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In this study, multi-planar Nearfield Acoustical Holography (NAH) is used to investigate noise radiated from the front, side and rear areas of single tires on a two-wheel trailer. Contributions to the radiated noise from the leading edge, trailing edge, and sidewall of the tire are identified. Two tires - an experimental monopitch tire and a production passenger car tire - are evaluated on a smooth asphalt pavement at 58 km/hr. From the measured complex pressure, acoustic intensity is reconstructed on three planes surrounding the tire using modified NAH procedures. Additionally, sound power levels are presented in tabulated and spectra forms. Tire noise generating mechanisms are inferred based on the results.

Experimental results are presented from plug flow reactor studies of the lean oxidation of iso-octane and compared to modeling results using a detailed kinetic mechanism. Two sets of experiments performed at 9 atm are presented: a temperature sweep from low temperature through the NTC region and temporal species profiles for an initial temperature within the low temperature regime. Species observed include C8 conjugate olefins, C8 cyclic ethers, acetone, acetaldehyde, iso-butyraldehyde, 2,2-dimethyl-propanal, iso-butene, propene, C7 olefins, and iso-butene oxide. In general the model predicts the overall trends observed in the experimental results, including the temperatures at which the NTC region begins and ends. However, it significantly over-predicts the extent of reaction in the low temperature regime.

The potential for catalytically enhanced ignition in low-heat rejection Diesel engines has been experimentally studied under engine simulated conditions in a high pressure chemical flow reactor. Results are presented for propane oxidation on platinum at 6 and 10 atmospheres, at temperatures from 800K to 1050K, and at equivalence ratios from 0.5 to 4.0. For turbulent transport rates which are typical of those in an engine, as much as 20% of the fuel was found to react on the catalyst before the onset of the gas-phase ignition reactions. Depending on the adiabaticity of the combustion chamber walls, this could lead to significant thermal enhancement of the gas-phase ignition process. Evidence of chemical enhancement was also observed, at 10 atm under very fuel rich conditions, in terms of a change in the concentration and distribution of the hydrocarbon intermediate species. Possible mechanisms for the observed chemical enhancement due to surface generated species are discussed.

Current phase of the study was undertaken to examine tensile fatigue behavior of cord-rubber composites representing bias tire carcass under various frequencies up to the level which closely simulates loading during high-speed take-off of aircraft. At a given stress amplitude, the use of higher cyclic frequency was found to affect strain response and heat build-up characteristics of composites significantly. The lower level of initial strain observed at higher frequency stems clearly from strain rate dependence of deformation of rubber matrix composites. The temperature profile of the specimens subjected from 20 to 30 Hz loading showed that hysteretic heating under these conditions may lead to thermal fatigue failure as well as chemical degradation influencing both fiber-matrix adhesion strength and matrix strength.

The oxidation of 1-butene and n-butane in air at elevated pressure was investigated in a high pressure chemical flow reactor. Results are presented for pressures of 3, 6, and 10 atm, temperatures near 900K, and lean equivalence ratio. Gas samples were analyzed using gas chromatography with aldehydes sampled using a dinitrophenylhydrazine/acetonitrile procedure employing gas chromatography/mass spectrometry analysis. Major common products observed include CO, CH2O, C2H4, C3H6, and CO2. Additional major products included 1,3-C4H6 for 1-butene and 1-C4H8 for n-butane. Fuel conversion was increased with increased pressure, temperature, and equivalence ratio with 1-butene more reactive than n-butane. Large levels of lower molecular weight carbonyls resulted from 1-butene whereas significant amounts of conjugate and lower molecular weight alkenes resulted from n-butane. Trends in product distributions with increasing pressure were successfully accounted for by current autoignition theories.

Legislation world-wide has made it necessary to find ways to control the level of engine emissions and reduce the damage to our environment. Increasing restrictions have made the elimination of zinc dithiophosphates from crankcase oils and increasing the effectiveness of catalytic converters viable options. Lead and phosphorus containing compounds in the exhaust are known catalyst poisons that shorten the life of current automotive catalysts. Unleaded fuel has successfully resulted in a reduction of harmful emissions due to the fuel. Current government and industry research is actively pursuing replacement of phosphorus additives with phosphorus free additives. Several phosphorus-free oils were developed and are evaluated in bench tests in this study. Test comparisons with phosphorus- containing oils demonstrated satisfactory oxidation stability and wear performance of the phosphorus free oils.

Mn and/or rare earth-doped xCaTiO₃ - (1-x)CaMeO₃ dielectrics, where Me=Hf or Zr and x=0.7, 0.8, and 0.9 were developed to yield materials with room temperature relative permittivities of Εr ~ 150-170, thermal coefficients of capacitance (TCC) of ± 15.8% to ± 16.4% from -50 to 150°C, and band gaps of ~ 3.3-3.6 eV as determined by UV-Vis spectroscopy. Un-doped single layer capacitors exhibited room temperature energy densities as large as 9.0 J/cm₃, but showed a drastic decrease in energy density above 100°C. When doped with 0.5 mol% Mn, the temperature dependence of the breakdown strength was minimized, and energy densities similar to room temperature values (9.5 J/cm₃) were observed up to 200°C. At 300°C, energy densities as large as 6.5 J/cm₃ were measured. These observations suggest that with further reductions in grain size and dielectric layer thickness, the xCaTiO₃ - (1-x)CaMeO₃ system is a strong candidate for integration into future power electronics applications.

Deep-hole drilling is among the most critical precision machining processes for production of high-performance discrete components. The effects of drilling with superimposed, controlled low-frequency modulation - Modulation-Assisted Machining (MAM) - on the surface textures created in deep-hole drilling (ie, gun-drilling) are discussed. In MAM, the oscillation of the drill tool creates unique surface textures by altering the burnishing action typical in conventional drilling. The effects of modulation frequency and amplitude are investigated using a modulation device for single-flute gun-drilling on a computer-controlled lathe. The experimental results for the gun-drilling of titanium alloy with modulation are compared and contrasted with conventional gun-drilling. The chip morphology and surface textures are characterized over a range of modulation conditions, and a model for predicting the surface texture is presented. Implications for production gun-drilling are discussed.

This paper presents simple but comprehensive modeling of the loads on the rubber sandwich-type mounts that often suspend the drum(s) in vibratory compactors or asphalt rollers. The goal of the modeling is to predict the overall performance of the rubber mount system. The modeling includes calculations to 1) identify and quantify all predictable low-frequency loads on the rubber mounts during normal vehicle operations, 2) predict the steady-state high-frequency vibration response of the drum, rubber mounts, and vehicle frame during compaction operations, 3) predict the heat generation in the rubber mounts from their hysteretic damping, and 4) predict the fatigue life and life distribution of the rubber mounts. Some typical results of the modeling are provided along with some brief criteria to assess suspension performance. Other, unpredictable suspension loads are discussed but not modeled.

The oxides of nitrogen (NOx) produced during combustion in an automobile engine play a major role in atmospheric chemistry and therefore need to be reduced by modifying vehicle engine designs and fuels of tomorrow. In a combustion chamber of a spark ignited engine, NOx is formed as atmospheric nitrogen competes with fuel molecules to couple with oxygen in the extremely hot burned gases behind the proceeding flame front (Zeldovich type) and as reactions occur directly in the combustion flame zone (“prompt” type). Since little nitrogen is present in the fuel, the fuel contribution to the overall NOx emissions is minor. Certain combustion chamber deposits have been shown to increase NOx emissions by thermally insulating the combustion chamber and taking up chamber volume, thus slightly increasing the compression ratio of the engine and raising the combustion gas temperature.