Search Results

Detailed combustion studies have historically been conducted in simplified reacting systems, such as shock-tubes and rapid compression machines. The reciprocating internal combustion engine presents many challenges when used to isolate the effects of fuel chemistry from thermodynamics. On the other hand, the conditions in such engines are the most representative in terms of pressure and temperature histories. This paper describes the use of a single-cylinder research engine as an advanced reactor to better determine fuel effects experimentally. In particular, a single-cylinder engine was operated in a manner that allowed the effects of changes in charge composition and temperatures to be isolated from changes in equivalence ratio. An example study is presented where the relative effects of low-temperature and high-temperature chemistry, and their effects on combustion phasing, are isolated and examined.

In the engine community, gasoline compression ignition (GCI) engines are at the forefront of research and efforts are being taken to commercialize an optimized GCI engine in the near future. GCI engines are operated typically at Partially Premixed Combustion (PPC) mode as it offers better control of combustion with improved combustion stability. While the transition in combustion homogeneity from convectional Compression Ignition (CI) to Homogenized Charge Compression Ignition (HCCI) combustion via PPC has been comprehensively investigated, the physical and chemical effects of fuel on GCI are rarely reported at different combustion modes. Therefore, in this study, the effect of physical and chemical properties of fuels on GCI is investigated. In-order to investigate the reported problem, low octane gasoline fuels with same RON = 70 but different physical properties and sensitivity (S) are chosen.

Knock in spark ignition engines is stochastic in nature. It is caused by autoignition in hot spots in the unburned end-gas ahead of the expanding flame front. Knock onset in an engine cycle can be predicted using the Livengood-Wu integral if the variation of ignition delay with pressure and temperature as well as the pressure and temperature variation with crank angle are known. However, knock intensity (KI) is determined by the evolution of the pressure wave following knock onset. In an earlier paper (SAE 2017-01-0689) we showed that KI can be approximated by KI = Z (∂T/∂x)-2 at a fixed operating condition, where Z is a function of Pko, the pressure, and (∂T/∂x) is the temperature gradient in the hot spot at knock onset. Then, from experimental measurements of KI and Pko, using five different fuels, with the engine operating at boosted conditions, a probability density function for (∂T/∂x) was established.

Most studies on knock ignore the stochastic nature of knock and focus on the onset of knock which is determined by chemical kinetics. This paper focuses on knock intensity (KI) which is determined by the evolution of the pressure wave following knock onset in a hot spot and highlights the stochastic processes involved. KI is defined in this study as the maximum peak-to-peak pressure fluctuation that follows the onset of knock. It depends on ξ = (a/ua) where ua is the speed of the autoignition front and a is the speed of sound. When ua is small, KI can be related to the product of a parameter Z, which depends on Pko, the pressure at knock onset and the square of (∂x/∂T), which is the inverse of the gradient of temperature with distance in the hot spot. Both Z and (∂x/∂T) were calculated using measured KI and Pko for hundreds of individual knocking cycles for different fuels.

A multi-objective optimization scheme based on stochastic global search is developed and used to examine the performance of an HCCI model containing a reduced chemical kinetic mechanism, and to study interrelations among different model responses. A stochastic reactor model of an HCCI engine is used in this study, and dedicated HCCI engine experiments are performed to provide reference for the optimization. The results revealed conflicting trends among objectives normally used in mechanism optimization, such as ignition delay and engine cylinder pressure history, indicating that a single best combination of optimization variables for these objectives did not exist. This implies that optimizing chemical mechanisms to maintain universal predictivity across such conflicting responses will only yield a predictivity tradeoff. It also implies that careful selection of optimization objectives increases the likelihood of better predictivity for these objectives.

Octane-on-Demand (OoD) is a promising technology for reducing greenhouse emissions from automobiles. The concept utilizes a low-octane fuel for low and mid load operating conditions, and a high-octane additive is added at high load operating conditions. Researchers have focused on the minimum ethanol content required for operating at high load conditions when the low-octane fuel becomes knock limited. However, it is also widely known that ethanol has a high tendency to pre-ignite, which has been linked with its high laminar flame speed and surface ignition tendency. Moreover, ethanol has a lower stoichiometric air-fuel ratio, requiring a larger injected fuel mass per cycle. A larger fuel mass increases the potential for oil dilution by the liquid fuel, creating precursors for pre-ignition. Hence, the limits on ethanol addition owing to pre-ignition also need consideration before the technology can be implemented.

