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Journal Article

Using Chemical Kinetics to Understand Effects of Fuel Type and Compression Ratio on Knock-Mitigation Effectiveness of Various EGR Constituents

2019-04-02
2019-01-1140
Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.
Technical Paper

Two-Dimensional Temperature Measurements in Diesel Piston Bowl Using Phosphor Thermometry

2009-09-13
2009-24-0033
Phosphor thermometry was used during fuel injection in an optical engine with the glass piston of reentrant type. SiO2 coated phosphor particle was used for the gas-phase temperature measurements, which gave much less background signal. The measurements were performed in motored mode, in combustion mode with injection of n-heptane and in non-combustion mode with injection of iso-octane. In the beginning of injection period, the mean temperature of each injection cases was lower than that of the motored case, and temperature of iso-octane injection cases was even lower than that of n-heptane injection cases. This indicates, even if vaporization effect seemed to be the same at both injection cases, the effect of temperature decrease changed due to the chemical reaction effect for the n-heptane cases. Chemical reaction seems to be initiated outside of the fuel liquid spray and the position was moving towards the fuel rich area as the time proceeds.
Journal Article

Theoretical Study on Spray Design for Small-Bore Diesel Engine (Second Report)

2017-03-28
2017-01-0704
Generally, soot emissions increase in diesel engines with smaller bore sizes due to larger spray impingement on the cavity wall at a constant specific output power. The objective of this study is to clarify the constraints for engine/nozzle specifications and injection conditions to achieve the same combustion characteristics (such as heat release rate and emissions) in diesel engines with different bore sizes. The first report applied the geometrical similarity concept to two engines with different bore sizes and similar piston cavity shapes. The smaller engine emitted more smoke because air entrainment decreases due to the narrower spray angle. A new spray design method called spray characteristics similarity was proposed to suppress soot emissions. However, a smaller nozzle diameter and a larger number of nozzle holes are required to maintain the same spray characteristics (such as specific air-entrainment and penetration) when the bore size decreases.
Technical Paper

The New Toyota Inline 4 Cylinder 1.8L ESTEC 2ZR-FXE Gasoline Engine for Hybrid Car

2016-04-05
2016-01-0684
The engine in the new fourth generation Prius carries over the same basic structure as the 2ZR-FXE used in the third generation and incorporates various refinements to enhance fuel efficiency. Called the ESTEC 2ZR-FXE, the new engine incorporates various fuel efficient technologies to improve combustion characteristics, knocking, and heat management, while also reducing friction. As a result of this meticulous approach to enhancing fuel efficiency, the new engine is the first gasoline engine in the world to achieve a maximum thermal efficiency of 40%. This paper describes the fuel efficient technologies incorporated into this engine.
Technical Paper

The Impact of RON on SI Engine Thermal Efficiency

2007-07-23
2007-01-2007
Recently, global warming and energy security have received significant attention. Thus an improvement of the vehicle fuel economy is strongly required. For engines, one effective way is to improve the engine thermal efficiency. Raising compression ratio [1] or turbo charging technologies have potential to achieve high thermal efficiency. However knock does not allow the high thermal efficiency. Knock depends on the fuel composition and the pressure and temperature history of unburnt end-gas [2-3]. For fuels, RON is well known for describing the anti knock quality. High RON fuels have high anti knock quality and result in higher thermal efficiency. This paper investigates the impact of high RON fuels on the thermal efficiency by using high compression ratio engine, turbo charged engine, and lean boosted engine [4]. Finally, it is shown that the high thermal efficiency can be approached with high RON gasoline and ethanol.
Technical Paper

The Effect of Gasoline Metallic Additives on Low Speed Pre-Ignition

2018-04-03
2018-01-0936
Methylcyclopentadienyl manganese tricarbonyl (MMT) is used as an octane-enhancing metallic additive for unleaded gasoline which can prevent engine knock by proactive reaction with the hydrocarbon free radicals before starting the auto-ignition of hydrocarbons. However it has been pointed out that MMT causes automotive catalysts clogging and spark plug severely fouling. Therefore, many countries have fuel standards that prohibit or limit the usage of MMT. Nevertheless, some countries still use MMT as there are no restrictions imposed by fuel standards. As mentioned in several papers, metallic additives of engine oil such as calcium cause an abnormal combustion phenomenon called low-speed pre-ignition (LSPI) in turbocharged spark ignition engines. In contrast, the effect of metallic additives of gasoline such as MMT on LSPI has not been studied.
Technical Paper

Summary report of Japan Clean Air Program diesel and diesel fuel activities

2007-07-23
2007-01-1952
Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.
Technical Paper

Research of Knocking Deterioration due to Accumulated Carbon Deposits on Piston Surfaces

2019-04-02
2019-01-1141
The quantity of heavy components in fuel is increasing as automotive fuels diversify, and engine oil formulations are becoming more complex. These trends result in the formation of larger amounts of carbon deposits as reaction byproducts during combustion, potentially worsening the susceptibility of the engine to knock [1]. The research described in this paper aimed to identify the mechanism that causes knocking to deteriorate due to carbon deposits in low to medium engine load ranges, which are mainly used when the vehicle drives off and accelerates. With this objective, the cylinder temperature and pressure with and without deposits were measured, and it was found that knocking deteriorates in a certain range of ignition timing.
Technical Paper

