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The accurate quantification and control of mixture stoichiometry is critical in many applications using new combustion strategies and fuels (e.g., homogeneous charge compression ignition, gasoline direct injection, and oxygenated fuels). The parameter typically used to quantify mixture stoichiometry (i.e., the proximity of a reactant mixture to its stoichiometric condition) is the equivalence ratio, ϕ. The traditional definition of ϕ is based on the relative amounts of fuel and oxidizer molecules in a mixture. This definition provides an accurate measure of mixture stoichiometry when the fuel molecule does not contain oxidizer elements and when the oxidizer molecule does not contain fuel elements. However, the traditional definition of ϕ leads to problems when the fuel molecule contains an oxidizer element, as is the case when an oxygenated fuel is used, or once reactions have started and the fuel has begun to oxidize.

This study summarizes the peer-reviewed literature regarding the use of raw pyrolysis liquids (PLs) created from woody biomass as fuels for compression-ignition (CI) engines. First, a brief overview is presented of fast pyrolysis and the potential advantages of PLs as fuels for CI engines. Second, a discussion of the general composition and properties of PLs relative to conventional, petroleum-derived diesel fuels is provided, with emphasis on the differences that are most likely to affect PL performance in CI-engine applications. Next, a synopsis is given of the peer-reviewed literature describing experimental studies of CI engines operated using neat PLs and PLs combined in various ways with other fuels. This literature conclusively indicates that raw PLs and PL blends cannot be used as “drop-in replacements” for diesel fuel in CI engines, which is reflected in part by none of the cited studies reporting successful operation on PL fuels for more than twelve consecutive hours.

In-cylinder fluid velocity is measured in an optically accessible, fired HSDI engine at idle. The velocity field is also calculated, including the full induction stroke, using multi-dimensional fluid dynamics and combustion simulation models. A detailed comparison between the measured and calculated velocities is performed to validate the computed results and to gain a physical understanding of the flow evolution. Motored measurements are also presented, to clarify the effects of the fuel injection process and combustion on the velocity field evolution. The calculated mean in-cylinder angular momentum (swirl ratio) and mean flow structures prior to injection agree well with the measurements. Modification of the mean flow by fuel injection and combustion is also well captured.

This work is a technical review of past research and a synthesis of current understanding of post injections for soot reduction in diesel engines. A post injection, which is a short injection after a longer main injection, is an in-cylinder tool to reduce engine-out soot to meet pollutant emissions standards while maintaining efficiency, and potentially to reduce or eliminate exhaust aftertreatment. A sprawling literature on post injections documents the effects of post injections on engine-out soot with variations in many engine operational parameters. Explanations of how post injections lead to engine-out soot reduction vary and are sometimes inconsistent or contradictory, in part because supporting fundamental experimental or modeling data are often not available. In this paper, we review the available data describing the efficacy of post-injections and highlight several candidate in-cylinder mechanisms that may control their efficacy.

This paper investigates flow and combustion in a full-cycle simulation of a four-stroke, three-valve HCCI engine by visualizing the flow with pathlines. Pathlines trace massless particles in a transient flow field. In addition to visualization, pathlines are used here to trace the history, or evolution, of flow fields and species. In this study evolution is followed from the intake port through combustion. Pathline analysis follows packets of intake charge in time and space from induction through combustion. The local scalar fields traversed by the individual packets in terms of velocity magnitude, turbulence, species concentration and temperatures are extracted from the simulation results. The results show how the intake event establishes local chemical and thermal environments in-cylinder and how the species respond (chemically react) to the local field.

Tracer-based PLIF temperature diagnostics have been used to study the distribution and evolution of naturally occurring thermal stratification (TS) in an HCCI engine under fired and motored operation. PLIF measurements, performed with two excitation wavelengths (277, 308 nm) and 3-pentanone as a tracer, allowed investigation of TS development under relevant fired conditions. Two-line PLIF measurements of temperature and composition were first performed to track the mixing of the fresh charge and hot residuals during intake and early compression strokes. Results showed that mixing occurs rapidly with no measureable mixture stratification remaining by early compression (220°CA aTDC), confirming that the residual mixing is not a leading cause of thermal stratification for low-residual (4-6%) engines with conventional valve timing.

