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Polyurethane chemists have been challenged for many years to develop a laboratory scale test to measure the reactivity of polyurethane foam systems. The task is complicated by the need for the test to satisfy the requirements of both the researcher and polyurethane foamer. Numerous tests have been developed to address this task. However, the cup foam test continues to be the industry standard for quick and easy measurement of the overall reactivity of polyurethane foam systems. The characteristics of a small scale laboratory test which measures the rise profile and adiabatic temperature profile of flexible, semi-flexible (semi-rigid) and rigid polyurethane foam systems will be presented.

Joining dissimilar parts in automotive interior trim applications has been accomplished by utilizing mechanical fasteners, organic and water based adhesives, and more recently, thermoplastic polymers. Recent trends towards reducing solvent emissions and waste management problems, improving the consistency of adhesive application, integrating parts, lowering parts fabrication costs, and designing a specified bond level has increased the use of thermoplastic adhesive films as bonding agents in several applications. Initial efforts began over fifteen years ago with Dow Adhesive Films (DAF) being designed for bonding interior trim fabrics to various substrates. Films have subsequently been designed to improve performance of many interior trim parts in many ways such as: improving water resistance, allowing the part to be molded before installation, imparting a slip surface to a part, and supporting a non-woven fabric.

The persistent occurrence of microporosity defects in AZ91 castings has made it difficult to consistently produce sound parts. Earlier work established that dissolved hydrogen gas causes microporosity defects in AZ91; however, the exact role of hydrogen in the nucleation and growth of microporosity was not determined. In this paper, the behavoir of dissolved hydrogen gas in elemental magnesium, AZ91 alloy, and liquid binary Mg/Al alloys was studied. The results show that during the last stages of solidification, hydrogen gas is rejected from the Mg17Al12 intermetallic compound to assist in the nucleation and/or growth of microporosity.

The effect of non-metallic inclusions (NMIs) on the properties of die cast magnesium was investigated. NMI content was quantified by a newly developed light reflectance technique. The mechanical properties of optimized AM60B test bars were found to decrease at high inclusion levels. Low inclusion levels did not statistically reduce the mechanical properties of AM60B as compared to virgin metal. Argon-refined AM60B displayed mechanical properties that were indistinguishable from virgin alloy. AZ91D test plates were die cast at various cleanliness levels. After salt spray testing, it was found that the surface quality of the castings was slightly degraded at high NMI levels. The general corrosion performance was also affected, but paint adhesion was relatively unaffected. At high NMI levels, the corrosion performance was still better than 380 A. Machinability of the AZ91D test plates was quantified by measuring tool wear and cutting forces.

With the introduction of high purity corrosion resistant magnesium alloys and also the re-emphasis of quality products throughout the industrial world, the need for more accurate and more reproducible analysis between laboratories has become apparent. The availability of high quality analytical standards was one of the principle obstacles to achieving analytical agreement between laboratories. This presentation briefly reviews what until recently was available to the industry and their customers with respect to analytical methods and analytical standards and their limitations in today's quality conscious world. The development of a new series of die cast magnesium standards by The Dow Chemical Company is also described in this paper including their compositional design considerations relating to the selection of the modern direct reading emission spectrometer as the analytical instrument of choice.

The magnesium alloy AE42 (nominally a 4 % aluminum, 2 % rare earth alloy of magnesium) is a developmental die cast alloy with good strength and creep resistance at elevated temperatures. Standard salt spray corrosion tests have been used with controlled purity AE42 die castings to define the critical iron, nickel and copper contaminant levels below which excellent corrosion performance can be obtained. As previously observed with the magnesium alloys AZ91, AM60, and AS41, the critical iron content is dependent upon the manganese content of the alloy. While the iron:manganese tolerance for AE42 is about the same as that of AM60, the tolerance for the nickel and copper contaminants is greater than that of AZ91. When each of these contaminants is less than the critical level, the salt spray performance was equal to or better than die cast 380 aluminum and cold rolled steel.

