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Technical Paper

Variation in Corrosion Resistance of Trivalent Chromate Coating Depending on Type of Zinc Plating Bath

Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.
Technical Paper

Using Chemical Kinetics to Understand Effects of Fuel Type and Compression Ratio on Knock-Mitigation Effectiveness of Various EGR Constituents

Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs. The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.
Technical Paper

Two-Dimensional Temperature Measurements in Diesel Piston Bowl Using Phosphor Thermometry

Phosphor thermometry was used during fuel injection in an optical engine with the glass piston of reentrant type. SiO2 coated phosphor particle was used for the gas-phase temperature measurements, which gave much less background signal. The measurements were performed in motored mode, in combustion mode with injection of n-heptane and in non-combustion mode with injection of iso-octane. In the beginning of injection period, the mean temperature of each injection cases was lower than that of the motored case, and temperature of iso-octane injection cases was even lower than that of n-heptane injection cases. This indicates, even if vaporization effect seemed to be the same at both injection cases, the effect of temperature decrease changed due to the chemical reaction effect for the n-heptane cases. Chemical reaction seems to be initiated outside of the fuel liquid spray and the position was moving towards the fuel rich area as the time proceeds.
Technical Paper

Toyota’s New Driveline for FR Passenger Vehicles

The renewed platform of the upcoming flagship front-engine, rear-wheel drive (FR) vehicles demands high levels of driving performance, fuel efficiency and noise-vibration performance. The newly developed driveline system must balance these conflicting performance attributes by adopting new technologies. This article focuses on several technologies that were needed in order to meet the demand for noise-vibration performance and fuel efficiency. For noise-vibration performance, this article will focus on propeller shaft low frequency noise (booming noise). This noise level is determined by the propeller shaft’s excitation force and the sensitivity of differential mounting system. In regards to the propeller shaft’s excitation force, the contribution of the axial excitation force was clarified. This excitation force was decreased by adopting a double offset joint (DOJ) as the propeller shaft’s second joint and low stiffness rubber couplings as the first and third joints.
Journal Article

Thermal Analysis of Traction Contact Area Using a Thin-film Temperature Sensor

The purpose of this paper is to construct the thermal analysis model by measuring and estimating the temperature at the traction contact area. For measurement of temperature, we have used a thin-film temperature sensor. For estimation of temperature, we have composed the thermal analysis model. The thin-film temperature sensor was formed on the contact surface using a spattering device. The sensor is constituted of three layers (sensor layer, insulation layer and intermediate layer). Dimensions of the sensor were sufficiently smaller than the traction contact area. The sensor featured high specific pressure capacity and high speed responsiveness. The thermal analysis model was mainly composed of three equations: Carslaw & Jaeger equation, Rashid & Seireg equation and heat transfer equation of shear heating in oil film. The heat transfer equation involved two models (local shear heating model at middle plane, homogeneous shear heating model).
Technical Paper

The application of the damage & fracture material model to crashworthiness evaluations for Aluminum cars.

In an evaluation of crashworthiness for the cars made of aluminum alloys, the evaluation considering fracture phenomenon comes to be needed because conventional aluminum alloys have low fracture strain (10-20%). In case of the development of a B-Pillar made by die cast, if crack occurrence, furthermore, separation of a part can be estimated by using CAE in crashworthiness evaluations, we can reduce the number of prototype makings and the cost of development using expensive dies. Therefore, we performed crashworthiness evaluations by CAE using some sort of a damage & fracture material model. It is known as “Orthotropic damage & fracture model”.
Technical Paper

The Establishment of Laboratory Test Method for Gelation of Engine Oil Containing Magnesium Detergents

It has been reported that engine oils containing magnesium detergents gel under special conditions. The authors have previously reported on the mechanism by which magnesium detergents form needle crystals, which is the main cause of the gelation[1]. For this article, the authors conducted tests in actual vehicles using several types of engine oils containing magnesium detergents, including oils for which gelation problems have been reported in the market. The gelation was reproduced, and the test oils were ranked by their propensity to gel. In addition, a laboratory test method was used in which water and CO2 were mixed into engine oil under controlled conditions, then left stored in a bottle for twenty days, after which the kinematic viscosity and the quantity of insolubles of the mixture were measured. The study demonstrated the correlation between the laboratory test method and the actual vehicle tests.
Technical Paper

The Development of Toyota Fantasy Print System

Recently, the demands of vehicle owners have become more diversified. This is particularly true in the paint appearance of the vehicle. Responding to these demands Toyota has developed an ink jet painting system, Toyota Fantasy Print System. This system can illustrate practically any picture which the customer desires. The system utilized a subtractive method of paint mixture which mixes or piles up these four permeable inks. The development of durable ink as well as equipment which can efficiently and effectively apply the ink onto the required contoured surface.
Technical Paper

The Development of Fluid for Small-Sized and Light Weight Viscous Coupling

For viscous couplings(VCs) as a driving force transmission system of vehicles, requirement of torque characteristics has been getting very stringent. Because the torque characteristics significantly affect four wheel drive vehicles' abilities such as traction performance and driving stability. Furthermore, the recent concerns on high fuel economy, low pollution and low cost require that design of VCs should be increasingly compact, light weighted and excellent in transmitted torque's stability. It is an easy way to increase viscosity of viscous coupling fluids(VCFs) for the compact design of the VC. But it might cause increase in heat load and wear of plates which resulted in degradation of the VCF. The degradation affects VCF's viscosity and impairs stability in torque transmission. Therefore it is indispensable to develop high viscosity VCF which is excellent in long-term viscosity's stability.
Journal Article