Particle image velocimetry (PIV) is used to investigate the structure and evolution of the mean velocity field in the swirl (r-θ) plane of a motored, optically accessible diesel engine with a typical production combustion chamber geometry under motoring conditions (no fuel injection). Instantaneous velocities were measured were made at three swirl-plane heights (3 mm, 10 mm and 18 mm below the firedeck) and three swirl ratios (2.2, 3.5 and 4.5) over a range of crank angles in the compression and expansion strokes. The data allow for a direct analysis of the structures within the ensemble mean flow field, the in-cylinder swirl ratio, and the radial profile of the tangential velocity. At all three swirl ratios, the ensemble mean velocity field contains a single dominant swirl flow structure that is tilted with respect to the cylinder axis. The axis of this structure precesses about the cylinder axis in a manner that is largely insensitive to swirl ratio.

This paper performs a parametric analysis of the influence of numerical grid resolution and turbulence model on jet penetration and mixture formation in a DI-H2 ICE. The cylinder geometry is typical of passenger-car sized spark-ignited engines, with a centrally located single-hole injector nozzle. The simulation includes the intake and exhaust port geometry, in order to account for the actual flow field within the cylinder when injection of hydrogen starts. A reduced geometry is then used to focus on the mixture formation process. The numerically predicted hydrogen mole-fraction fields are compared to experimental data from quantitative laser-based imaging in a corresponding optically accessible engine. In general, the results show that with proper mesh and turbulence settings, remarkable agreement between numerical and experimental data in terms of fuel jet evolution and mixture formation can be achieved.

The in-cylinder charge motion during the compression stroke of an optically accessible engine equipped with direct injection of hydrogen fuel is measured via particle image velocimetry (PIV). The evolution of the mean flow field and the tumble ratio are examined with and without injection, each with the unmodified 4-valve pent-roof engine head and with the intake ports modified to yield higher tumble. The measurements in the vertical symmetry plane of the cylinder show that intake modification produces the desired drastic increase in tumble flow, changing the tumble ratio at BDC from 0.22 to 0.70. Either intake-induced flow is completely disrupted by the high-pressure hydrogen injection from an angled, centrally located single-hole nozzle. The injection event leads to sudden reversal of the tumble. Hence the tumble ratio is negative after injection. However, the two intake configurations still differ in tumble ratio by about the same magnitude as before injection.

Nitric Oxide (NO) can significantly influence the autoignition reactivity and this can affect knock limits in conventional stoichiometric SI engines. Previous studies also revealed that the role of NO changes with fuel type. Fuels with high RON (Research Octane Number) and high Octane Sensitivity (S = RON - MON (Motor Octane Number)) exhibited monotonically retarding knock-limited combustion phasing (KL-CA50) with increasing NO. In contrast, for a high-RON, low-S fuel, the addition of NO initially resulted in a strongly retarded KL-CA50 but beyond the certain amount of NO, KL-CA50 advanced again. The current study focuses on same high-RON, low-S Alkylate fuel to better understand the mechanisms responsible for the reversal in the effect of NO on KL-CA50 beyond a certain amount of NO.

Unlike other gases, hydrogen can promote embrittlement of structural metals at ambient temperature. The effects of high-pressure hydrogen gas on structural metals vary significantly depending on material, environmental, and mechanical variables as well as the metric used to evaluate performance. In this short review, we provide basic guidance on selection of materials for hydrogen gas service emphasizing the need for performing tests in relevant environments and using appropriate methods. Fracture mechanics and fitness-for-service type design approaches are highly recommended for ensuring robust yet efficient high-pressure designs for hydrogen gas service.

