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Technical Paper

Φ-Sensitivity for LTGC Engines: Understanding the Fundamentals and Tailoring Fuel Blends to Maximize This Property

2019-04-02
2019-01-0961
Φ-sensitivity is a fuel characteristic that has important benefits for the operation and control of low-temperature gasoline combustion (LTGC) engines. A fuel is φ-sensitive if its autoignition reactivity varies with the fuel/air equivalence ratio (φ). Thus, multiple-injection strategies can be used to create a φ-distribution that leads to several benefits. First, the φ-distribution causes a sequential autoignition that reduces the maximum heat release rate. This allows higher loads without knock and/or advanced combustion timing for higher efficiencies. Second, combustion phasing can be controlled by adjusting the fuel-injection strategy. Finally, experiments show that intermediate-temperature heat release (ITHR) increases with φ-sensitivity, increasing the allowable combustion retard and improving stability. A detailed mechanism was applied using CHEMKIN to understand the chemistry responsible for φ-sensitivity.
Journal Article

Visualization of Diesel Spray Penetration, Cool-Flame, Ignition, High-Temperature Combustion, and Soot Formation Using High-Speed Imaging

2009-04-20
2009-01-0658
Shadowgraph/schlieren imaging techniques have often been used for flow visualization of reacting and non-reacting systems. In this paper we show that high-speed shadowgraph visualization in a high-pressure chamber can also be used to identify cool-flame and high-temperature combustion regions of diesel sprays, thereby providing insight into the time sequence of diesel ignition and combustion. When coupled to simultaneous high-speed Mie-scatter imaging, chemiluminescence imaging, pressure measurement, and spatially-integrated jet luminosity measurements by photodiode, the shadowgraph visualization provides further information about spray penetration after vaporization, spatial location of ignition and high-temperature combustion, and inactive combustion regions where problematic unburned hydrocarbons exist. Examples of the joint application of high-speed diagnostics include transient non-reacting and reacting injections, as well as multiple injections.
Journal Article

Using Chemical Kinetics to Understand Effects of Fuel Type and Compression Ratio on Knock-Mitigation Effectiveness of Various EGR Constituents

2019-04-02
2019-01-1140
Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.
Technical Paper

Update on Engine Combustion Research at Sandia National Laboratories

2001-05-14
2001-01-2060
The objectives of this paper are to describe the research efforts in diesel engine combustion at Sandia National Laboratories' Combustion Research Facility and to provide recent experimental results. We have four diesel engine experiments supported by the Department of Energy, Office of Heavy Vehicle Technologies: a one-cylinder version of a Cummins heavy-duty engine, a diesel simulation facility, a one-cylinder Caterpillar engine to evaluate combustion of alternative fuels, and a homogeneous-charge, compression-ignition (HCCI) engine. Recent experimental results of diesel combustion research will be discussed and a description will be given of our HCCI experimental program and of our HCCI modeling work.
Journal Article

Understanding Hydrocarbon Emissions to Improve the Performance of Catalyst-Heating Operation in a Medium-Duty Diesel Engine

2023-04-11
2023-01-0262
To cope with regulatory standards, minimizing tailpipe emissions with rapid catalyst light-off during cold-start is critical. This requires catalyst-heating operation with increased exhaust enthalpy, typically by using late post injections for retarded combustion and, therefore, increased exhaust temperature. However, retardability of post injection(s) is constrained by acceptable pollutant emissions such as unburned hydrocarbon (UHC). This study provides further insight into the mechanisms that control the formation of UHC under catalyst-heating operation in a medium-duty diesel engine, and based on the understanding, develops combustion strategies to simultaneously improve exhaust enthalpy and reduce harmful emissions. Experiments were performed with a full boiling-range diesel fuel (cetane number of 45) using an optimized five-injections strategy (2 pilots, 1 main, and 2 posts) as baseline condition.
Journal Article

UHC and CO Emissions Sources from a Light-Duty Diesel Engine Undergoing Dilution-Controlled Low-Temperature Combustion

