Search Results

From the viewpoint of primary energy diversification and CO2 reduction, interests of using Biomass Fuel are rising. Some kinds of FAME (Fatty Acid Methyl Ester), which are obtained from oil fats like vegetable oil using transesterification reaction with methanol, are getting Palm Oilpular for bio-diesel recently. In this study, we have conducted many experiments of palm oil hydrogenations using our pilot plants, and checked the reactivity and the pattern of product yields. As a result, we figured out that the hydrocarbon oil equivalent to the conventional diesel fuel can be obtained from vegetable oils in good yield under mild hydrogenation conditions. Moreover, as a result of various evaluations for the hydrogenated palm oil (oxidation stability, lowtemperature flow property, LCA, etc.), we found that the hydrogenated palm oil by our technology has performances almost equivalent to conventional diesel fuel.

Phosphor thermometry was used during fuel injection in an optical engine with the glass piston of reentrant type. SiO2 coated phosphor particle was used for the gas-phase temperature measurements, which gave much less background signal. The measurements were performed in motored mode, in combustion mode with injection of n-heptane and in non-combustion mode with injection of iso-octane. In the beginning of injection period, the mean temperature of each injection cases was lower than that of the motored case, and temperature of iso-octane injection cases was even lower than that of n-heptane injection cases. This indicates, even if vaporization effect seemed to be the same at both injection cases, the effect of temperature decrease changed due to the chemical reaction effect for the n-heptane cases. Chemical reaction seems to be initiated outside of the fuel liquid spray and the position was moving towards the fuel rich area as the time proceeds.

Generally, soot emissions increase in diesel engines with smaller bore sizes due to larger spray impingement on the cavity wall at a constant specific output power. The objective of this study is to clarify the constraints for engine/nozzle specifications and injection conditions to achieve the same combustion characteristics (such as heat release rate and emissions) in diesel engines with different bore sizes. The first report applied the geometrical similarity concept to two engines with different bore sizes and similar piston cavity shapes. The smaller engine emitted more smoke because air entrainment decreases due to the narrower spray angle. A new spray design method called spray characteristics similarity was proposed to suppress soot emissions. However, a smaller nozzle diameter and a larger number of nozzle holes are required to maintain the same spray characteristics (such as specific air-entrainment and penetration) when the bore size decreases.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

Single cylinder engine testing was carried out to clearly understand the test results of multi-cylinder engines reported by the Diesel WG in JCAP (Japan Clean Air Program) (1), (2), (3) and (4). In this tests, engine specifications such as fuel injection pressure, nozzle hole diameter, turbo-charging pressure, EGR rate, and fuel properties such as 1-, 2-, 3-ring aromatics content, n-,i-paraffins content, and T90 were parametrically changed and their influence on the emissions were studied. PM emission generally increased in each engine condition with increased aromatic contents and T90. In particular, multi ring aromatics brought about large increases in PM regardless of the engine conditions. The influence of fuel properties on NOx emission is smaller than the influence on PM emission. Some other fuels that have various side chain structures of 1-ring aromatics, normal paraffins only and various naphthene contents were also investigated.

A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.

The effects of fuel octane have been assessed on the efficiency and emissions of a high compression ratio (ε=13) spark ignition direct injection (SIDI) engine. Under low load stratified operation (1200 rpm, ∼20% load), a low octane fuel (RON=84, comprised of toluene, iso-octane, and n-heptane) yielded higher brake thermal efficiency and significantly lower hydrocarbon emissions than a base gasoline (RON=91). The indicator diagram for the low octane fuel showed evidence for two stage heat release, suggesting the presence of spark induced compression ignition (SICI). These results suggest that higher efficiency under low load stratified conditions can be obtained with lower octane fuels that undergo SICI combustion. The effect of fuel octane under high load was assessed at WOT with a high RON model fuel (RON=103, comprised of toluene, iso-octane, and n-heptane).