Over the past decade, laser diagnostics have improved our understanding of many aspects of diesel combustion. However, interactions between the combusting fuel jet and the piston-bowl wall are not well understood. In heavy-duty diesel engines, with typical fuels, these interactions occur with the combusting vapor-phase region of the jet, which consists of a central region containing soot and other products of rich-premixed combustion, surrounded by a diffusion flame. Since previous work has shown that the OH radical is a good marker of the diffusion flame, planar laser-induced fluorescence (PLIF) imaging of OH was applied to an investigation of the diffusion flame during wall interaction. In addition, simultaneous OH PLIF and planar laser-induced incandescence (PLII) soot imaging was applied to investigate the likelihood for soot deposition on the bowl wall.

The temporal and spatial evolution of the ignition and premixed-burn phases of a direct-injection (DI) diesel spray were investigated under quiescent conditions. The diagnostics used included temporally resolved measurements of natural light emission and pressure, and spatially resolved images of natural light emission. Temporally resolved natural light emission measurements were made with a photo-multiplier tube and a photodiode, while the images were acquired with an intensified CCD camera. The experiments were conducted in an optically accessible, constant-volume combustion vessel over a range of ambient gas temperatures and densities: 800-1100 K and 7.3-45.0 kg/m3. The fuel used was a ternary blend of single-component fuels representative of diesel fuel with a cetane number of 45. The fuel was injected with a common-rail injector at high pressure (140 MPa). The results provide new information on the evolution of the two-stage ignition/premixed-burn phases of DI diesel sprays.

At 70 miles per hour, overcoming aerodynamic drag represents about 65% of the total energy expenditure for a typical heavy truck vehicle. The goal of this US Department of Energy supported consortium is to establish a clear understanding of the drag producing flow phenomena. This is being accomplished through joint experiments and computations, leading to the intelligent design of drag reducing devices. This paper will describe our objective and approach, provide an overview of our efforts and accomplishments related to drag reduction devices, and offer a brief discussion of our future direction.

RNG k-ε closure turbulence dissipation equations are evaluated employing the CFD code KIVA-3V Release 2. The numerical evaluations start by considering simple jet flows, including incompressible air jets and compressible helium jets. The results show that the RNG closure turbulence model predicts lower jet tip penetration than the "standard" k-ε model, as well as being lower than experimental data. The reason is found to be that the turbulence kinetic energy is dissipated too slowly in the downstream region near the jet nozzle exit. In this case, the over-predicted R term in RNG model becomes a sink of dissipation in the ε-equation. As a second step, the RNG turbulence closure dissipation models are further tested in complex engine flows to compare against the measured evolution of turbulence kinetic energy, and an estimate of its dissipation rate, during both the compression and expansion processes.

Mixture formation in an optically accessible hydrogen-fueled engine was investigated using Planar Laser-Induced Fluorescence (PLIF) of acetone as a fuel tracer. The engine was motored and fueled by direct high-pressure injection. This paper presents the evolution of the spatial distribution of the ensemble-mean equivalence ratio for six different combinations of nozzle design and injector geometry, each for three different injection timings after intake-valve closure. Asymmetric single-hole and 5-hole nozzles as well as symmetric 6-hole and 13-hole nozzles were used. For early injection, the low in-cylinder pressure and density allow the jet to preserve its momentum long enough to undergo extensive jet-wall and (for multi-hole nozzles) jet-jet interaction, but the final mixture is fairly homogeneous. Intermediately timed injection yields inhomogeneous mixtures with surprisingly similar features observed for all multi-hole injectors.

This work is a comprehensive technical review of existing literature and a synthesis of current understanding of the governing physics behind the interaction of multiple fuel injections, ignition, and combustion behavior of multiple-injections in diesel engines. Multiple-injection is a widely adopted operating strategy applied in modern compression-ignition engines, which involves various combinations of small pre-injections and post-injections of fuel before and after the main injection and splitting the main injection into multiple smaller injections. This strategy has been conclusively shown to improve fuel economy in diesel engines while achieving simultaneous NOX, soot, and combustion noise reduction - in addition to a reduction in the emissions of unburned hydrocarbons (UHC) and CO by preventing fuel wetting and flame quenching at the piston wall.

The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.