2009-09-13
2009-24-0043
Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.
Technical Paper

Transmission Electron Microscopy of Soot Particles sampled directly from a Biodiesel Spray Flame

2011-08-30
2011-01-2046
For better understanding of soot formation and oxidation processes in a biodiesel spray flame, the morphology, microstructure and sizes of soot particles directly sampled in a spray flame fuelled with soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at different axial locations in the spray flame, 40, 50 and 70 mm from injector nozzle, which correspond to soot formation, peak, and oxidation zones, respectively. The biodiesel spray flame was generated in a constant-volume combustion chamber under a diesel-like high pressure and temperature condition (6.7 MPa, 1000K). Density, diameter of primary particles and radius of gyration of soot aggregates reached a peak at 50 mm from the injector nozzle and was lower or smaller in the formation or oxidation zones of the spray.
Journal Article

Transmission Electron Microscopy of Soot Particles Directly Sampled in Diesel Spray Flame - A Comparison between US#2 and Biodiesel Soot

2012-04-16
2012-01-0695
For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.
Journal Article

Transient Liquid Penetration of Early-Injection Diesel Sprays

2009-04-20
2009-01-0839
Diesel low-temperature combustion strategies often rely on early injection timing to allow sufficient fuel-ambient mixing to avoid NOx and soot-forming combustion. However, these early injection timings permit the spray to penetrate into a low ambient temperature and density environment where vaporization is poor and liquid impingement upon the cylinder liner and piston bowl are more likely to occur. The objective of this study is to measure the transient liquid and vapor penetration at early-injection conditions. High-speed Mie-scatter and shadowgraph imaging are employed in an optically accessible chamber with a free path of 100 mm prior to wall impingement and using a single-spray injector. The ambient temperature and density within the chamber are well-controlled (uniform) and selected to simulate in-cylinder conditions when injection occurs at -40 crank-angle degrees (CAD) or fewer before top-dead center (TDC).
Technical Paper

Transient Internal Nozzle Flow in Transparent Multi-Hole Diesel Injector

2020-04-14
2020-01-0830
An accurate prediction of internal nozzle flow in fuel injector offers the potential to improve predictions of spray computational fluid dynamics (CFD) in an engine, providing a coupled internal-external calculation or by defining better rate of injection (ROI) profile and spray angle information for Lagrangian parcel computations. Previous research has addressed experiments and computations in transparent nozzles, but less is known about realistic multi-hole diesel injectors compared to single axial-hole fuel injectors. In this study, the transient injector opening and closing is characterized using a transparent multi-hole diesel injector, and compared to that of a single axial hole nozzle (ECN Spray D shape). A real-size five-hole acrylic transparent nozzle was mounted in a high-pressure, constant-flow chamber. Internal nozzle phenomena such as cavitation and gas exchange were visualized by high-speed long-distance microscopy.
Technical Paper

The Use of Transient Operation to Evaluate Fuel Effects on Knock Limits Well beyond RON Conditions in Spark-Ignition Engines

2017-10-08
2017-01-2234
Fundamental engine research is primarily conducted under steady-state conditions, in order to better describe boundary conditions which influence the studied phenomena. However, light-duty automobiles are operated, and tested, under heavily transient conditions. This mismatch between studied conditions and in-use conditions is deemed acceptable due to the fundamental knowledge gained from steady-state experiments. Nonetheless, it is useful to characterize the conditions encountered during transient operation and determine if the governing phenomena are unduly influenced by the differences between steady-state and transient operation, and further, whether transient behavior can be reasonably extrapolated from steady-state behavior. The transient operation mode used in this study consists of 20 fired cycles followed by 80 motored cycles, operating on a continuous basis.
Technical Paper

The Quantification of Mixture Stoichiometry When Fuel Molecules Contain Oxidizer Elements or Oxidizer Molecules Contain Fuel Elements