Syndiotactic potystyrene (SPS) is a new semi-crystalline polymer under development by Dow Plastics, a business group of The Dow Chemical Company. The material is differentiated from conventional styrenic polymers in terms of microstructure and physical properties and represents the basis for an entirely new family of materials derived from crystalline polystyrene. SPS exhibits excellent thermal performance with a melting point of 270° C (520° F) combined with resistance to moisture and automotive fluids. Products produced from SPS demonstrate exceptional electrical performance, low specific gravity, competitive toughness and high modulus relative to other semi-crystalline engineering polymers. A wide range of products have been formulated including impact modified and glass reinforced resins for use in specific markets.

The opportunity for composites in engine closure systems such as valve covers, oil pans, and timing belt covers is expanding rapidly. The primary driving forces are lighter weight finished components, integrated designs, improved isolation of engine noise, improved materials systems, and matured manufacturing processes for composite materials. Thermoset-based composite materials, particularly those based on high-temperature resistant epoxy vinyl ester matrices, offer improved performance with respect to thermoplastic and thermoset polyester-based composites and can be manufactured using different processing methods. This paper presents the current state-of-the-art design, engineering and optimization techniques for engine closure systems. The performance requirements of different systems such as valve covers and oil pans are explained in detail. Techniques for long-term structural stiffness evaluation, vibration performance assessment and noise transmission estimation are described.

Recent growth in automotive applications of magnesium die cast alloys has made the refining and recycling of magnesium scrap a key issue for the automotive and magnesium industries, if growth is to continue. Today, with only a few exceptions, commercially refined and recycled alloy is produced using a variety of flux-based processes. However, fluxless refining, has been the focus of growing interest, particularly for the in-house refining of scrap by the die cast producers. This paper summarizes the results of a study conducted to better understand the behavior of non-metallic contaminants in scrap melts and the requirements for their separation, using argon sparging. Brightness measurements were used to experimentally determine the distribution of non-metallic contaminants within scrap melts both before and after argon treatment.

Syndiotactic Polystyrene (SPS) is a new semi-crystalline polymer under development by Dow Plastics. The material is completely different from conventional styrenics in structure, physical properties and synthetic method, and represents the basis for an entirely new family of materials based on crystalline polystyrene. SPS has a melting point of 270°C (520°F) combined with excellent resistance to moisture and automotive fluids. Additionally, SPS products exhibit exceptional electrical performance and competitive toughness and stiffness. A wide range of products have been formulated for specific applications including impact-modified and glass-reinforced grades. This paper was designed to discuss the performance attributes of SPS as they relate to use of this material in automotive, interconnect systems where a combination of heat resistance, chemical resistance, dimensional stability and enhanced processability are required.

The objective of this paper will be to review a novel recycle process involving Structural Reaction Injection Molding(SRIM) which enables a variety of coarsely ground plastic recycle materials to be incorporated into the molded part. What makes this approach novel, is that flexural modulus of the fabricated parts are actually increased when the recycled granulate is employed in the part. This paper will present data for the recycle of a variety of automotive parts, including painted fascia, door skins, covered interior door panels, armrests and instrument panels along with composite bumper beams into the SRIM recycle core process. Resulting part economics will be reviewed along with potential applications to utilize this technology.

A family of thermoplastic Polyurethane (TPU) blends is being developed to compete in the flexible automotive bumper fascia market. Features of these blends include paintability without adhesion promoter or primer, ease of processing, outstanding low temperature impact strength, good mar resistance, and excellent property retention upon recycling. Laboratory and application performance data indicate that painted TPU/ABS Blend XT2100 regrind can be incorporated up to a 25% level into flexible thermoplastic fascia without sacrificing impact resistance.

A highly reflective polymeric sheet has been invented which has a metallic appearance but contains no metal. The material can appear chrome-like, or be designed to transmit and reflect light for novel lens applications. The absence of metal waste streams and volatile organic emissions gives this technology significant environmental advantages over competitive methods of bright work or reflector fabrication. This unique optical material is non-corroding, and has the low thermal and electrical conductance of plastic. It is produced by coextruding a large number of alternating layers of polymers having a refractive index difference. This technology offers new degrees of freedom for light control in many applications including lighting reflectors, lenses, display panels, decorative trims, and energy management.

