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For applications of planar laser induced fluorescence (PLIF) to measure the fuel or equivalence ratio distributions in internal combustion (IC) engines it is typically assumed that the addition of a fluorescence tracer to a base fuel does not alter the combustion performance. We have investigated the impact on combustion performance through the addition of various amounts of 3-pentanone or toluene to iso-octane fuel. Correlations between equivalence ratio for a range of fuel/tracer mixtures and engine parameters, like peak pressure, location of peak pressure, indicated mean effective pressure (IMEP), and peak burn rate are discussed for data obtained in a spark-ignition direct-injection (SIDI) gasoline engine operated with near homogeneous charge. For typical tracer concentrations the impact on combustion performance is mostly negligible.

Quantitative planar laser-induced fluorescence measurements of fuel/air mixing in engines are usually based on the use of fluorescence tracers. The strength of the signals often depends on temperature, pressure and mixture composition. This complicates a quantitative analysis. The use of a small-bore optical engine for fundamental studies of absorption and fluorescence properties of fluorescence tracers is described. The temperature, pressure and composition dependence of the spectra of toluene, acetone, 3-pentanone, and biacetyl are examined under motored conditions to extend the experimental data base for the development of comprehensive models that predict the strength of fluorescence signals for a given condition.