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Dedicated Exhaust Gas Recirculation (D-EGR®) technology provides a novel means for fuel efficiency improvement through efficient, on-board generation of H2 and CO reformate [1, 2]. In the simplest form of the D-EGR configuration, reformate is produced in-cylinder through rich combustion of the gasoline-air charge mixture. It is also possible to produce more H2 by means of a Water Gas Shift (WGS) catalyst, thereby resulting in further combustion improvements and overall fuel consumption reduction. In industrial applications, the WGS reaction has been used successfully for many years. Previous engine applications of this technology, however, have only proven successful to a limited degree. The motivation for this work was to develop and optimize a WGS catalyst which can be employed to a D-EGR configuration of an internal combustion engine. This study consists of two parts.

The Exhaust Composition Transient Operation LaboratoryTM (ECTO-LabTM) is a burner system developed at Southwest Research Institute (SwRI) for simulation of IC engine exhaust. The current system design requires metering and combustion of nitromethane in conjunction with the primary fuel source as the means of NOX generation. While this method affords highly tunable NOX concentrations even over transient cycles, no method is currently in place for dictating the speciation of nitric oxide (NO) and nitrogen dioxide (NO2) that constitute the NOX mixture. NOX generated through combustion of nitromethane is dominated by NO, and generally results in an NO2:NOX ratio of < 5 %. Generation of any appreciable quantities of NO2 is therefore dependent on an oxidation catalyst to oxidize a fraction of the NO to NO2.

A dilute spark-ignited engine concept has been developed as a potential low cost competitor to diesel engines by Southwest Research Institute (SwRI), with a goal of diesel-like efficiency and torque for light- and medium-duty applications and low-cost aftertreatment. The targeted aftertreatment method is a traditional three-way catalyst, which offers both an efficiency and cost advantage over typical diesel aftertreatment systems. High levels of exhaust gas recirculation (EGR) have been realized using advanced ignition systems and improved combustion, with significant improvements in emissions, efficiency, and torque resulting from using high levels of EGR. The primary motivation for this work was to understand the impact high levels of EGR would have on particulate matter (PM) formation in a port fuel injected (PFI) engine. While there are no proposed regulations for PFI engine PM levels, the potential exists for future regulations, both on a size and mass basis.

Experiments were performed on a 2.4L boosted, MPI gasoline engine, equipped with a low-pressure loop (LPL) cooled EGR system and an advanced ignition system, using fuels with varying anti-knock indices. The fuels were blends of 87, 93 and 105 Anti-Knock Index (AKI) gasoline. Ignition timing and EGR sweeps were performed at various loads to determine the tradeoff between EGR level and fuel octane rating. The resulting engine data was analyzed to establish the relationship between the octane requirement and the level of cooled EGR used in a given application. In addition, the combustion difference between fuels was examined to determine the effect that fuel reactivity, in the form of anti-knock index (AKI), has on EGR tolerance and burn rate. The results indicate that the improvement in effective AKI of the fuel from using EGR is constant across commercial grade gasolines at about 0.5 ON per % EGR.

Experiments were performed on a small displacement (< 2 L), high compression ratio, 4 cylinder, port injected gasoline engine equipped with Dedicated EGR® (D-EGR®) technology using fuels with varying anti-knock properties. Gasolines with anti-knock indices of 84, 89 and 93 anti-knock index (AKI) were tested. The engine was operated at a constant nominal EGR rate of ∼25% while varying the reformation ratio in the dedicated cylinder from a ϕD-EGR = 1.0 - 1.4. Testing was conducted at selected engine speeds and constant torque while operating at knock limited spark advance on the three fuels. The change in combustion phasing as a function of the level of overfuelling in the dedicated cylinder was documented for all three fuels to determine the tradeoff between the reformation ratio required to achieve a certain knock resistance and the fuel octane rating.

The use of cooled EGR as a knock suppression tool is gaining more acceptance worldwide. As cooled EGR become more prevalent, some challenges are presented for engine designers. In this study, the impact of cooled EGR on peak cylinder pressure was evaluated. A 1.6 L, 4-cylinder engine was operated with and without cooled EGR at several operating conditions. The impact of adding cooled EGR to the engine on peak cylinder pressure was then evaluated with an attempt to separate the effect due to advanced combustion phasing from the effect of increased manifold pressure. The results show that cooled EGR's impact on peak cylinder pressure is primarily due to the knock suppression effect, with the result that an EGR rate of 25% leads to an almost 50% increase in peak cylinder pressure at a mid-load condition if the combustion phasing is advanced to Knock Limited Spark Advance (KLSA). When combustion phasing was held constant, increasing the EGR rate had almost no effect on PCP.