Spark ignition direct injection (SIDI) engines have the potential to realize significant thermal efficiency improvements compared to conventional port fuel injection engines. The effects of fuel properties on efficiency and emissions have been investigated in a prototype of an Avensis Wagon equipped with a 2.0 liter, 4 cylinder spark ignition, direct injection (SIDI) engine designed to meet US 2000 emission standards. The vehicle employed a close coupled three-way catalyst and a NOx storage and reduction catalyst. Seven matrix fuels were blended to the same RON with varying levels of aromatics, olefins, ethanol, and volatility. Relative thermal efficiency, fuel economy, and tailpipe emissions were measured for the matrix fuels and a base fuel under the FTP LA4 driving cycle. The engine was operated in a lean burn mode in light load condition for approximately half of the driving cycle.

Nitric Oxide (NO) can significantly influence the autoignition reactivity and this can affect knock limits in conventional stoichiometric SI engines. Previous studies also revealed that the role of NO changes with fuel type. Fuels with high RON (Research Octane Number) and high Octane Sensitivity (S = RON - MON (Motor Octane Number)) exhibited monotonically retarding knock-limited combustion phasing (KL-CA50) with increasing NO. In contrast, for a high-RON, low-S fuel, the addition of NO initially resulted in a strongly retarded KL-CA50 but beyond the certain amount of NO, KL-CA50 advanced again. The current study focuses on same high-RON, low-S Alkylate fuel to better understand the mechanisms responsible for the reversal in the effect of NO on KL-CA50 beyond a certain amount of NO.

Hydrotreated Vegetable Oil (HVO) and Sugar-to-Diesel as next-generation bio diesel fuels consist of normal and iso-paraffin, and those carbon number of paraffinic hydrocarbons and distillation characteristics are narrow distribution. These characteristics would cause to deteriorate the evaporation and mixture with air and fuel. Therefore, in this study, the effects of normal paraffin (Tridecane) and iso-paraffin (HVO) on emission characteristics and cold start performance in a diesel engine were investigated by engine dynamometer tests, cold start vehicle tests, and spray analyzer tests. From the results, it was found that normal and iso-paraffin are beneficial for HC, CO, Smoke emission reduction. In addition, isomerization is effective for the diesel engine to fulfill cold start performance, since normal paraffin of narrow carbon number distribution became solidified under low temperature and high pressure condition in a common rail system.

Fischer-Tropsch Diesel (FTD) fuel is expected to be a promising clean diesel fuel in the future because of its characteristics of zero sulfur, zero aromatics and a high cetane number. However, the optimum fuel properties for diesel engines have not been realized. In this study, the effects of cetane number and distillation characteristics on engine-out PM emissions from a conventional direct injection diesel engine were investigated by using paraffinic fuels which were made to simulate FTD fuel. From the results of the vehicle exhaust emissions test and engine dynamometer test, it was found that the narrow distillation characteristics (which eliminates heavy hydrocarbon fraction) could reduce the soluble organic fraction (SOF) in PM emissions, and the excess high cetane number characteristic promoted the formation of insoluble organic fraction (ISOF).

Combustion chamber deposits (CCD) in wall-guided stratified charged direct injection spark ignition (DISI) engines affect combustion significantly because CCD may disturb the air-fuel mixture formation and, as a result, cause emission deterioration. For the design of engines and fuels, it is therefore important to determine the effects of CCD on emissions from DISI engines. In this study, the effects of CCD on emissions from a DISI engine using different fuel distillation properties were investigated. The study results show that, during stratified charged operation, an increase in CCD increased the total hydrocarbon (THC) emissions under high speed conditions and the NOx emissions under the low speed conditions.

A new V-6 stoichiometric gasoline direct injection engine was developed for high performance FR (Front Engine Rear Drive) vehicles. High power performance, low fuel consumption and low exhaust emissions were achieved by employing a stoichiometric direct injection system that uses Toyota's unique slit nozzle injector that generates a fan-shaped fuel spray and variable intake and exhaust valve timing systems. Focusing on the power performance, maximum power of 183kW (61kW/L) is achieved at 6200rpm and maximum torque is 312Nm at 3600rpm. This power performance is among the top production 3.0 L gasoline engines in the world. This paper outlines the features of this engine and some special technologies contributing to the achievement of the above-mentioned high performance. Optimizing the intake-port design was done to improve power performance.

It is well known that pilot injection is an effective method of reducing diesel knock noise during idling, but no actual system has as yet been commercially produced. With the objective of developing a practicable pilot injection device, simulations were conducted of various simple mechanisms in order to determine the best specifications and analyze the fuel injection characteristics. Based on these results, a chamber expansion type pilot injection device, which enables the injection pump pressure chamber volume to be increased at a given moment during the fuel compression stroke, has been developed and has been found to remarkably decrease knock noise during cold idling. An investigation into the effects of this device on output power, exhaust emissions, cold startability and durability revealed that it is eminently suitable for practical application.

Global focus on CO2 reduction and environmental protection is increasing. To comply with stricter exhaust gas regulations and reduce real world emissions, it is becoming increasingly important to improve the performance of three-way catalysts. Therefore, highly efficient conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) is required. In general, the more active the precious metals used, the better the conversion performance. However, precious metals have supply risks, such as price fluctuation and the uneven distribution of production areas. Therefore, it is necessary to lower emissions while also lowering the amount of precious metals used. This paper focuses on how catalysts are used and describes the development of a new three-way catalyst for the purpose of strengthening cold conversion and decreasing the usage of precious metals.

In order to optimize air-fuel mixture formation in a small DI diesel engine, studies were conducted into the effects of combustion chamber shape and fuel spray impingement. Based on the findings of these studies, the shape of the combustion chamber was modified to induce complex air motion with high turbulence and fuel injection was carefully controlled to achieve optimum impingement intensity. As a result, the mixture formation process was greatly improved with a consequent gain in terms of engine performance. To clarify the reasons for this improvement in combustion, a three-dimensional calculation of the in-cylinder air motion was made. The behaviour of the spray and flame was observed using an endoscope. The new combustion system, named TOYOTA Reflex Burn system (TRB) thus developed has been adopted in production engines since August 1988.

From the point of global and local environment, internal combustion engine is facing the need for significant improvement of exhaust emission. Especially, important is the reduction of unburned hydrocarbon (HC) from fuel film on liner under cold condition. In this study, at first, quantitative fuel film measurement technique by using Laser Induced Exciplex Fluorescence (LIEF) was developed. For the light source, 4th harmonic pulse yttrium aluminum garnet (YAG) laser (266nm) was used. For the tracer, the combination of N,N-Dimethylaniline (DMA) and naphthalene was used and quantitative concentration was decided by calibration test. With LIEF, the distribution of fuel film can be obtained by measuring the fluorescence only from the liquid phase. In order to evaluate the effect of fuel film on exhaust HC emission from engine, the film distribution was measured using quartz glass liner. For the injector, a prototype 6-hole gasoline injector was used.

An unique diesel engine electronic control system has been developed, which contains two distinctive features. Firstly, the delivery type fuel injection pump has an electro-magnetic valve to control the quantity of fuel injected. This valve is then acutuated to ensure that the timing of the high pressure fuel flow out stops the fuel injection. In the previous diesel electronic control system, the fuel quantity control was effected via the position control of a mechanical spill ring. Since timing control is more suitable than position control for handling by a microcomputer, the electro-magnetic valve is able to control the quantity of fuel injected more precisely, whilst consisting of a simpler structure. Secondly, an optical combustion timing sensor is able to detect initial combustion timing by sensing the light of the combustion flame in the combustion chamber. Using the signal from the sensor, the microcomputer then exerts a compensating control over the fuel injection timing.

One primary result of the reduction of platinum group metals (PGM) within a catalytic converter is the decline in NOx conversion efficiency. This paper hypothesizes that the primary factor of this decline to be hydrocarbon (HC) poisoning. To maintain high NOx conversion efficiency as the PGM reduces, Rh activation improvement becomes significant to overcome the HC poisoning. Analysis of the Rh deterioration mechanism found that it is effective to separately arrange Rh and CeO2 on the converter, avoiding the Rh deactivation. By this improvement, we improved the catalyst activity at less than 25% of the original Rh loading.