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An author's previous studies addressed a combustion system which reduces emissions, noise, and fuel consumption by using PCCI with the split injection of fuel. This concept relies on the premixed combustion of the first injected fuel and accelerated oxidation by the second injected fuel. Although this combustion system requires the optimization of the timing of the second injection, the details of how noise and emissions are reduced have not been elucidated. In this paper, the authors explain the mechanism whereby emissions and noise are reduced by the second injection. In-cylinder visualizations and numerical simulations both showed an increase in smoke and CO as the second injection timing was advanced, as induced by the inhibited oxidation of the rich flame. When the second injection timing is excessively retarded, the amount of soot forming around the near-nozzle increased.