Because of the thermodynamic relationship of pressure, temperature and volume for processes which occur in an internal-combustion engine (ICE), and their relationship to ideal efficiency and efficiency-limiting phenomena e.g. knock in spark-ignition engines, changing the thermo-chemical properties of the in-cylinder charge should be considered as an increment in the development of the ICE engine for future efficiency improvements. Exhaust gas recirculation (EGR) in spark-ignited gasoline engines is one increment that has been made to alter the in-cylinder charge. EGR gives proven thermal efficiency benefits for SI engines which improve vehicle fuel economy, as demonstrated through literature and production applications. The thermal efficiency benefit of EGR is due to lower in-cylinder temperatures, reduced heat transfer and reduced pumping losses. The next major increment could be modifying the constituents of the EGR stream, potentially through the means of a membrane.

The spark ignition (SI) engine has been known to exhibit several different abnormal combustion phenomena, such as knock or pre-ignition, which have been addressed with improved engine design or control schemes. However, in highly boosted SI engines - where the engine displacement is reduced and turbocharging is employed to increase specific power - a new combustion phenomenon, described as Low-Speed Pre-Ignition (LSPI), has been exhibited. LSPI is characterized as a pre-ignition event typically followed by heavy knock, which has the potential to cause degradation of the engine. However, because LSPI events occur only sporadically and in an uncontrolled fashion, it is difficult to identify the causes for this phenomenon and to develop solutions to suppress it. Some countermeasures exist that OEMs can use to avoid LSPI, such as load limiting, but these have drawbacks.

In light of the increasingly stringent efficiency and emissions requirements, several new engine technologies are currently under investigation. One of these new concepts is the Dedicated EGR (D-EGR®) engine. The concept utilizes fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency. While the positive impact of reformate, in particular hydrogen, on gasoline engine performance has been widely documented, the on-board reforming process and / or storage of H2 remains challenging. The Water-Gas-Shift (WGS) reaction is well known and has been used successfully for many years in the industry to produce hydrogen from the reactants water vapor and carbon monoxide. For this study, prototype WGS catalysts were installed in the exhaust tract of the dedicated cylinder of a turbocharged 2.0 L in-line four cylinder MPI engine. The potential of increased H2 production in a D-EGR engine was evaluated through the use of these catalysts.

Selective Catalytic Reduction is the primary method of NOX emission abatement in lean-burn internal combustion. This process requires the decomposition of a 32.5 wt. % urea-water solution (UWS) to provide ammonia as a reducing agent for NOX, but at temperatures < 250 °C the injection of UWS is limited due to the formation of harmful deposits within an aftertreatment system and decreased ammonia production. Previous work has sufficiently demonstrated that the addition of surfactant and a urea/isocyanic acid (HNCO) decomposition catalyst to UWS can significantly decrease deposit formation within an aftertreatment system. The objective of this work was to further optimize the modified UWS formulation by investigating different types and concentrations of surfactants and titanium-based urea/HNCO catalyst. Because there is a correlation between surface tension and water evaporation, it was theorized that minimizing the surface tension of UWS would result in decreased deposit formation.

SCR-on-filter, or SCRoF, is an emerging technology for different market segments and vehicle applications. The technology enables simultaneous particulate matter trapping and NOX reduction, and provides thermal management and aftertreatment packaging benefits. However, there is little information detailing the lubricant derived exposure effects on functional SCR performance. A study was conducted to evaluate the impact of various oil consumption pathways on a light duty DOC and SCRoF aftertreatment system. This aftertreatment system was aged utilizing an engine test bench modified to enable increased oil consumption rates via three unique oil consumption pathways. The components were characterized for functional SCR performance, ash morphology, and ash deposition characteristics. This included utilizing techniques, such as SEM / EDS, to evaluate the ash structures and quantify the ash elemental composition.

High dilution engines have been shown to have a significant fuel economy improvement over their non-dilute counterparts. Much of this improvement comes through an increase in compression ratio enabled by the high knock resistance from high dilution. Unfortunately, the same reduction in reactivity that leads to the knock reduction also reduces flame speed, leading to the engine becoming unstable at high dilution rates. Advanced ignition systems have been shown to improve engine stability, but their impact is limited to the area at, or very near, the spark plug. To further improve the dilute combustion, a system in which a microwave field is established in the combustion chamber is proposed. This standing electric field has been shown, in other applications, to improve dilution tolerance and increase the burning velocity.

The primary focus of this investigation was to determine the hydrogen reformation, efficiency and knock mitigation benefits of methanol-fueled Dedicated EGR (D-EGR®) operation, when compared to other EGR types. A 2.0 L turbocharged port fuel injected engine was operated with internal EGR, high-pressure loop (HPL) EGR and D-EGR configurations. The internal, HPL-EGR, and D-EGR configurations were operated on neat methanol to demonstrate the relative benefit of D-EGR over other EGR types. The D-EGR configuration was also tested on high octane gasoline to highlight the differences to methanol. An additional sub-task of the work was to investigate the combustion response of these configurations. Methanol did not increase its H2 yield for a given D-EGR cylinder equivalence ratio, even though the H:C ratio of methanol is over twice typical gasoline.