An earlier paper has shown the ability to predict the phasing of knock onset in a gasoline PFI engine using a simple ignition delay equation for an appropriate surrogate fuel made up of toluene and PRF (TPRF). The applicability of this approach is confirmed in this paper in a different engine using five different fuels of differing RON, sensitivity, and composition - including ethanol blends. An Arrhenius type equation with a pressure correction for ignition delay can be found from interpolation of previously published data for any gasoline if its RON and sensitivity are known. Then, if the pressure and temperature in the unburned gas can be estimated or measured, the Livengood-Wu integral can be estimated as a function of crank angle to predict the occurrence of knock. Experiments in a single cylinder DISI engine over a wide operating range confirm that this simple approach can predict knock very accurately.

This paper is the first of a two part study which investigates the use of advanced combustion modes as a means of improving the efficiency and environmental impact of conventional light-duty vehicles. This first study focuses on the application of so-called Octane-on-Demand combustion, whereby the fuel anti-knock quality is customized to match the real-time requirements of an otherwise conventional spark-ignition engine. Methanol is utilized as the high octane fuel, while three alternative petroleum-derived fuels with Research octane numbers (RONs) ranging from 61 to 90 are examined as candidates for the lower octane fuel. Experimental engine calibration maps are first developed to quantify the minimum amount of methanol that must be added to each lower octane fuel in order to reproduce the baseline engine performance attained on a market gasoline (RON 95). The properties of the lower octane fuel are shown to affect the engine performance significantly.

Conventional fossil fuels will constitute the majority of automotive fuels for the foreseeable future but will have to adapt to changes in engine technology. Unconventional transport fuels such as biofuels, gas-to-liquid fuels, compressed natural gas, and liquid petroleum gas will also play a role. Hydrogen might be a viable transport fuel if it overcomes barriers in production, transport, storage, and safety and/or if fuel cells become viable. This book opens by considering these issues and then introduces practical transport fuels. A chapter on engine deposits follows, which is an important practical topic about how fuels affect engines that is not usually considered in other books. The next three chapters discuss auto-ignition phenomena in engines. The auto-ignition resistance of fuels is the most important fuel property since it limits the efficiency of spark ignition engines and determines the performance of compression ignition engines.

Stochastic pre-ignition remains one of the major barriers limiting further engine downsizing and down-speeding; two widely used strategies for improving the efficiency of spark-ignited engines. One of the most cited mechanisms thought to be responsible for pre-ignition is the ignition of a rogue droplet composed of lubricant oil and fuel. This originates during mixture formation from interactions between the fuel spray and oil on the cylinder liner. In the present study, this hypothesis is further examined using a single cylinder supercharged engine which employs a range of air-fuel mixture formation strategies. These strategies include port-fuel injection (PFI) along with side and central direct injection (DI) of an E5 gasoline (RON 97.5) using single and multiple injection events. Computational fluid dynamic (CFD) calculations are then used to explain the observed trends.

The objective of this study was to investigate the effect of aromatic on combustion stratification and particulate emissions for PRF60. Experiments were performed in an optical CI engine at a speed of 1200 rpm for TPRF0 (100% v/v PRF60), TPRF20 (20% v/v toluene + 80% PRF60) and TPRF40 (40% v/v toluene + 60% PRF60). TPRF mixtures were prepared in such a way that the RON of all test blends was same (RON = 60). Single injection strategy with a fuel injection pressure of 800 bar was adopted for all test fuels. Start of injection (SOI) was changed from early to late fuel injection timings, representing various modes of combustion viz HCCI, PPC and CDC. High-speed video of the in-cylinder combustion process was captured and one-dimensional stratification analysis was performed from the intensity of images. Particle size, distribution and concentration were measured and linked with the in-cylinder combustion images.

Results from a large set of HCCI experiments performed on a single-cylinder research engine fueled with different mixtures of iso-octane and n-heptane are presented and discussed in this paper. The experiments are designed to scrutinize fuel reactivity effects on the operating range of an HCCI engine. The fuel effects on upper and lower operating limits are measured respectively by the maximum pressure rise rate inside the cylinder and the stability of engine operation as determined by cycle-to-cycle variations in IMEP. Another set of experiments that examine the intake air heating effects on HCCI engine performance, exhaust emissions and operating envelopes is also presented. The effects of fuel reactivity and intake air heating on the HCCI ranges are demonstrated by constructing the operating envelopes for the different test fuels and intake temperatures.

Partially premixed combustion (PPC) is an operating mode that lies between the conventional compression ignition (CI) mode and homogeneous charge compression ignition (HCCI) mode. The combustion in this mixed mode is complex as it is neither diffusion-controlled (CI mode) nor governed solely by chemical kinetics (HCCI mode). In this study, CFD simulations were performed to evaluate flame index, which distinguishes between zones having a premixed flame and non-premixed flame. Experiments performed in the optical engine supplied data to validate the model. In order to realize PPC, the start of injection (SOI) was fixed at −40 CAD (aTDC) so that a required ignition delay is created to premix air/fuel mixture. The reference operating point was selected to be with 3 bar IMEP and 1200 rpm. Naphtha with a RON of 77 and its corresponding PRF surrogate were tested. The simulations captured the general trends observed in the experiments well.