In 1998, approximately 57,000 Tonnes of plastic composites were utilized as body panels on cars and trucks in North America. Three material types, generically labeled SMC, RIM and Thermoplastic are vying to carve a market niche from steel which dominates the market place with an estimated volume of 1 million Tonnes per year. Since plastic body panels have higher material costs but lower tooling costs, they are primarily utilized when build volumes are less than 200,000 vehicles per year or specific composite performance capabilities are demanded. This paper reviews the various performance parameters required of a body panel material and the relative strengths of Aluminum, RIM, SMC, Steel and Thermoplastics to meet these demands. A decision making process is utilized which allows for a comparison between the different materials. Since cost is so critical, it is left as an independent variable.

Novel acoustical materials have been developed. The materials are thermoplastic foams extruded from blends of a polypropylene (PP) resin with an ethylenic polymer resin. One material is an open-cell sheet product made from a blend of a PP resin and a polyolefin elastomer (POE). Another is a large-celled plank foam of substantially closed-cell structure made from a blend of a polypropylene resin and a low density polyethylene (PE) resin. The foam materials are of lightweight, hydrophobic, dust free, recyclable and withstand the temperatures prevailing in automotive uses.

A new family of high heat stable, few gloss ABS resins has been developed specifically to offer the automotive industry improved performance in molded interior trim parts. The new resins offer excellent fabrication and property performance similar to that of standard-heat low gloss ABS resins. Advantages over current high heat ABS resins include improved injection moldability, greater resistance to heat warping and to U.V. degradation, improved color stability, improved toughness, and consequent good finished part economics while maintaining equivalent heat resistance. Physical property and testing-evaluation data are provided.

The use of low density reinforced Reaction Injection Molded (RIM) substrates for covered interior automotive articles continues to increase globally. Reduced party mass, consolidation of manufacturing steps (labor), and the use of aluminum tooling, instead of steel, are cited advantages that LD-RIM offers when compared to traditional wood based and thermoplastic materials. Two RIM processes are successfully being used to produce covered interior door panels. Low density structural RIM (LD-SRIM), utilizing conventional RIM equipment, involves the placement of a pre-cut fiberglass mat in the tool cavity prior to open-pour injection of the 2-stream liquid urethane components. Low density reinforced RIM (LD-RRIM), utilizing lance cylinder RIM equipment, incorporates reinforcing fibers, such as milled fiberglass or wollastonite, in the liquid resin component. The liquid resin containing reinforcing filler is injected with the isocyanate component into a closed mold.

Structural instrument panels are an excellent alternative to traditional constructions since they can provide substantial part consolidation, weight reduction, tool and cost savings, and manufacturing and assembly simplification. In structural panels, the main energy absorbing element for decelerating an unrestrained occupant is the plastic integrated retainer-structural duct. The role of the components in the instrument panel needs to be clearly understood for adequately engineering the system and properly selecting the polymeric material for optimum system performance in the different operating environments. The present paper discusses the performance of the structural instrument panel, the engineering and design requirements, and provides guidelines for selection of materials.

A method for refining magnesium scrap which produces consistent, high quality magnesium metal has been developed. High quality magnesium metal is defined in this paper as metal which has heavy metal contaminants controlled within high-purity ASTM chemical specification, and is relatively free of internal impurities such as non-metallic inclusions (oxides and flux) and dissolved gas. The refining process utilizes a protective gas atmosphere, inert gas sparging and filtration techniques, rather than salt based fluxes, to remove both non-metallic inclusions and dissolved gases. Experimentation results of this refining process indicate magnesium scrap can be remelted and refined to a quality equal to or better than virgin ingot, without the introduction of salt based fluxes or a large capital investment.

The relationship between hydrogen gas and microporosity in magnesium alloy AZ91 was quantified, refuting the belief that hydrogen levels less than the maximum solid solubility are of no detriment. Sand castings were made from melts containing measured levels of hydrogen gas, and the amount of porosity was determined by density measurements. At concentrations below the maximum solid solubility, it was established that the amount of microporosity is directly proportional to the gas content. This supports the premise that dissolved hydrogen gas provides nucleation sites for microporosity, and that it is useful to remove all gas to achieve porosity-free cast parts.