Research of Fuel Components to Enhance Engine Thermal Efficiency Part I: Concepts for Fuel Molecule Candidate

2019-12-19
2019-01-2255
As part of efforts to address climate change and improve energy security, researchers have improved the thermal efficiency of engines by expanding the lean combustion limit. To further expand the lean combustion limit, the authors focused not only on engine technology but the chemical reactivity of various fuel molecules. Furan and anisole were among the fuel molecules selected, based on the idea that promising candidates should enhance the flame propagation speed and have good knocking resistance. Engine testing showed that the lean limit can be expanded by using fuels with the right molecular structures, resulting in higher thermal efficiency.
Technical Paper

Parametric Study and Clarification of Determination Factors of Diesel Exhaust Emission Using a Single Cylinder Engine and Model Fuels - JCAP Combustion Analysis Working Group Report Part I

2002-10-21
2002-01-2824
Single cylinder engine testing was carried out to clearly understand the test results of multi-cylinder engines reported by the Diesel WG in JCAP (Japan Clean Air Program) (1), (2), (3) and (4). In this tests, engine specifications such as fuel injection pressure, nozzle hole diameter, turbo-charging pressure, EGR rate, and fuel properties such as 1-, 2-, 3-ring aromatics content, n-,i-paraffins content, and T90 were parametrically changed and their influence on the emissions were studied. PM emission generally increased in each engine condition with increased aromatic contents and T90. In particular, multi ring aromatics brought about large increases in PM regardless of the engine conditions. The influence of fuel properties on NOx emission is smaller than the influence on PM emission. Some other fuels that have various side chain structures of 1-ring aromatics, normal paraffins only and various naphthene contents were also investigated.
Journal Article

On the Role of Nitric Oxide for the Knock-Mitigation Effectiveness of EGR in a DISI Engine Operated with Various Gasoline Fuels

2019-12-19
2019-01-2150
The knock-suppression effectiveness of exhaust-gas recirculation (EGR) can vary between implementations that take EGR gases after the three-way catalyst and those that use pre-catalyst EGR gases. A main difference between pre-and post-catalyst EGR gases is the level of trace species like NO, UHC, CO and H2. To quantify the role of NO, this experiment-based study employs NO-seeding in the intake tract for select combinations of fuel types and compression ratios, using simulated post-catalyst EGR gases as the diluent. The four investigated gasoline fuels share a common RON of 98, but vary in octane sensitivity and composition. To enable probing effects of near-zero NO levels, a skip-firing operating strategy is developed whereby the residual gases, which contain trace species like NO, are purged from the combustion chamber. Overall, the effects of NO-seeding on knock are consistent with the differences in knock limits for preand post-catalyst EGR gases.
Technical Paper

Octane Appetite Studies in Direct Injection Spark Ignition (DISI) Engines

2005-04-11
2005-01-0244
The anti-knock or octane quality of a fuel depends on the fuel composition as well as on the engine design and operating conditions. The true octane quality of practical fuels is defined by the Octane Index, OI = (1-K)RON + KMON where K is a constant for a given operating condition and depends only on the pressure and temperature variation in the engine (it is not a property of the fuel). RON and MON are the Research and Motor Octane numbers respectively, of the fuel. OI is the octane number of the primary reference fuel (PRF) with the same knocking behaviour at the given condition. In this work a wide range of fuels of different RON and MON were tested in prototype direct injection spark ignition (DISI) engines with compression ratios of 11 and 12.5 at different speeds up to 6000 RPM. Knock Limited Spark Advance (KLSA) was used to characterize the anti-knock quality of the fuel. Experiments were also done using two cars with DISI engines equipped with knock sensor systems.
Journal Article

Low Emissions and High-Efficiency Diesel Combustion Using Highly Dispersed Spray with Restricted In-Cylinder Swirl and Squish Flows

2011-04-12
2011-01-1393
A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.
Technical Paper

Fuel Effects on SIDI Efficiency and Emissions

2003-10-27
2003-01-3186
Spark ignition direct injection (SIDI) engines have the potential to realize significant thermal efficiency improvements compared to conventional port fuel injection engines. The effects of fuel properties on efficiency and emissions have been investigated in a prototype of an Avensis Wagon equipped with a 2.0 liter, 4 cylinder spark ignition, direct injection (SIDI) engine designed to meet US 2000 emission standards. The vehicle employed a close coupled three-way catalyst and a NOx storage and reduction catalyst. Seven matrix fuels were blended to the same RON with varying levels of aromatics, olefins, ethanol, and volatility. Relative thermal efficiency, fuel economy, and tailpipe emissions were measured for the matrix fuels and a base fuel under the FTP LA4 driving cycle. The engine was operated in a lean burn mode in light load condition for approximately half of the driving cycle.
Technical Paper

Friction Reduction Technology for Low Viscosity Engine Oil Compatible with LSPI Prevention Performance

2016-10-17
2016-01-2276
Increasing numbers of vehicles equipped with downsized, turbocharged engines have been introduced seeking for better fuel economy. LSPI (low speed pre-ignition), which can damage engine hardware, is a potential risk of the engines. We reported that engine oil formulation affects frequency of LSPI events, and formulating magnesium detergents into oil is a promising option to prevent LSPI events. From the viewpoint of achieving better fuel economy by engine oil, lowering viscosity is being required. However, it causes reduced oil film thickness and will expand boundary lubrication condition regions in some engine parts. Hence, a technology to reduce friction under boundary lubrication becomes important.
Technical Paper

Feasibility Study of Ethanol Applications to A Direct Injection Gasoline Engine

2007-07-23
2007-01-2037
Feasibility studies concerning ethanol utilization in direct injection gasoline engines were conducted in order to clarify the effects of ethanol on engine performance, exhaust emissions and injector deposit formation. The investigation results indicate that E100 (100% ethanol fuel) can improve full load engine performance around whole engine speed range in a high compression ratio engine (ε=13:1), compared to that of a base compression ratio engine (ε=11.5:1) operated on a premium gasoline. This was caused by the volumetric efficiency (ηv) improvement and engine knock suppression in the high compression ratio engine. On the other hand, HC emissions remarkably increased under lower engine speeds at a full load condition. This phenomenon suggests that poor combustion occurred due to insufficient mixing of air and E100 fuel under these conditions, in which the amount of ethanol injected was too large and fluidity in the cylinder was weak.
Journal Article

Experimental and Numerical Study on the Effect of Nitric Oxide on Autoignition and Knock in a Direct-Injection Spark-Ignition Engine

2022-08-30
2022-01-1005
Nitric Oxide (NO) can significantly influence the autoignition reactivity and this can affect knock limits in conventional stoichiometric SI engines. Previous studies also revealed that the role of NO changes with fuel type. Fuels with high RON (Research Octane Number) and high Octane Sensitivity (S = RON - MON (Motor Octane Number)) exhibited monotonically retarding knock-limited combustion phasing (KL-CA50) with increasing NO. In contrast, for a high-RON, low-S fuel, the addition of NO initially resulted in a strongly retarded KL-CA50 but beyond the certain amount of NO, KL-CA50 advanced again. The current study focuses on same high-RON, low-S Alkylate fuel to better understand the mechanisms responsible for the reversal in the effect of NO on KL-CA50 beyond a certain amount of NO.
Technical Paper

Engine Thermal Control for Improving the Engine Thermal Efficiency and Anti-Knocking Quality

2012-04-16
2012-01-0377
In recent years, improving the engine thermal efficiency is strongly required. To enhance the engine thermal efficiency, it is important to improve the engine anti-knock quality. Technologies for modifying engine cooling have been developed to improve anti-knocking quality of engines. However, excessive improvement of engine cooling leads to an increase in cooling heat loss. Therefore, it is necessary to clarify the effects of the temperature of each part of the engine such as engine head-cylinder, cylinder-liner, and piston on knocking and cooling heat loss. In this paper, computer aided engineering (CAE) is used to predict the effects of each part of the engine on engine knocking and cooling heat loss. Firstly, the amount of heat energy that air-fuel mixture receives from engine cylinder-head, cylinder-liner, and piston is calculated during the intake stroke. The result shows that the cylinder-liner contributes largest heat energy to air-fuel mixture, especially the exhaust side.
Technical Paper

Effects of High Turbulence Flow on Knock Characteristics

2004-03-08
2004-01-0977
In enhancing the performance of automotive internal combustion engines, increasing the compression ratio offers an effective means of improving engine thermal efficiency. If the compression ratio is increased, however, the problem of knock occurs in exchange for improvement in engine thermal efficiency. In other words, an increase in compression ratio causes in-cylinder compressive end gas temperature to rise, resulting in the occurrence of knock. This in turn requires ignition timing retard to combat the knock. This trade-off makes it difficult to achieve the theoretical maximum combustion efficiency. In this paper, we clarify the feasibility of suppressing the occurrence of knock by increasing the burn rate. Specifically, we increase the burn rate by injecting high-pressure air directly into the combustion chamber, causing highly turbulent in-cylinder flow.
Technical Paper

Effects of Fuel Properties on Premixed Charge Compression Ignition Combustion in a Direct Injection Diesel Engine

2003-05-19
2003-01-1815
Effects of fuel distillation characteristics and cetane number on premixed charge compression ignition (PCCI) combustion were investigated for the purpose of reducing NOx and PM emissions from a direct injection diesel engine. The test engine had a hole type injection nozzle for conventional diesel combustion at high load operation. A low compression ratio and cooled EGR were applied to the test engine in order to reduce the compression temperature for avoiding pre-ignition. The investigation results show that, in the case of ignition control by EGR, a light fuel with lower distillation characteristics had an advantage of reducing smoke at higher loads. This means that high volatility fuel is effective in promoting lean mixture formation of fuel and air during the ignition delay. Moreover, lowering the cetane number was effective in reducing NOx emissions by suppression of combustion temperature.
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