2005-10-24
2005-01-3705
The accurate quantification and control of mixture stoichiometry is critical in many applications using new combustion strategies and fuels (e.g., homogeneous charge compression ignition, gasoline direct injection, and oxygenated fuels). The parameter typically used to quantify mixture stoichiometry (i.e., the proximity of a reactant mixture to its stoichiometric condition) is the equivalence ratio, ϕ. The traditional definition of ϕ is based on the relative amounts of fuel and oxidizer molecules in a mixture. This definition provides an accurate measure of mixture stoichiometry when the fuel molecule does not contain oxidizer elements and when the oxidizer molecule does not contain fuel elements. However, the traditional definition of ϕ leads to problems when the fuel molecule contains an oxidizer element, as is the case when an oxygenated fuel is used, or once reactions have started and the fuel has begun to oxidize.
Technical Paper

The Influence of Fuel Volatility on the Liquid-Phase Fuel Penetration in a Heavy-Duty D.I. Diesel Engine

1998-02-23
980510
The objective of this investigation is to verify and characterize the influence of fuel volatility on maximum liquid-phase fuel penetration for a variety of actual Diesel fuels under realistic Diesel engine operating conditions. To do so, liquid-phase fuel penetration was measured for a total of eight Diesel fuels using laser elastic-scatter imaging. The experiments were carried out in an optically accessible Diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. In addition to liquid-phase fuel penetration, ignition delay was assessed for each fuel based on pressure-derived apparent heat release rate and needle lift data. For all fuels examined, it was observed that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum characteristic length. Beyond this characteristic length, the fuel is entirely vapor phase and not just smaller fuel droplets.
Journal Article

The Impact of Fuel Mass, Injection Pressure, Ambient Temperature, and Swirl Ratio on the Mixture Preparation of a Pilot Injection

2013-09-08
2013-24-0061
Fuel tracer-based planar laser-induced fluorescence is used to investigate the vaporization and mixing behavior of pilot injections for variations in pilot mass of 1-4 mg, and for two injection pressures, two near-TDC ambient temperatures, and two swirl ratios. The fluorescent tracer employed, 1-methylnaphthalene, permits a mixture of the diesel primary reference fuels, n-hexadecane and heptamethylnonane, to be used as the base fuel. With a near-TDC injection timing of −15°CA, pilot injection fuel is found to penetrate to the bowl rim wall for even the smallest injection quantity, where it rapidly forms fuel-lean mixture. With increased pilot mass, there is greater penetration and fuel-rich mixtures persist well beyond the expected pilot ignition delay period. Significant jet-to-jet variations in fuel distribution due to differences in the individual jet trajectories (included angle) are also observed.
Journal Article

The Future Adoption and Benefit of Electric Vehicles: A Parametric Assessment

2013-04-08
2013-01-0502
We present a parametric analysis of electric vehicle (EV) adoption rates and the corresponding contribution to greenhouse gas (GHG) reduction in the US light-duty vehicle (LDV) fleet through 2050. The analysis is performed with a system dynamics based model of the supply-demand interactions among the fleet, its fuels, and the corresponding primary energy sources. The differentiating feature of the model is the ability to conduct global sensitivity and parametric trade-space analyses. We find that many factors impact the adoption rates of EVs. These include, in particular, policy initiatives that encourage consumers to consider lifetime ownership costs, the price of oil, battery performance, as well as the pace of technological development for all powertrains (conventional internal combustion engines included). Widespread EV adoption can have noticeable impact on petroleum consumption and GHG emissions by the LDV fleet.
Journal Article

The Feasibility of Using Raw Liquids from Fast Pyrolysis of Woody Biomass as Fuels for Compression-Ignition Engines: A Literature Review

2013-04-08
2013-01-1691
This study summarizes the peer-reviewed literature regarding the use of raw pyrolysis liquids (PLs) created from woody biomass as fuels for compression-ignition (CI) engines. First, a brief overview is presented of fast pyrolysis and the potential advantages of PLs as fuels for CI engines. Second, a discussion of the general composition and properties of PLs relative to conventional, petroleum-derived diesel fuels is provided, with emphasis on the differences that are most likely to affect PL performance in CI-engine applications. Next, a synopsis is given of the peer-reviewed literature describing experimental studies of CI engines operated using neat PLs and PLs combined in various ways with other fuels. This literature conclusively indicates that raw PLs and PL blends cannot be used as “drop-in replacements” for diesel fuel in CI engines, which is reflected in part by none of the cited studies reporting successful operation on PL fuels for more than twelve consecutive hours.
Technical Paper

The Effect of Swirl Ratio and Fuel Injection Parameters on CO Emission and Fuel Conversion Efficiency for High-Dilution, Low-Temperature Combustion in an Automotive Diesel Engine

2006-04-03
2006-01-0197
Engine-out CO emission and fuel conversion efficiency were measured in a highly-dilute, low-temperature diesel combustion regime over a swirl ratio range of 1.44-7.12 and a wide range of injection timing. At fixed injection timing, an optimal swirl ratio for minimum CO emission and fuel consumption was found. At fixed swirl ratio, CO emission and fuel consumption generally decreased as injection timing was advanced. Moreover, a sudden decrease in CO emission was observed at early injection timings. Multi-dimensional numerical simulations, pressure-based measurements of ignition delay and apparent heat release, estimates of peak flame temperature, imaging of natural combustion luminosity and spray/wall interactions, and Laser Doppler Velocimeter (LDV) measurements of in-cylinder turbulence levels are employed to clarify the sources of the observed behavior.
Journal Article

Study of Soot Formation and Oxidation in the Engine Combustion Network (ECN), Spray A: Effects of Ambient Temperature and Oxygen Concentration

2013-04-08
2013-01-0901
Within the Engine Combustion Network (ECN) spray combustion research frame, simultaneous line-of-sight laser extinction measurements and laser-induced incandescence (LII) imaging were performed to derive the soot volume fraction (fv). Experiments are conducted at engine-relevant high-temperature and high-pressure conditions in a constant-volume pre-combustion type vessel. The target condition, called "Spray A," uses well-defined ambient (900 K, 60 bar, 22.8 kg/m₃, 15% oxygen) and injector conditions (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K). Extinction measurements are used to calibrate LII images for quantitative soot distribution measurements at cross sections intersecting the spray axis. LII images are taken after the start of injection where quasi-stationary combustion is already established.
Technical Paper

Stochastic Knock Detection Model for Spark Ignited Engines

2011-04-12
2011-01-1421
This paper presents the development of a Stochastic Knock Detection (SKD) method for combustion knock detection in a spark-ignition engine using a model based design approach. The SKD set consists of a Knock Signal Simulator (KSS) as the plant model for the engine and a Knock Detection Module (KDM). The KSS as the plant model for the engine generates cycle-to-cycle accelerometer knock intensities following a stochastic approach with intensities that are generated using a Monte Carlo method from a lognormal distribution whose parameters have been predetermined from engine tests and dependent upon spark-timing, engine speed and load. The lognormal distribution has been shown to be a good approximation to the distribution of measured knock intensities over a range of engine conditions and spark-timings for multiple engines in previous studies.
Technical Paper

Spatio-Temporal Progression of Two-Stage Autoignition for Diesel Sprays in a Low-Reactivity Ambient: n-Heptane Pilot-Ignited Premixed Natural Gas

2021-04-06
2021-01-0525
The spatial and temporal locations of autoignition depend on fuel chemistry and the temperature, pressure, and mixing trajectories in the fuel jets. Dual-fuel systems can provide insight into fuel-chemistry aspects through variation of the proportions of fuels with different reactivities, and engine operating condition variations can provide information on physical effects. In this context, the spatial and temporal progression of two-stage autoignition of a diesel-fuel surrogate, n-heptane, in a lean-premixed charge of synthetic natural gas (NG) and air is imaged in an optically accessible heavy-duty diesel engine. The lean-premixed charge of NG is prepared by fumigation upstream of the engine intake manifold.
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