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The question of whether increasing the fuel economy of light-duty natural gas fueled vehicles can improve their economic competitiveness in the U.S. market, and help the US Department of Energy meet stated goals for such vehicles is explored. Key trade-offs concerning costs, exhaust emissions and other issues are presented for a number of possible advanced engine designs. Projections of fuel economy improvements for a wide range of lean-burn engine technologies have been developed. It appears that compression ignition technologies can give the best potential fuel economy, but are less competitive for light-duty vehicles due to high engine cost. Lean-burn spark ignition technologies are more applicable to light-duty vehicles due to lower overall cost. Meeting Ultra-Low Emission Vehicle standards with efficient lean-burn natural gas engines is a key challenge.

This paper explores the extent to which standard dilution tunnel measurements of motor vehicle exhaust particulate matter modify particle number and size. Steady state size distributions made directly at the tailpipe, using an ejector pump, are compared to dilution tunnel measurements for three configurations of transfer hose used to transport exhaust from the vehicle tailpipe to the dilution tunnel. For gasoline vehicles run at a steady 50 - 70 mph, ejector pump and dilution tunnel measurements give consistent results of particle size and number when using an uninsulated stainless steel transfer hose. Both methods show particles in the 10 - 100 nm range at tailpipe concentrations of the order of 104 particles/cm3.

As vehicle tailpipe emission levels decrease with improvements in emission control technology and reformulation of gasolines, exhaust hydrocarbon levels begin to approach the levels in ambient air. Hydrocarbon speciation at these low levels requires high sensitivity capillary gas chromatography methods. In this study, a mixture of “synthetic” exhaust was prepared at two concentration levels (approximately 5 ppm C and 10 ppm C), and was analyzed by the widely-used Auto/Oil Air Quality Improvement Research Program (AQIRP) Phase II (gas chromatography) speciation method with a sensitivity of 0.005 ppm C for individual species. The mixture at each concentration level, along with a sample of ambient air, was analyzed a total of 20 times on 10 separate days over a 2½ week period. Concentrations of total hydrocarbons (HCs) and individual species (using the AQIRP library) were measured; averages and standard deviations were calculated.

Liquid fuels and the fuel vapors in equilibrium with them typically differ in composition. These differences impact automotive fuel systems in several ways. Large compositional differences between liquid and vapor phases affect the composition of species taken up within the evaporative emission control canister, since the canister typically operates far from saturation and doesn't reach equilibrium with the fuel tank. Here we discuss how these differences may be used to diagnose the mode of emission from a sealed container, e.g., a fuel tank. Liquid or vapor leaks lead to particular compositions (reported here) that depend on the fuel components but are independent of the container material. Permeation leads to emissions whose composition depends on the container material. If information on the relative permeation rates of the different fuel components is available, the results given here provide a tool to decide whether leakage or permeation is the dominant mode of emission.

A simple set of equations has been developed to characterize automotive fuel behavior in fuel tanks, fuel vapor systems and fuel rails, particularly under hot weather conditions. The system of equations links the vapor pressure P, the temperature T, and the mass fraction evaporated Z. Parameters are determined empirically from laboratory vapor pressure and distillation tests. With appropriate values for heat capacity, heat of vaporization, and vapor composition, the equations can be used to estimate upper flammability limits, fuel weathering under hot fuel handling conditions, pressure rise in tanks, and evaporative vapor generation. The equations were developed as part of a larger fuel vapor system model.

The feasibility of using experimentally determined flow fields at intake valve closing, IVC, as initial conditions for computing the in-cylinder flow dynamics during the compression stroke is demonstrated by means of a computer simulation of the overall approach. A commercial CFD code, STAR-CD, was used for this purpose. The study involved two steps. First, in order to establish a basis for comparison, the in-cylinder flow field throughout the intake and compression strokes, from intake valve opening, IVO, to top dead center, TDC, was computed for a simple engine geometry. Second, experimental initial conditions were simulated by randomly selecting and perturbing a set of velocity vectors from the computed flow field at IVC.

This paper describes two types of dielectric-effect sensors that may be used as alternatives to a dielectric-effect sensor using a single capacitor. In the first type, three capacitors are mounted in a compact module inserted into a vehicle fuel line. The three capacitors are connected together to form an electrical pi-filter network. This approach provides a large variation of output signal as the fuel changes from gasoline to methanol. The sensor can be designed to operate in the 1 to 20 MHz frequency range. The second type of sensor investigated uses a resonant-cavity structure. Ordinarily, sensors based on resonant cavities are useful only if the operating frequency is several hundred MHz or higher. The high relative dielectric constant of methanol allows useful sensors to be built using relatively short lengths of metal tubing for the cavities. For example, a sensor built using a fuel rail only 38.7 cm long operated in a frequency range from 31 to 52 MHz.

