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It is becoming increasingly difficult to obtain good repeatability from running lab vehicle correlation testing, since vehicle variability is so significant at the Low ULEV and SULEV emissions levels. These new emission standards are becoming so stringent that it makes it very difficult to distinguish whether a problem is a result of vehicle variability, test cell sampling or the analytical system. A vehicle exhaust emission simulator (VEES) developed by Horiba, can simulate emissions from low emitting gasoline vehicles by producing tailpipe flow rates containing emissions constituents ( HC, CH4, CO, NOx, CO2 ) injected at the tailpipe flow stream via mass flow controllers.

Diesel fuel is a blend of various middle distillate components separated at the refinery. The composition and characteristics of the diesel fuel blend changes daily if not hourly because of normal process variation, changing refinery processing conditions, changing crude oil diet or changing diesel fuel and kerosene market conditions. Regardless of the situation going on at the refinery or the market, the resultant diesel fuel must consistently meet established cloud point specifications. To consistently meet the cloud point specifications, refiners are forced to blend their diesel fuels in such a way that the resultant blend is always on the low side of the cloud point specification even when the refining process adversely changes the fuel characteristics. This practice has the effect of producing several degrees of cloud point “giveaway” when the refinery is not experiencing adverse swings in product quality.

Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.

Characteristics of E diesel, a fuel blend of diesel fuel and ethanol, are considered in a matrix of tests. One characteristic of particular concern and a subject of this investigation is that of stability. Methods to evaluate stability are looked at and compared in light of the potential for distillate and ethanol to separate under certain conditions. The quality of the fuel blend is enhanced by the use of enabling additives to ensure stability which necessitates development of a standard for assessment of the quality of stability. The properties of various base diesel fuels and their influence on stability are also studied. Other key characteristics are evaluated including viscosity, pour point, and oxidative stability.

Recently, research and testing of oxygenated diesel fuels has increased, particularly in the area of exhaust emissions. Included among the oxygenated diesel fuels are blends of diesel fuel with ethanol, or E diesel fuels. Exhaust emissions testing of E diesel fuel has been conducted by a variety of test laboratories under various conditions of engine type and operating conditions. This work reviews the existing public data from previous exhaust emissions testing on E diesel fuel and includes new testing performed in engines of varied design. Emissions data compares E diesel fuel with normal diesel fuel under conditions of different engine speeds, different engine loads and different engine designs. Variations in performance under these various conditions are observed and discussed with some potential explanations suggested.

As SULEV emission regulations approach, the bag mini-diluter (BMD) technology is gaining acceptance as a replacement for the existing constant volume sampler (CVS) for SULEV exhaust emission measurement and certification. The heart of the BMD system is the direct vehicle exhaust (DVE) flow measurement system. Due to the transient nature of vehicle exhaust during a standard FTP emission test cycle, the DVE must be capable of rapid and accurate response in order to track these varying exhaust flow rates. The DVE must also be robust enough to accurately measure flow rate despite variations in exhaust gas composition, pulsation effects, and rapid changes in both exhaust temperature and pressure. One of the primary DVE systems used on BMDs is the E-Flow, an ultrasonic flow meter manufactured by Flow Technologies, Inc.

This paper features the results of emission tests conducted on diesel oxidation catalysts, and the combination of diesel oxidation catalysts and water blend fuel (diesel fuel continuous emulsion). Vehicle chassis emission tests were conducted using an urban bus. The paper reviews the impact and potential benefits of combining catalyst and water blend diesel fuel technologies to reduce exhaust emissions from diesel engines.

The search for alternative energy sources, particularly renewable sources, has led to increased activity in the area of ethanol blended diesel fuel, or E diesel. E diesel offers potential benefits in reducing greenhouse gases, reducing dependence on crude oil and reducing engine out emissions of particulate matter. However, there are some concerns about the use of E diesel in the existing vehicle fleet. One of the chief concerns of the use of E diesel is the affect of the ethanol on the lubricating properties of the fuel and the potential for fuel system wear. Additive packages that are used to formulate E diesel fuels can improve fuel lubricity and prevent abnormal fuel system wear. This work studies the lubricity properties of several E diesel blends and the diesel fuels that are used to form them. In addition to a variety of bench scale lubricity tests, injector pump tests were performed as an indicator of long term durability in the field.

Downsized gasoline engines, coupled with gasoline direct injection (GDI) and turbocharging, have provided an effective means to meet both emissions standards and customers’ drivability expectations. As a result, these engines have become more and more common in the passenger vehicle marketplace over the past 10 years. To maximize fuel economy, these engines are commonly calibrated to operate at low speeds and high engine loads – well into the traditional ‘knock-limited’ region. Advanced engine controls and GDI have effectively suppressed knock and allowed the engines to operate in this high efficiency region more often than was historically possible. Unfortunately, many of these downsized, boosted engines have experienced a different type of uncontrolled combustion. This combustion occurs when the engine is operating under high load and low speed conditions and has been named Low Speed Pre-Ignition (LSPI). LSPI has shown to be very damaging to engine hardware.

Vehicle evaluations and model calculations were conducted on a vacuum-insulated catalytic converter (VICC). This converter uses vacuum and a eutectic PCM (phase-change material) to prolong the temperature cool-down time and hence, may keep the converter above catalyst light-off between starts. Tailpipe emissions from a 1992 Tier 0 5.2L van were evaluated after 3hr, 12hr, and 24hr soak periods. After a 12hr soak the HC emissions were reduced by about 55% over the baseline HC emissions; after a 24hr soak the device did not exhibit any benefit in light-off compared to a conventional converter. Cool-down characteristics of this VICC indicated that the catalyst mid-bed temperature was about 180°C after 24hrs. Model calculations of the temperature warm-up were conducted on a VICC converter. Different warm-up profiles within the converter were predicted depending on the initial temperature of the device.

