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Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.

In an evaluation of crashworthiness for the cars made of aluminum alloys, the evaluation considering fracture phenomenon comes to be needed because conventional aluminum alloys have low fracture strain (10-20%). In case of the development of a B-Pillar made by die cast, if crack occurrence, furthermore, separation of a part can be estimated by using CAE in crashworthiness evaluations, we can reduce the number of prototype makings and the cost of development using expensive dies. Therefore, we performed crashworthiness evaluations by CAE using some sort of a damage & fracture material model. It is known as “Orthotropic damage & fracture model”.

In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).

In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.

We have tried to improve damping capacity of an aluminum alloy by means of dispersing ceramic particles (low damping SiC and high damping NdNbO4) of different sizes and volume fractions in the aluminum alloy by powder metallurgy. It is shown that the damping capacity is increased in every case accompanying an increase of Young's modulus. It is also shown that the intrinsic damping capacity of dispersed particles does not play a role in improving the damping capacity. The increase of the damping capacity seems to be attributed to dislocations breakaway, interaction of fine particles and dislocations, and relaxation of interface between ceramic particles and aluminum matrix.

A technique for induction-hardening local portions of vehicle body reinforcements press-formed of thin sheet steel has been developed, with the aim of ensuring occupant safety in a side collision. This technique for increasing the tensile strength of sheet steel was practically applied to the front floor cross member and center pillar reinforcement. Owing to this method, the weight of body reinforcements can be decreased. New induction-hardening systems have also been developed for the present technique. One is an apparatus which allows induction-hardening a part with a three-dimensionally curved surface. Another is a straightening quench technique used to retain the same dimensional accuracy as the original press-formed part.

From the viewpoint of measures for environmental issues, the amount of solvents in paint for aluminum wheels needs to be minimized. Environmentally friendly powder coatings have been used widely for primer coating and clear coating, but there is no precedent for its use for base coating. This time, we optimized the condition of surface treatment of pigment and hardening behavior of constituent resin in the melting process and succeeded in developing a metallic powder coating for aluminum wheels that fulfills the appearance and the quality requirements of aluminum wheels.

The experimental research vehicle ES3 body was realized by using various aluminum-joining technologies: MIG welding, laser welding, self-piercing riveting. These technologies were applied selectively to make full use of their individual characteristics, according to the body structure and joined materials. Of these technologies, self-piercing riveting is advantageous in several respects. Aiming to expand the application range of riveting technology, we developed a die that prevents cracks in joining aluminum casting, and a method to improve rivet driving in thick, multi-pile portion. We further studied the feasibility of aluminum rivets. This paper outlines the ES3 body structure and it's joining technologies used and introduces the further improvements we developed concerning self-piercing riveting.

Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.

Fluoroelastmers are well known for their resistance to heat and fluids, and have become major material for crankcase oil seals. On the other hand, new additive formulations are developed for engine lubricants used for fuel economic gasoline engines. In this paper, the effects of those additives on properties of fluoroelastmers are investigated. The results of the immersion tests of both test plaques and oil seal products indicate that dithiocarbamates, friction modifier, have hardening effects on fluoroelastmers. The fluoroelastmer deterioration mechanism is determined by analysis of elastmer samples after immersion in oil.

In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.

In this report, adhesion mechanism between epoxy resin and primer and between primer and Ni platting in Hybrid vehicle (HV) was investigated. Adhesion forces are thought to be a combination of mechanical bond forces (such as anchor effect), chemical bond forces and physical bond forces (such as hydrogen bonding and Van der Waals force). Currently there is insufficient understanding of the adhesion mechanism. In particular, the extent to which the three bond forces contribute to adhesion strength. So the adhesion mechanism of polyimide primers was analyzed using a number of different methods, including transmission electron microscope (TEM) and atomic force microscope (AFM) observation, to determine the contributions of the three bonding forces. Molecular simulation was also used to investigate the relationship between adhesion strength and the molecular structure of the primer.

1 Structural parts, such as the center pillar, are a multi-layer structure. They are a combination of high-strength panels and high-toughness panels, to control the deformation mode during a crash. If we can make this multi-layered structure as one panel, consisting of different hardness within it, we will be able to make a lightweight part. In this study, we have developed a method to fabricate a ‘lightweight center pillar’ with the following processes. First, the whole panel is hardened by quenching within the hot stamp process. Next, certain areas of the panel are softened by partial tempering. We have found that the temperature zone for softening is between A1 and A3, and it is easy to perform a rapid and accurate tempering by utilizing induction heating around the Curie temperature between A1 and A3 transformation temperature.

Mass reduction of parts is growing in importance as a means for reducing CO2 emissions from vehicles.The aim of the present research was to contribute to further mass reduction of pistons by developing a new aluminum casting material with highest level of fatigue strength. This goal was achieved using a development concept of creating a homogeneous structure in which Ti was added to create a fine structure and appropriate quantities of Fe and Mn were added to form a compound that is stable at high temperatures. Stand-alone tests of prototype pistons fabricated using the developed material show that the material is 14% stronger than the conventional material, thereby enabling increases in power and mass reduction.

A hardening depth evaluation technique using eddy current has been developed, which can be applied to a mass production line for destructive (cutting) inspections. Using this technique, changes in the hardness of the induction-hardened structure can be detected based on the changes in magnetic permeability. This technique reduces the thermal effect and improves measurement accuracy through a multi-frequency exciting method and a difference method algorithm.

The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.

The use of lead-free (Pb-free) solder and plating in onboard electronic components has accelerated rapidly in recent years, but solutions have yet to be found for the issues of whisker generation in tin (Sn) plating and crack initiation in Pb-free solder, despite widespread research efforts. Analysis of the whisker generation mechanism has focused on internal energy levels and crystal orientation, and analysis of the crack initiation mechanism in Pb-free solder has examined changes in the grain boundaries of Sn crystals.