The ongoing pursuit of improved engine efficiency and emissions is driving gasoline low-pressure loop EGR systems into production around the globe. The Dedicated EGR (D-EGR®) engine was developed to minimize some of the challenges of cooled EGR while maintaining its advantages. The D-EGR engine is a high efficiency, low emissions internal combustion engine for automotive and off-highway applications. The core of the engine development focused on a unique concept that combines the efficiency improvements associated with recirculated exhaust gas and the efficiency improvements associated with fuel reformation. To outline the differences of the new engine concept with a conventional LPL EGR setup, a turbocharged 2.0 L PFI engine was modified to operate in both modes. The second part of the cooled EGR engine concept comparison investigates efficiency, knock resistance, combustion stability, and maximum load potential at high load conditions.

The ongoing pursuit of improved engine efficiency and emissions are driving gasoline low-pressure loop EGR systems into production around the globe. To minimize inevitable downsides of cooled EGR while maintaining its advantages, the Dedicated EGR (D-EGR®) engine was developed. The core of the D-EGR engine development focused on a unique concept that combines the efficiency improvements associated with recirculated exhaust gas and the efficiency improvements associated with fuel reformation. To outline the differences of the new engine concept with a conventional low-pressure loop (LPL) EGR setup, a turbocharged 2.0 L PFI engine was modified to operate in both modes and also compared to the baseline. The first part of the cooled EGR engine concept comparison investigates efficiency, emissions, combustion stability, and robustness at throttled part load conditions.

Ideally, complete thermal decomposition of urea should produce only two products in active Selective Catalytic Reduction (SCR) systems: ammonia and carbon dioxide. In reality, urea thermal decomposition reaction includes the formation of isocyanic acid as an intermediate product. Being highly reactive, isocyanic acid can initiate the formation of larger molecular weight compounds such as cyanuric acid, biuret, melamine, ammeline, ammelide, and dicyandimide [1,2,3,4]. These compounds can be responsible for the formation of deposits on the walls of the decomposition reactor in urea SCR systems. Composition of these deposits varies with temperature exposure, and under certain conditions, can create oligomers such as melam, melem, and melon [5, 6] that are difficult to remove from exhaust systems. Deposits can affect the efficiency of the urea decomposition, and if large enough, can inhibit the exhaust flow.

Ideally, complete decomposition of urea should produce only two products in active Selective Catalytic Reduction (SCR) systems: ammonia and carbon dioxide. In reality, urea decomposition reaction is a two-step process that includes the formation of ammonia and isocyanic acid as intermediate products via thermolysis. Being highly reactive, isocyanic acid can initiate the formation of larger molecular weight compounds such as cyanuric acid (CYN), biuret (BIU), melamine (MEL), ammeline (AML), ammelide (AMD), and dicyandimide (DICY). These compounds can be responsible for the formation of deposits on the walls of the decomposition reactor in urea SCR systems. Composition of these deposits varies with temperature exposure, and under certain conditions can create oligomers that are difficult to remove from exhaust pipes. Deposits can affect efficiency of the urea decomposition, and if large enough, can inhibit the exhaust flow and negatively impact ammonia distribution on the SCR catalyst.

Mitigation of urea deposit formation and improved ammonia production at low exhaust temperatures continues to be one of the most significant challenges for current generation selective catalytic reduction (SCR) aftertreatment systems. Various technologies have been devised to alleviate these issues including: use of alternative reductant sources, and thermal treatment of the urea-water solution (UWS) pre-injection. The objective of this work was to expand the knowledge base of a potential third option, which entails chemical modification of UWS by addition of a titanium-based urea/isocyanic acid (HNCO) decomposition catalysts and/or surfactant to the fluid. Physical solid mixtures of urea with varying concentrations of ammonium titanyl oxalate (ATO), oxalic acid, and titanium dioxide (TiO2) were generated, and the differences in NH3 and CO2 produced upon thermal decomposition were quantified.

In response to the sensitivity to diesel aftertreatment costs in the medium duty market, a John Deere 4045 was converted to burn gasoline with high levels of EGR. This presented some unique challenges not seen in light duty gasoline engines as the flat head and diesel adapted ports do not provide optimum in-cylinder turbulence. As the bore size increases, there is more opportunity for knock or incomplete combustion to occur. Also, the high dilution used to reduce knock slows the burn rates. In order to speed up the burn rates, various levels of swirl were investigated. A four valve head with different levels of port masking showed that increasing the swirl ratio decreased the combustion duration, but ultimately ran into high pumping work required to generate the desired swirl. A two valve head was used to overcome the breathing issue seen in the four valve head with port masking.

The use of cooled EGR in gasoline engines improves the fuel efficiency of the engine through a variety of mechanisms, including improving the charge properties (e.g. the ratio of specific heats), reducing knock and enabling higher compression ratio operation and, at part loads conditions in particular, reducing pumping work. One of the limiting factors on the level of improvement from cooled EGR is the ability of the ignition system to ignite a dilute mixture and maintain engine stability. Previous work from SwRI has shown that, by increasing the ignition duration and using a continuous discharge ignition system, an improved ignition system can substantially increase the EGR tolerance of an engine [1, 2]. This improvement comes at a cost, however, of increased ignition system energy requirements and a potential decrease in spark plug durability. This work examines the impact of engine operating parameters on the ignition energy requirements under high dilution operation.