Light naphtha is the light distillate from crude oil and can be used in compression ignition (CI) engines; its low boiling point and octane rating (RON = 64.5) enable adequate premixing. This study investigates the combustion characteristics of light naphtha (LN) and its multicomponent surrogate under various start of injection (SOI) conditions. LN and a five-component surrogate for LN, comprised of 43% n-pentane, 12% n-heptane, 10% 2-methylhexane, 25% iso-pentane and 10% cyclo-pentane, has been tested in a single cylinder optical diesel engine. The transition in combustion homogeneity from CI combustion to homogenized charge compression ignition (HCCI) combustion was then compared between LN and its surrogate. The engine experimental results showed good agreement in combustion phasing, ignition delay, start of combustion, in-cylinder pressure and rate of heat release between LN and its surrogate.

Low temperature combustion concepts are studied recently to simultaneously reduce NOX and soot emissions. Optical studies are performed to study gasoline PPC in CI engines to investigate in-cylinder combustion and stratification. It is imperative to perform emission measurements and interpret the results with combustion images. In this work, we attempt to investigate this during the transition from CI to HCCI mode for FACE I gasoline (RON = 70) and its surrogate, PRF70. The experiments are performed in a single cylinder optical engine that runs at a speed of 1200 rpm. Considering the safety of engine, testing was done at lower IMEP (3 bar) and combustion is visualized using a high-speed camera through a window in the bottom of the bowl. From the engine experiments, it is clear that intake air temperature requirement is different at various combustion modes to maintain the same combustion phasing.

Blending gasoline with oxygenates like ethanol, MTBE or ETBE has a proven potential to increase the thermodynamic efficiency by enhancing knock resistance. The present research focuses on assessing the capability of a 2- and tert-butanol mixture as a possible alternative to state-of-the-art oxygenates. The butanol mixture was blended into a non-oxygenated reference gasoline with a research octane number (RON) of 97. The butanol blending ratios were 15% and 30% by mass. Both the thermodynamic potential and the impact on emissions were investigated. Tests are performed on a highly boosted single-cylinder gasoline engine with high load capability and a direct injecting fuel system using a solenoid-actuated multi-hole injector. The engine is equipped with both intake and exhaust cam phasers. The engine has been chosen for the fuel investigation, as it represents the SI technology with a strongly increasing market share.

The blending behavior of ethanol in five different hydrocarbon base fuels with octane numbers of approximately 70 and 84 was examined under Spark-Ignited (SI) and Homogeneous Charge Compression Ignited (HCCI) operating conditions. The Blending octane number (BON) was used to characterize the blending behavior on both a volume and molar basis. Previous studies have shown that the blending behavior of ethanol generally follows several well-established rules. In particular, non-linear blending effects are generally observed on a volume basis (i.e. BON > RON or MON of pure ethanol; 108 and 89, respectively), while linear blending effects are generally observed on a molar basis (i.e. BON = RON or MON of pure ethanol). This work firstly demonstrates that the non-linear volumetric blending effects traditionally observed under SI operating conditions are also observed under HCCI operating conditions.

The effect of ethanol blended with three FACE (Fuels for Advanced Combustion Engines) gasolines, I, J and A corresponding to RON 70.3, 71.8 and 83.5, respectively, were compared to PRF70 and PRF84 with the same ethanol concentrations, these being 2%, 5%, 10%, 15% and 20% by volume. A Cooperative Fuel Research (CFR) engine was used to understand the blending effect of ethanol with FACE gasolines and PRFs in spark-ignited and homogeneous charge compression ignited mode. Blending octane numbers (BON) were obtained for both the modes. All the fuels were also tested in an ignition quality tester to obtain Blending Derived Cetane numbers (BDCN). It is shown that fuel composition and octane number are important characteristics of all the base fuels that have a significant impact on octane increase with ethanol. The dependency of octane number for the base fuel on the blending octane number depended on the combustion mode operated.

The increasing demand for high-octane fuels is pushing the combustion research towards investigating new potential fuels and octane boosters. In addition to their high-octane, those additives should be environmentally friendly. In this study, the anti-knock properties of Dicyclopentadiene (DCPD) as an additive to primary reference fuels (PRF) and toluene primary reference fuels (TPRF) have been investigated. The Research octane number (RON) and Motor octane number (MON) were measured using Cooperative Fuels Research (CFR) engine for four different fuel blends; PRF 60 + 10% DCPD, PRF 60 + 20% DCPD, PRF 70 + 10% DCPD and TPRF 70 + 10% DCPD. In addition, homogenous charge compression ignition (HCCI) was also performed using the CFR engine to show the effect of DCPD on suppressing low temperature chemistry of reference fuels.

Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol.