignition (HCCI) combustion include an extremely rapid pressure rise on the high load side and resultant knocking. Studies conducted to date have examined ways of expanding the region of stable HCCI combustion on the high load side such as by applying supercharging or recirculating exhaust gas (EGR). However, the effect of applying EGR gas to supercharged HCCI combustion and the mechanisms involved are not fully understood. In this study, the effect of EGR gas components on HCCI combustion was investigated by conducting experiments in which external EGR gas was applied to supercharged HCCI combustion and also experiments in which nitrogen (N2) and carbon dioxide (CO2) were individually injected into the intake air pipe to simulate EGR gas components. In addition, HCCI combustion reactions were analyzed by conducting chemical kinetic simulations under the same conditions as those of the experiments.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest in recent years as a clean, high-efficiency combustion system. However, it is difficult to control the ignition timing in HCCI engines because they lack a physical means of inducing ignition. Another issue of HCCI engines is their narrow operating range because of misfiring that occurs at low loads and abnormal combustion at high loads. As a possible solution to these issues, this study focused on the application of a streamer discharge in the form of non-equilibrium plasma as a technique for assisting HCCI combustion. Experiments were conducted with a four-stroke single-cylinder engine fitted with an ignition electrode in the combustion chamber. A streamer discharge was continuously generated in the cylinder during a 720-degree interval from the intake stroke to the exhaust stroke.

In this research, the effect of high-temperature residual gas, resulting from the application of a certain level of EGR, on combustion was investigated using a two-stroke engine and alcohol fuels (ethanol and methanol) and gasoline as the test fuels. Measurements were made of the light emission intensity of the OH radical on the intake and exhaust port sides of the combustion chamber and of the combustion chamber wall temperature (spark plug washer temperature) and the exhaust gas temperature. Data were measured and analyzed in a progression from normal combustion to autoignited combustion to preignition and to knocking operation.

This study investigated the effects of recirculated exhaust gas (EGR) and its principal components of N2, CO2 and H2O on moderating Homogeneous Charge Compression Ignition (HCCI) combustion. Experiments were conducted using two types of gaseous fuel blends of DME/propane and DME/methane as the test fuels. The addition rates of EGR, N2, CO2 and H2O were varied and the effects of each condition on HCCI combustion of propane and methane were investigated. The results revealed that the addition of CO2 and H2O had the effect of substantially delaying and moderating rapid combustion. The addition of N2 showed only a slight delaying and moderating effect. The addition of EGR had the effect of optimally delaying the combustion timing, while either maintaining or increasing the indicated mean effective pressure and indicated thermal efficiency ηi.

There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

The use of a higher compression ratio is desirable for improving the thermal efficiency and specific power of spark-ignition engines, but it gives rise to a problem of engine knock. In the present research, an investigation was made of the role of the preflame reaction region of a spark-ignition engine in the occurrence of autoignition. Emission spectroscopy was used to measure the behavior of formaldehyde (HCHO) in a cool flame. In addition, measure the behavior of the faint light attributed to the HCO radical in a blue flame with the concurrent measurement of the OH radical. The emission waveforms measurements obtained for HCHO when n-heptane (ORON) was used as the fuel, It is thought that these tendencies correspond to the passage and degeneracy of a cool flame. Further, the emission waveforms measured for the HCO radical when blended fuels (6ORON, 8ORON) were correspond to that of a blue flame.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).

In-cylinder visualization of the entire bore area at an identical frame rate was used to investigate knocking conditions under spark ignition (SI) combustion and under Homogeneous Charge Compression Ignition (HCCI) combustion in the same test engine. A frequency analysis was also conducted on the measured pressure signals. The results revealed that a combustion regime accompanied by strong pressure oscillations occurred in both the SI and HCCI modes, which was presumably caused by rapid autoignition with attendant brilliant light emission that took place near the cylinder wall. It was found that the knocking timing was the dominant factor of this combustion regime accompanied by cylinder pressure oscillations in both the SI and HCCI combustion modes.

In this research, an investigation was made of ion current and OH radical luminescence behavior in the progression from normal combustion to knocking operation. One pair each of an ion probe and a quartz observation window was fitted in the center and on the end of the combustion chamber. The peak values of the ion voltage drop and the OH radical emission intensity both increased as the cylinder head temperature and the cylinder pressure rose. It is possible to understand combustion conditions by analyzing measured waveformes of the ion voltage drop and the OH radical emission intensity.

This study investigated the origin of knocking combustion accompanied by pressure wave and strong pressure oscillations in a Homogeneous Charge Compression Ignition (HCCI) engine. Experiments were conducted with a two-stroke single cylinder optically accessible engine that allowed the entire bore area to be visualized. The test fuel used was n-heptane. The equivalence ratio and intake temperature were varied to induce a transition from moderate HCCI combustion to extremely rapid HCCI combustion accompanied by in-cylinder pressure oscillations. Local autoignition and pressure wave behavior under each set of operating conditions were investigated in detail on the basis of high-speed in-cylinder visualization and in-cylinder pressure analysis. As a result, under conditions where strong knocking occurs, a brilliant flame originates from the burned gas side in the process where the locally occurring autoignition gradually spreads to multiple locations.

This study attempted to elucidate combustion conditions in a progression from normal combustion to knocking by analyzing the ion current and light emission intensity that occurred during this transition. With the aim of understanding the combustion states involved, the ion current was measured at two positions in the combustion chamber. Light emission spectroscopy was applied to examine preflame reactions that are observed prior to autoignition in the combustion process of hydrocarbon fuels. The results obtained by analyzing the experimental data made clear the relationship between the ion current and light emission during the transition from normal combustion to knocking operation.