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The question of whether increasing the fuel economy of light-duty natural gas fueled vehicles can improve their economic competitiveness in the U.S. market, and help the US Department of Energy meet stated goals for such vehicles is explored. Key trade-offs concerning costs, exhaust emissions and other issues are presented for a number of possible advanced engine designs. Projections of fuel economy improvements for a wide range of lean-burn engine technologies have been developed. It appears that compression ignition technologies can give the best potential fuel economy, but are less competitive for light-duty vehicles due to high engine cost. Lean-burn spark ignition technologies are more applicable to light-duty vehicles due to lower overall cost. Meeting Ultra-Low Emission Vehicle standards with efficient lean-burn natural gas engines is a key challenge.

Thermal barrier coated diesel engines, also known as low heat rejection (LHR) engines, have offered the promise of reducing heat rejection to the engine coolant and thereby increasing overall thermal efficiency. However, the larger market potential for thermal barrier coated engines may be in retrofitting in-service diesel engines to reduce particulate emissions. Prior work by the authors has demonstrated a significant decrease in particulate emissions from a thermal barrier coated, single-cylinder, indirect injection (IDI) diesel engine, primarily through reduction of the volatile (VOF) and soluble (SOF) fraction of the particulate. This prior work relied on conventional, commercially available, petroleum-based lubricants. The present study concerns the additional benefits for particulate reduction provided by vegetable oil lubricants. These lubricants are derived from renewable resource materials and can provide a reduction in lubricant generated particulate matter.

Urea/SCR systems have been proven effective at reducing NOx over a wide range of operating conditions on mid/heavy duty diesel vehicles. However, design changes due to reduction in the size of modern compact Urea/SCR systems and lower exhaust temperature have increased the possibility of urea deposit formation. Urea deposits are formed when urea in films and droplets undergoes undesirable secondary reactions and generate by-products such as ammelide, biuret and cyanuric Acid (CYA). Ammelide and CYA are difficult to decompose which lead to the formation of solid deposits on the surface. This phenomenon degrades the performance of the after treatment system by decreasing overall mixing efficiency, lowering de-NOx efficiency and increasing pressure drop. Therefore, mitigating urea deposits is a primary design goal of modern diesel after-treatment systems.

This paper investigates experimental uncertainties associated with gaseous and particulate emissions measurements in a partial flow emissions sampling system developed and built at the Larson Transportation Institute of the Pennsylvania State University. A small fraction of the tail pipe exhaust is diluted with dilution air and passed through a cyclone to eliminate particles bigger than 2.5 microns. The diluted exhaust is then passed through a 47 mm Teflon filter for gravimetric measurement of Particulate Matter (PM). Mass flow controllers operating at 5Hz are used to control the flow rates of dilution air, diluted exhaust, and proportional flow of diluted exhaust into a Tedlar bag. An ultrasonic flow meter is used to measure flow rate of tail pipe exhaust. At the end of a test, the concentration of gaseous emissions in the bag, namely CO2, CO, HC, and NOx are measured using a bag emissions analyzer.

The friction and wear characteristics of three commercially-available, electrolytic coatings for aluminum engine cylinder bores were compared to those of cast iron liners. A Ni/SiC electrocomposite, a hard anodized treatment, and a Plasma Electrolytic Oxidation (PEO) coating were investigated. ASTM standard test method G133-95, non-firing test method, for linearly reciprocating sliding wear was modified to use segments of piston rings and cylinder liners. Tests were conducted using Mr. Goodwrench™ 5W30 as a lubricant at room temperature. The normal force was 150N, the reciprocating frequency was 15Hz, the stroke length was 8mm, and the test duration was 60 minutes. Kinetic friction coefficients ranged from 0.1 to 0.22, typical of boundary lubrication. The Ni/SiC and cast iron samples exhibited the lowest friction. The wear resistance of the Ni/SiC coating was superior to that of cast iron.

Ongoing efforts in applying a “high-end” turbulent combustion model (a transported probability density function - tPDF - method) to direct-injection internal combustion engines are discussed. New numerical algorithm and physical modeling issues arise compared to more conventional modeling approaches. These include coupling between Eulerian finite-volume methods and Lagrangian Monte Carlo particle methods, liquid fuel spray/tPDF coupling, and heat transfer. Sensitivity studies are performed and quantitative comparisons are made between model results and experimental measurements in a diesel/PCCI engine. Marked differences are found between tPDF results that account explicitly for turbulence/chemistry interactions (TCI) and results obtained using models that do not account for TCI. Computed pressure and heat release profiles agree well with experimental measurements and respond correctly to variations in engine operating conditions.

