Search Results

Laboratory and vehicle tests were carried out to investigate behaviour and potentiality of NOx-trap catalytic system in Diesel conditions. Three main aspects were studied. The first one deals with the NOx storage capacity of adsorber under laboratory and vehicle conditions, especially regarding the influence of driving conditions. The second one focuses on the regenerability of different materials. At length, special attention is devoted to the sulphur poisoning rate. A representative laboratory test method was built up, to evaluate NOx storage capacity under Diesel conditions. It is shown that NOx adsorption occurs from 100 to 400°C. Low temperature activity (100 to 250°C) is conditioned by low NOx flow emission, mainly due to the use of high EGR rate. Higher temperatures lead to an increase in the intrinsic NOx Storage capacity of the material, but are also accompanied by high NOx concentration and space velocity.

This presented paper deals with NOx trap sulphur poisoning and its regeneration. Sulphur poisoning has been studied with different SO2 gas concentrations under laboratory and engine test bench conditions. The sulphur poisoning studies have shown that the different NOx-traps available in the market have different behaviours toward SO2 poisoning and are all very sensitive to it. The results outline a non linear relationship of the NOx trap sulphur poisoning as a function of SO2 concentration. For instance, engine bench tests show that with a 50 and a 110ppm sulphur containing gasoline, a decrease of 50% in the NOx-trap storage capacity is respectively observed after 20 and 15 hours. With a gasoline containing 20ppm of sulphur, the same deactivation level is observed after 90 hours.

Laboratory and engine tests were carried out to describe the sulphur effect on the NOx adsorbers catalysts efficiency for gasoline lean burn engines. Two main aspects were studied. The first one deals with the NOx storage efficiency of the adsorber under laboratory conditions, especially regarding the SO2 gas phase concentration. The rate of sulfur storing is greatly affected by the SO2 gas concentration. While 6.5 hours are required to get from 70 % NOx reduction to only 35 % when the gas mixture contains 10 ppm SO2, it takes 20 hours with 5 ppm SO2 and more than 60 hours with the 2 ppm SO2 condition. The relationship between the loss in NOx trap performance and SO2 concentration appears to have an exponential shape. The same amount of sulphur (0.8 % mass) is deposited onto the catalyst within 10 hours with the feed gas containing 10 ppm of SO2 and within 50 hours with 2 ppm SO2. Nevertheless, It was shown that the loss in NOx-Trap efficiency is not the same in these two cases.