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A Selective Catalytic Reduction (SCR) system is a simple solution to mitigate high concentration of nitrogen oxides from tail pipe emissions using ammonia as catalyst. In recent years, implementation of stringent emission standards for diesel exhaust made the SCR system even more lucrative aftertreatment solution for diesel engine manufacturer due to its well established reaction mechanism and lower initial cost involved compared to other available options. Nitrogen oxides reduction efficiency and ammonia slip are two main parameters that affects SCR system performance. Therefore, primary design objective of an efficient SCR system is to enhance reduction of nitrogen oxides and control ammonia slip. Both these factors can be improved by having a uniform mixture of ammonia at the SCR inlet. In this mathematical simulation, various parameters that affect accuracy in predicting the uniformity of mixture at the SCR inlet have been documented.

The presented work describes how numerical modeling techniques were extended to simulate a full Selective Catalytic Reduction (SCR) NOx aftertreatement system. Besides predicting ammonia-to-NOX ratio (ANR) and uniformity index (UI) at the SCR inlet, the developed numerical model was able to predict NOx reduction and ammonia slip. To reduce the calculation time due to the complexity of the chemical process and flow field within the SCR, a semi-1D approach was developed and applied to model the SCR catalyst, which was subsequently coupled with a 3D model of the rest of the exhaust system. Droplet depletion of urea water solution (UWS) was modeled by vaporization and thermolysis techniques while ammonia generation was modeled by the thermolysis and hydrolysis method. Test data of two different SCR systems were used to calibrate the simulation results. Results obtained using the thermolysis method showed better agreement with test data compared to the vaporization method.