Exhaust pressures (P3) are hard parameters to measure and can be readily estimated, the cost of the sensors and the temperature in the exhaust system makes the implementation of an exhaust pressure sensor in a vehicle control system a costly endeavor. The contention with measured P3 is the accuracy required for proper engine and vehicle control can sometimes exceed the accuracy specification of market available sensors and existing models. A turbine inlet exhaust pressure observer model based on isentropic expansion and heat transfer across a turbocharger turbine was developed and investigated in this paper. The model uses 4 main components; an open loop P3 orifice flow model, a model of isentropic expansion across the turbine, a turbine and pipe heat transfer models and an integrator with the deviation in the downstream turbine outlet parameter.

The friction and wear characteristics of three commercially-available, electrolytic coatings for aluminum engine cylinder bores were compared to those of cast iron liners. A Ni/SiC electrocomposite, a hard anodized treatment, and a Plasma Electrolytic Oxidation (PEO) coating were investigated. ASTM standard test method G133-95, non-firing test method, for linearly reciprocating sliding wear was modified to use segments of piston rings and cylinder liners. Tests were conducted using Mr. Goodwrench™ 5W30 as a lubricant at room temperature. The normal force was 150N, the reciprocating frequency was 15Hz, the stroke length was 8mm, and the test duration was 60 minutes. Kinetic friction coefficients ranged from 0.1 to 0.22, typical of boundary lubrication. The Ni/SiC and cast iron samples exhibited the lowest friction. The wear resistance of the Ni/SiC coating was superior to that of cast iron.

The objective of this study is to investigate the removal of methane (CH4), nitric oxide (NO), and carbon monoxide (CO) from simulated natural gas vehicle (NGV) exhaust over a palladium catalyst. The effects of changes in space velocity and natural gas sulfur (S) content were studied. The study suggests that the NGV has to be operated slightly rich of stoichiometry to achieve simultaneous removal of the three constituents. The CH4 conversion decreases with an increase in the space velocity. The CO and NO conversions remain unaffected over the space velocity range (10,000 hr-1 to 100,000 hr-1) investigated. The presence of sulfur dioxide in the exhaust lowers the CH4 conversion and increases the CO conversion in the rich region. The NO conversion remains unaffected. Studies were conducted over model catalysts to investigate the modes of CH4 removal from the simulated NGV exhaust.

While a Ni-MH battery has good performance properties, such as a high power density and no memory effect, it needs a powerful thermal management system to maintain within the required narrow thermal operating range for the 42V HEV applications. Inappropriate battery temperatures result in degradation of the battery performance and life. For the battery cooling system, air is blown into the battery pack. The exhaust is then vented outside due to potential safety issues with battery emissions. This cooling strategy can significantly impact fuel economy and cabin climate control. This is particularly true when the battery is experiencing frequent charge and discharge of high-depths in extreme hot or cold weather conditions. To optimize performance and life of HEV traction batteries, the battery cooling design must keep the battery operation temperature below a maximum value and uniform across the battery cells.

Modern diesel engines employ a multitude of strategies for oxides of nitrogen (NOx) emission abatement, with exhaust gas recirculation (EGR) being one of the most effective technique. The need for a precise control on the intake charge dilution (as a result of EGR) is paramount since small fluctuations in the intake charge dilution at high EGR rates may cause larger than acceptable spikes in NOx/soot emissions or deterioration in the combustion efficiency, especially at low to mid-engine loads. The control problem becomes more pronounced during transient engine operation; currently the trend is to momentarily close the EGR valve during tip-in or tip-out events. Therefore, there is a need to understand the transient EGR behaviour and its impact on the intake charge development especially under unstable combustion regimes such as low temperature combustion.

A new estimator for IC engine A/F ratio is described. A/F ratio is important for engine operation since it determines the quantities of engine emissions, such as HC, CO, NOx, the conversion efficiency of catalyst systems, and the engine combustion stability. The A/F ratio estimator described in this paper is based on a fundamental metric that relies on inducing and detecting crankshaft speed fluctuations caused by modulating the engine's fuel injection pulse widths. Fuel pulse width modulation varies the instantaneous combustion A/F ratio crankshaft velocity. Synchronous measurement of crankshaft velocity provides a metric that, when used with other engine state variables as inputs to a conventional neural network, can accurately estimate A/F ratio. The estimator provides A/F information when a physical sensor is not available.