In order to assist in fast design cycle of Diesel engines selective catalytic reduction (SCR) exhaust systems, significant endeavor is currently being made to improve numerical simulation accuracy of urea thermo-hydrolysis. In this article, the achievements of a recently developed urea semi-detailed decomposition chemical scheme are assessed using three available databases from the literature. First, evaporation and thermo-hydrolysis of urea-water solution (UWS) single-droplets hanged on a thin thermocouple ring (127 μm) as well as on a thick quartz (275 μm), have been simulated at ambient temperature conditions ranging from 473K to 773K. It has been shown that the numerical results, in terms of evaporation rate and urea gasification, as well as droplet temperature history are very close to the experiments if the heat flux coming from the droplet support is properly accounted for.

Laser-induced incandescence is used to measure time-resolved diesel particulate emissions for two lean NOx trap regeneration strategies that utilize intake throttling and in-cylinder fuel enrichment. The results show that when the main injection event is increased in duration and delayed 13 crank-angle degrees, particulate emissions are very high. For a repetitive pattern of 3 seconds of rich regeneration followed by 27 seconds of NOx-trap loading, we find a monotonic increase in particulate emissions during the loading intervals that approaches twice the initial baseline particulate level after 1000 seconds. In contrast, particulate emissions during the regeneration intervals are constant throughout the test sequence.

Semi-volatile species in the exhaust can condense on the primary particulate matter (PM) forming significant secondary PM mass downstream1. We developed a new thermographic technique to measure the volatility of a particle population. The instrument is called vapor-particle separator (VPS)2. A two-parameter model was used to interpret the thermographic data3. These two parameters define volatilization potential and thermodynamic capacity of the particles. The volatization potential delineates the unique particle volatility, while the thermodynamic capacity illustrates the work required to eliminate the particles. The thermodynamic capacity is found much smaller for small particles than that for large particles.

In this research, small, single cylinder engines have been used to simulate larger engines in the areas of aftertreatment, combustion, and fuel formulation effects. The use of small engines reduces overall research cost and allows more rapid experiments to be run. Because component costs are lower, it is also possible to investigate more variations and to sacrifice components for materials characterization and for subsequent experiments. Using small engines in this way is very successful in some cases. In other cases, limitations of the engines influence the results and need to be accounted for in the experimental design and data analysis. Some of the results achieved or limitations found may be of interest to the small engine market, and this paper is offered as a summary of the authors' research in these areas. Research is being conducted in two areas. First, small engines are being used to study the rapid aging and poisoning of exhaust aftertreatment catalysts.

On a gasoline engine platform, homogeneous charge compression ignition (HCCI) holds the promise of improved fuel economy and greatly reduced engine-out NOx emissions, without an increase in particulate matter emissions. In this investigation, a variable compression ratio (CR) engine equipped with a throttle and intake air heating was used to test the robustness of these control parameters to accommodate a series of fuels blended from reference gasoline, straight run refinery naphtha, and ethanol. Higher compression ratios allowed for operation with higher octane fuels, but operation could not be achieved with the reference gasoline, even at the highest compression ratio. Compression ratio and intake heat could be used separately or together to modulate combustion. A lambda of 2 provided optimum fuel efficiency, even though some throttling was necessary to achieve this condition. Ethanol did not appear to assist combustion, although only two ethanol-containing fuels were evaluated.

The deactivation of diesel oxidation catalysts (DOCs) by soot contamination and lube-oil derived phosphorus poisoning is investigated. Pt/CeO2/γ-AI2O3 DOCs aged using three different protocols developed by the authors and six high mileage field-returned DOCs of similar formulation are evaluated for THC and CO oxidation performance using a bench-flow reactor. Collectively, these catalysts exhibit a variety of phosphorus and soot morphologies contributing to performance deactivation.