With the adoption of the California Low-Emission Vehicle Regulations and the associated lower emission standards such as LEV (Low-Emission Vehicle in 1990), ULEV (Ultra-Low-Emission Vehicle), and LEV II (1998 with SULEV-Super Ultra Low Emission Vehicle), concerns were raised by emissions researchers over the accuracy and reliability of collecting and analyzing emissions measurements at such low levels. The primary concerns were water condensation, optimizing dilution ratios, and elimination of background contamination. These concerns prompted a multi-year research program looking at several new sampling techniques. This paper will describe the cooperative research conducted into one of these new technologies, namely the Bag Mini-Diluter (BMD) and Direct Vehicle Exhaust (DVE) Volume system.

Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

The engine-out emissions and fuel consumption rates for a modern, heavy-duty diesel engine were compared when fueling with a conventional diesel fuel and three water-blend-fuel emulsions. Four different fuels were studied: (1) a conventional diesel fuel, (2) PuriNOx,™ a water-fuel emulsion using the same conventional diesel fuel, but having 20% water by mass, and (3,4) two other formulations of the PuriNOx™ fuel that contained proprietary chemical additives intended to improve combustion efficiency and emissions characteristics. The emissions data were acquired with three different injection-timing strategies using the AVL 8-Mode steady-state test method in a Caterpillar 3176 engine, which had a calibration that met the 1998 nitrogen oxides (NOX) emissions standard.

Forthcoming on-highway 2005/2007 European and North American emission regulations will require modern diesel engines to be equipped with Diesel Particulate Filters (DPF) capable of trapping up to 99% of the exhaust particulate matter. Since diesel particulates (soot) accumulate in the filter over time, the overall system needs to be regenerated by attaining the ignition temperature of soot, which in the presence of oxygen is >600 °C. Catalyzed DPFs regenerate at temperatures as low as ∼300 °C. One of the major issues facing OEMs, aftertreatment system manufacturers, and lubricant formulators is the potential effects of the lubricant-derived ash deposits and their impact on a pressure increase across filters, as well as overall filter performance and its service characteristics.

A new generation of fluid technology using novel diesel fuel detergent/dispersant chemistry provides a multitude of beneficial effects to the diesel engine, especially the latest model designs. In addition to improved injector, valve and combustion chamber deposit removal, the additive restores power, fuel economy, performance and emission levels1. Positive observations have also been documented along with improved performance concerning crankcase lube viscosity, soot loading and TBN retention. An even greater added benefit is the inherent capability of the fuel additive to deal with several EGR issues now prominent with the introduction of new engines. Recent research, reported herein, has uncovered the extensive efficacy of this chemistry for piston durability and neutralization of ring corrosion phenomena. All of the beneficial additive attributes are further enhanced with increased oxidative and thermal fuel stability and no loss of filterability.

A new gas phase kinetic model using Westbrook's gas phase n-heptane model and Frenklach's soot model was constructed. This model was then used to predict the impact on PAH formation as an indices of soot formation on ethanol/diesel fuel blends. The results were then compared to soot levels measured by various researchers. The ignition delay characteristics of ethanol were validated against experimental results in the literature. In this paper the results of the model and the comparison with experimental results will be discussed along with implications on the method of incorporation of additives and alternative fuels.

Many marketers of branded diesel fuels are introducing a “premium” diesel fuel grade. The National Conference on Weights and Measures is recommending that one of the criteria for marketing a fuel as “premium” is that it have a lower cloud point or alternatively a reduced low temperature flow test (LTFT) failure point [1]. However, waxy crudes and process limitations make it difficult for refiners to economically make very low cloud point diesel fuel. Fortunately, cloud point depressants (CPDs) can overcome these limitations. However, refiners are concerned about the effect cloud point additives have on other diesel fuel properties. We found that cloud point depressants allow refiners to meet low temperature specifications while being neutral or beneficial to other diesel fuel properties.

Cloud point depressants (CPD) have been successfully used for many years in low-sulfur diesel fuels. For over ten years, custom-designed, specialty polymer chemistry has enabled refiners to meet cloud point (CP) guidelines with substantially less kerosene. This translates into greater refined yields through cut-point adjustment upgrades and the potential for diverting kerosene to more lucrative market opportunities, such as jet fuel. The practice of cut-point downgrades to gas oil can be costly because diesel fuel generally has greater value. Kerosene dilutions have historically been as high as 30%-40% by volume with low-sulfur diesel fuels [1, 2]. While kerosene addition enables fuels to reach CP guidelines, it may negatively impact the fuel's energy content, cetane number, lubricity, flash point and density. Properly designed CP additives are able to substantially reduce or even eliminate the need for kerosene, thus substantially reducing refinery costs.

This paper reports on DaimlerChrysler's participation in the Ad Hoc Diesel Fuels Test Program. This program was initiated by the U.S. Department of Energy and included major U.S. auto makers, major U.S. oil companies, and the Department of Energy. The purpose of this program was to identify diesel fuels and fuel properties that could facilitate the successful use of compression ignition engines in passenger cars and light-duty trucks in the United States at Tier 2 and LEV II tailpipe emissions standards. This portion of the program focused on minimizing engine-out particulates and NOx by using selected fuels, (not a matrix of fuel properties,) in steady state dynamometer tests on a modern, direct injection, common rail diesel engine.