Aftertreatment system design involves multiple tradeoffs between engine performance, fuel economy, regulatory emission levels, packaging, and cost. Selection of the best design solution (or “architecture”) is often based on an assumption that inherent catalyst activity is unaffected by location within the system. However, this study acknowledges that catalyst activity can be significantly impacted by location in the system as a result of varying thermal exposure, and this in turn can impact the selection of an optimum system architecture. Vehicle experiments with catalysts aged over a range of mild to moderate to severe thermal conditions that accurately reflect select locations on a vehicle were conducted on a chassis dynamometer. The vehicle test data indicated CO and NOx could be minimized with a catalyst placed in an intermediate location.

Speciated HC emissions from the exhaust system of a production engine without an active catalyst have been obtained with 3 sec time resolution during a 70°F cold start using two control strategies. For the conventional cold start, the emissions were initially enriched in light fuel alkanes and depleted in heavy aromatic species. The light alkanes fell rapidly while the lower vapor pressure aromatics increased over a period of 50 sec. These results indicate early retention of low vapor pressure fuel components in the intake manifold and exhaust system. Loss of higher molecular weight HC species does occur in the exhaust system as shown by experiments in which the exhaust system was preheated to 100° C. The atmospheric reactivity of the exhaust HC emissions for photochemical smog formation increases as the engine warms.

Laser-induced incandescence is used to measure time-resolved diesel particulate emissions for two lean NOx trap regeneration strategies that utilize intake throttling and in-cylinder fuel enrichment. The results show that when the main injection event is increased in duration and delayed 13 crank-angle degrees, particulate emissions are very high. For a repetitive pattern of 3 seconds of rich regeneration followed by 27 seconds of NOx-trap loading, we find a monotonic increase in particulate emissions during the loading intervals that approaches twice the initial baseline particulate level after 1000 seconds. In contrast, particulate emissions during the regeneration intervals are constant throughout the test sequence.

Thermophysical properties of materials used in the design of automotive interiors are needed for computer simulation of climate conditions inside the vehicle. These properties are required for assessment of the vehicle occupants' thermal sensation as they come in contact with the vehicle interior components, such as steering wheels, arm rests, instruments panel and seats. This paper presents the results of an investigation into the thermophysical properties of materials which are required for solving the non-linear Fourier equations with any boundary conditions and taking into account materials' specific heat, volume density, thermal conductivity, and thermal optical properties (spectral and total emissivity and absorptivity). The model and results of the computer simulation will be published in a separate paper.

Semi-volatile species in the exhaust can condense on the primary particulate matter (PM) forming significant secondary PM mass downstream1. We developed a new thermographic technique to measure the volatility of a particle population. The instrument is called vapor-particle separator (VPS)2. A two-parameter model was used to interpret the thermographic data3. These two parameters define volatilization potential and thermodynamic capacity of the particles. The volatization potential delineates the unique particle volatility, while the thermodynamic capacity illustrates the work required to eliminate the particles. The thermodynamic capacity is found much smaller for small particles than that for large particles.

Carbon dioxide (CO2)-based refrigeration systems have been proposed as environmentally benign alternatives to current automotive air conditioners. The CO2 vapor-compression system requires very high operating pressures and complicated control strategies. Recent experimental results indicate that operating pressures comparable to those of current automotive air conditioners can be attained by the inclusion of a secondary carrier fluid (a “co-fluid”), with solution and desolution of the CO2 from the co-fluid substituting for condensation and vaporization of pure CO2. In this work, modeling tools have been developed to optimize the CO2/co-fluid cycle, including the selection of a co-fluid, the CO2/co-fluid ratio (the “loading”), and the operating conditions.

Cabin heating of current electric vehicle (EV) designs is typically provided using electrical energy from the traction battery, since waste heat is not available from an engine as in the case of a conventional automobile. In very cold climatic conditions, the power required for space heating of an EV can be of a similar magnitude to that required for propulsion of the vehicle. As a result, its driving range can be reduced very significantly during the winter season, which limits consumer acceptance of EVs and results in increased battery costs to achieve a minimum range while ensuring comfort to the EV driver. To minimize the range penalty associated with EV cabin heating, a novel climate control system that includes thermal energy storage from an advanced phase change material (PCM) has been designed for use in EVs and plug-in hybrid electric vehicles (PHEVs).