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UV-absorption measurements are sparse in diesel(-like) combustion, particularly close to the premixed burn. Thus, such measurements are conducted in diesel-like jets in a high-pressure vessel in this work, using 1D spontaneous Raman scattering (SRS) from N2. Stokes (~263 nm) and anti-Stokes (~235 nm) SRS induced by a krypton fluoride excimer (KrF*) laser (~248 nm) is exploited. Anti-Stokes SRS can be directly used for attenuation correction of laser-induced fluorescence (LIF) from NO at ~236 nm. Results show the importance of attenuation correction, although the jets are largely non-sooting. To identify absorbers, effects of SRS wavelength, measurement time in the injection event, location in the flame, jet width (JW), temperature, CO concentration, and injection pressure are considered. Particularly strong attenuation observed around the time of second-stage ignition appears to be primarily caused by combustion intermediates such as partially oxidized fuel.

Due to experimental challenges, combustion of diesel-like jets has rarely been characterized by laser-based quantitative multiscalar measurements. In this work, recently developed laser diagnostics for combustion temperature and the concentrations of CO, O2, and NO are applied to a diesel-like jet, using a highly oxygenated fuel. The diagnostic is based on spontaneous Raman scattering (SRS) and laser-induced fluorescence (LIF) methods. Line imaging yields multiscalar profiles across the jet cross section. Measurements turn out to be particularly accurate, because near-stoichiometric combustion occurs in the central region of the jet. Thereby, experimental cross-influences by light attenuation and interfering emissions are greatly reduced compared to the combustion of conventional, sooting diesel fuel jets. This is achieved by fuel oxygenation and enhanced premixing.