Technical Development of Electro Magnetic Compatibility for Plug-in Hybrid Vehicle / Electric Vehicle Using Wireless Power Transfer System

In 2007, researchers at the Massachusetts Institute of Technology successfully completed a Wireless Power Transfer (WPT) experiment. Ever since, interest in WPT has been growing. At Toyota, we have been developing the underlying technology of a WPT system. Simultaneously we have been working with regulatory committees to create a standard for WPT. In particular, there are concerns that WPT’s radiated emissions could cause harm to humans and the neighboring electronic equipment. There are many challenges that need to be overcome, but a key concern is understanding WPT’s electromagnetic compatibility (EMI: Electro-Magnetic Interference and EMF: Electro-Magnetic Field). In this paper, we show the technical issues, the evaluation method, and the development status of EMI and EMF on PHVs/EVs when using WPT. For Electromagnetic interference (EMI) performance, we investigated both an open area test site and an electromagnetic anechoic chamber as evaluation environments.
Technical Paper

Study of Plastic Plating Using Highly Concentrated Ozonized Water Pretreatment

In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).
Technical Paper

Study of Large OSC Materials (Ln2O2SO4) on the Basis of Sulfur Redox Reaction

Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.
Technical Paper

Study of Future Engine Oil (First Report): Future Engine Oil Scenario

In recent years, problems such as global warming, the depletion of natural resources, and air pollution caused by emissions are emerging on a global scale. These problems call for efforts directed toward the development of fuel-efficient engines and exhaust gas reduction measures. As a solution to these issues, performance improvements should be achieved on the oil that lubricates the sliding sections of engines. This report points to features required of future engine oil-such as contribution to fuel consumption, minimized adverse effects on the exhaust gas aftertreatment system, and improved reliability achieved by sludge reduction-and discusses the significance of these features. For engine oil to contribution of engine oil to lower fuel consumption, we examined the effects of reduced oil viscosity on friction using gasoline and diesel engines.
Journal Article

Study of Alternative Oxygen Reduction Electrocatalyst for Pt Based on Transition Metal Chalcogenides

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.
Technical Paper

Solar Module Laminated Constitution for Automobiles

Replacing the metal car roof with conventional solar modules results in the increase of total car weight and change of center of mass, which is not preferable for car designing. Therefore, weight reduction is required for solar modules to be equipped on vehicles. Exchanging glass to plastic for the cover plate of solar module is one of the major approaches to reduce weight; however, load bearing property, impact resistance, thermal deformation, and weatherability become new challenges. In this paper a new solar module structure that weighs as light as conventional steel car roofs, resolving these challenges is proposed.
Technical Paper

Small Bore Diesel Engine Combustion Concept

Small bore diesel engines often adopt a two-valve cylinder head and a non-central injector layout to expand the port flow passage area. This non-central injector layout causes asymmetrical gas flow and fuel distribution, resulting in worse heat losses and a less homogenous fuel-air mixture than an equivalent four-valve cylinder head layout with a central injector. This paper describes the improvement of piston bowl geometry to achieve a more homogeneous gas flow and fuel-air mixture. This concept reduced fuel consumption by 2.5% compared to the original piston bowl geometry, while also reducing NOx emissions by 10%.
Technical Paper

Simultaneous PM and NOx Reduction System for Diesel Engines

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.
Technical Paper

Silicon Nitride Turbocharger Rotor for High Performance Automotive Engines

Toyota Motor Corporation has mass-produced turbochargers with silicon nitride ceramic rotors since October, 1989. Those turbochargers have been introduced into Celica and MR-2 which are Toyota sporty-type passenger cars. The designing of ceramic rotor was carried out in order to ensure the strength and durability of the component as well as to obtain the same aerodynamic characteristics as in the metal rotor. A moment of inertia was reduced by 60% using ceramic rotor which improved turbocharger response. The ceramic rotor was joined to metal shaft by new method which compensated problems in both shrink fitting and active brazing methods. High temperature strength of silicon nitride material was improved by controlling the amount of sintering additives and sintering conditions. The ceramic injection moulding was employed to mass-produce rotors with complicated shape, applying optimun binder compositions and moulding conditions.
Technical Paper

Rubber Suspension Bushing Model Identified by General Design Parameters for Initial Design Phase

This paper proposes a rubber suspension bushing model considering amplitude dependence as a useful tool at the initial design phase. Experiments were carried out to verify several dynamic characteristics of rubber bushings under vibration up to a frequency of 100 Hz, which is an important frequency range when designing ride comfort performance. When dynamic characteristic theory and the geometrical properties of the force-displacement characteristic curve were considered using these dynamic characteristics as assumptions, an equation was derived that is capable of calculating the dynamic stiffness under an arbitrary amplitude by identifying only two general design parameters (dynamic stiffness and loss factor) under a reference amplitude. The rubber suspension bushing model was then constructed by transforming this equation. Two verifications were carried out to confirm that the model is capable of reproducing measured bushing characteristics.
Technical Paper

Research in Aluminum Matrix Composites for Improvement in Damping Capacity

We have tried to improve damping capacity of an aluminum alloy by means of dispersing ceramic particles (low damping SiC and high damping NdNbO4) of different sizes and volume fractions in the aluminum alloy by powder metallurgy. It is shown that the damping capacity is increased in every case accompanying an increase of Young's modulus. It is also shown that the intrinsic damping capacity of dispersed particles does not play a role in improving the damping capacity. The increase of the damping capacity seems to be attributed to dislocations breakaway, interaction of fine particles and dislocations, and relaxation of interface between ceramic particles and aluminum matrix.