This study shows conclusively that some of the direct microbial mutagenic activity of the soluble-organie-fraction from Diesel particulate matter can be attributed to 1-nitropyrene. 1-nitropyrene has been shown to be formed by the nitration of pyrene, and pyrene is one inherent product of the diffusion-controlled-combustion of hycrocarbons that occurs with Diesel engine operation. Nitrogen dioxide, in the presence of water vapor, is shown to be a potential nitrating agent, and this gas can be produced by the high temperature oxidation of the nitrogen contained in the oxidant. These results are based on studies which used a well-documented engine, model fuel, model oxidants, and synthetic lubricant.

Numerous studies have demonstrated that exhaust gas recirculation (EGR) can attenuate knock propensity in spark ignition (SI) engines at naturally aspirated or lightly boosted conditions [1]. In this study, we investigate the role of cooled EGR under higher load conditions with multiple fuel compositions, where highly retarded combustion phasing typical of modern SI engines was used. It was found that under these conditions, EGR attenuation of knock is greatly reduced, where EGR doesn’t allow significant combustion phasing advance as it does under lighter load conditions. Detailed combustion analysis shows that when EGR is added, the polytropic coefficient increases causing the compressive pressure and temperature to increase. At sufficiently highly boosted conditions, the increase in polytropic coefficient and additional trapped mass from EGR can sufficiently reduce fuel ignition delay to overcome knock attenuation effects.

Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called “E85,” underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane “E85” fuel.

The ignition of single fuel droplets in air is modeled according to the time-varying conditions within the droplet and the boundary layer around the droplet. Ignition is hypothesized when some point in the boundary layer has experienced a sufficiently severe history in terms of pressure, temperature, equivalence ratio, and time to auto ignite. Experiments were conducted with a wide variety of fuels to validate the model. A critical size concept for ignition was predicted by the model and substantiated by the experiments.

The effects of variable compression ratio (CR) and fuel composition on thermal efficiency were investigated in a homogeneous charge compression ignition (HCCI) engine using blends of n-heptane and toluene with research octane numbers (RON) of 0 to 90. Experiments were conducted by performing CR sweeps at multiple intake temperatures using both unthrottled operation, and constant Φ conditions by throttling to compensate for varying air density. It was found that CR is effective at changing and controlling the HCCI combustion phasing midpoint, denoted here as CA 50. Thermal efficiency was a strong function of CA 50, with overly advanced CA 50 leading to efficiency decreases. Increases in CR at a constant CA 50 for a given fuel composition did, in most cases, increase efficiency, but the relationship was weaker than the dependence of efficiency on CA 50.

Results are presented from an experimental study of the effects of engine speed and injection pressure transients on the cold start performance of a gasoline direct injection engine operating on iso-octane. The experiments are performed in an optically-accessible single-cylinder research engine modified for gasoline direct injection operation. In order to isolate the effects of the engine speed and injection pressure transients, three different cold start simulations are used. In the first cold start simulation the engine speed and injection pressure are constant. In the second cold start simulation the injection pressure is constant while the engine speed transient of an actual cold start is simulated. In the third cold start simulation both the engine speed and the injection pressure transients of an actual cold start are simulated.

The partnership for advancing combustion engines (PACE) is a US Department of Energy consortium involving multiple national laboratories and includes a goal of addressing key efficiency and emission barriers in light-duty engines fueled with a market-representative E10 gasoline. A major pillar of the initiative is the generation of detailed experimental data and modeling capabilities to understand and predict cold-start behavior. Cold-start, as defined by the time between first engine crank and three-way catalyst light-off, is responsible for a large percentage of NOx, unburned hydrocarbon and particulate matter emissions in light-duty engines. Minimizing emissions during cold-start is a trade-off between achieving faster light-off of the three-way catalyst and engine out emissions during that period.

Current methods for reducing emission of oxides of nitrogen (NOx) from the spark ignition (SI) engine employ dilution of intake charge with relatively inert gases which tends to limit peak combustion temperatures and pressures. Employment of intake charge dilution has led to reduction in engine power output and increased combustion cycle-by-cycle (CBC) irregularity. This investigation sought to determine the degree of increased CBC combustion variations experienced as increased amounts of charge dilution reduced emission of NOx. Emission of unburned hydrocarbons (HC) was also documented. It was found that increased CBC variations result from employing intake charge dilution as a tool to reduce NOx emissions. The significant aspects of the increased CBC variations were an observed increase in maximum cyclic pressure dispersion, a slower flame speed as reflected by an increased angle of occurrence of peak cyclic pressure, and increased variations in the crank angle of peak pressure.